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arxiv: physics/0310043 · v1 · submitted 2003-10-09 · ⚛️ physics.chem-ph

Restoration of Many Electron Wave Functions from One-Electron Density

classification ⚛️ physics.chem-ph
keywords densityone-electronmany-electrontheoremcertainclasscolemanconditions
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General theorem describing a relation between diagonal of one-electron density matrix and a certain class of many-electron ensembles of determinant states is proved. As a corollary to this theorem a constructive proof of sufficiency of Coleman's representability conditions is obtained. It is shown that there exist rigorous schemes for construction of energy of many-electron system as functionals of one-electron density.

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