{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2006:22SQNGOVJAVMLZDCBBYOG4CIC5","short_pith_number":"pith:22SQNGOV","canonical_record":{"source":{"id":"physics/0604017","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"physics.chem-ph","submitted_at":"2006-04-04T14:46:49Z","cross_cats_sorted":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"title_canon_sha256":"126241a3a796a6ad72aa5ac18d423f5b12895b9cc048499e48fb472e9ea1a3c8","abstract_canon_sha256":"ea786efb5cd861d9c6b15713e6631d212883317610e4349def5146262b29e3d5"},"schema_version":"1.0"},"canonical_sha256":"d6a50699d5482ac5e4620870e37048174239238612b794814a36e8589b7562b1","source":{"kind":"arxiv","id":"physics/0604017","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"physics/0604017","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"arxiv_version","alias_value":"physics/0604017v2","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0604017","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"pith_short_12","alias_value":"22SQNGOVJAVM","created_at":"2026-05-18T12:25:53Z"},{"alias_kind":"pith_short_16","alias_value":"22SQNGOVJAVMLZDC","created_at":"2026-05-18T12:25:53Z"},{"alias_kind":"pith_short_8","alias_value":"22SQNGOV","created_at":"2026-05-18T12:25:53Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2006:22SQNGOVJAVMLZDCBBYOG4CIC5","target":"record","payload":{"canonical_record":{"source":{"id":"physics/0604017","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"physics.chem-ph","submitted_at":"2006-04-04T14:46:49Z","cross_cats_sorted":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"title_canon_sha256":"126241a3a796a6ad72aa5ac18d423f5b12895b9cc048499e48fb472e9ea1a3c8","abstract_canon_sha256":"ea786efb5cd861d9c6b15713e6631d212883317610e4349def5146262b29e3d5"},"schema_version":"1.0"},"canonical_sha256":"d6a50699d5482ac5e4620870e37048174239238612b794814a36e8589b7562b1","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:05:07.988915Z","signature_b64":"YHIlthvEA1lOk6xhb7gFaRZ+N6tN19ac9loMn0SJqW3Pw6p+HcUyT2TaALMy2D9/fijZb8hCNK61Xq4rJHIkDQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d6a50699d5482ac5e4620870e37048174239238612b794814a36e8589b7562b1","last_reissued_at":"2026-05-18T01:05:07.988243Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:05:07.988243Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"physics/0604017","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:05:07Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"VPGfbmFEraZeiI2Mm2U52+IF4+kdLxLRoiTDIOKLQZ4rdUfWe2jUZyMMqtnJsWYLZAI9FJixKBPsrUQ+GVwcAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-02T17:26:18.578188Z"},"content_sha256":"a4a36bffa3fd3a2a23819d16fe10271e9ff9f3d6e65e61160e34f32b1f3c63ba","schema_version":"1.0","event_id":"sha256:a4a36bffa3fd3a2a23819d16fe10271e9ff9f3d6e65e61160e34f32b1f3c63ba"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2006:22SQNGOVJAVMLZDCBBYOG4CIC5","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Modelling competitive coadsorption in electrochemical growth processes","license":"","headline":"","cross_cats":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"primary_cat":"physics.chem-ph","authors_text":"Daniel Lincot, Fabio D. A. Aarao Reis, J. P. Badiali, Thierry Pauporte","submitted_at":"2006-04-04T14:46:49Z","abstract_excerpt":"We present models of electrodeposition of ZnO films with organic additives, with focus on the growth of hybrid films with eosin Y. First we propose a rate equation model which assumes that the additives form branches with an exposed part above the ZnO deposit, growing with larger rate than the pure film, and that the rate of production of ZnO near those branches is proportional to the height exposed to the solution. This accounts for the production of OH- ions near the branches and the reactions with Zn++ ions. The steady state solution shows both species growing with the rate of the branches,"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0604017","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:05:07Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Bg6xV9at6WZn+BuYtPSZT4AqQyZrR0mKTr0MXxmgTmDCreCa3QRY81+kEUUJaoCLG/npJ2m3TftncujhulIjDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-02T17:26:18.578542Z"},"content_sha256":"ebc362a676e65d2ece3a26222c4bc12f9d8ee5d44dddb9035a4f09cc9fa7df4d","schema_version":"1.0","event_id":"sha256:ebc362a676e65d2ece3a26222c4bc12f9d8ee5d44dddb9035a4f09cc9fa7df4d"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/bundle.json","state_url":"https://pith.science/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-02T17:26:18Z","links":{"resolver":"https://pith.science/pith/22SQNGOVJAVMLZDCBBYOG4CIC5","bundle":"https://pith.science/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/bundle.json","state":"https://pith.science/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/state.json","well_known_bundle":"https://pith.science/.well-known/pith/22SQNGOVJAVMLZDCBBYOG4CIC5/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2006:22SQNGOVJAVMLZDCBBYOG4CIC5","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"ea786efb5cd861d9c6b15713e6631d212883317610e4349def5146262b29e3d5","cross_cats_sorted":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2006-04-04T14:46:49Z","title_canon_sha256":"126241a3a796a6ad72aa5ac18d423f5b12895b9cc048499e48fb472e9ea1a3c8"},"schema_version":"1.0","source":{"id":"physics/0604017","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"physics/0604017","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"arxiv_version","alias_value":"physics/0604017v2","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0604017","created_at":"2026-05-18T01:05:07Z"},{"alias_kind":"pith_short_12","alias_value":"22SQNGOVJAVM","created_at":"2026-05-18T12:25:53Z"},{"alias_kind":"pith_short_16","alias_value":"22SQNGOVJAVMLZDC","created_at":"2026-05-18T12:25:53Z"},{"alias_kind":"pith_short_8","alias_value":"22SQNGOV","created_at":"2026-05-18T12:25:53Z"}],"graph_snapshots":[{"event_id":"sha256:ebc362a676e65d2ece3a26222c4bc12f9d8ee5d44dddb9035a4f09cc9fa7df4d","target":"graph","created_at":"2026-05-18T01:05:07Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We present models of electrodeposition of ZnO films with organic additives, with focus on the growth of hybrid films with eosin Y. First we propose a rate equation model which assumes that the additives form branches with an exposed part above the ZnO deposit, growing with larger rate than the pure film, and that the rate of production of ZnO near those branches is proportional to the height exposed to the solution. This accounts for the production of OH- ions near the branches and the reactions with Zn++ ions. The steady state solution shows both species growing with the rate of the branches,","authors_text":"Daniel Lincot, Fabio D. A. Aarao Reis, J. P. Badiali, Thierry Pauporte","cross_cats":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"headline":"","license":"","primary_cat":"physics.chem-ph","submitted_at":"2006-04-04T14:46:49Z","title":"Modelling competitive coadsorption in electrochemical growth processes"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0604017","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a4a36bffa3fd3a2a23819d16fe10271e9ff9f3d6e65e61160e34f32b1f3c63ba","target":"record","created_at":"2026-05-18T01:05:07Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"ea786efb5cd861d9c6b15713e6631d212883317610e4349def5146262b29e3d5","cross_cats_sorted":["cond-mat.mtrl-sci","cond-mat.stat-mech","physics.comp-ph"],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2006-04-04T14:46:49Z","title_canon_sha256":"126241a3a796a6ad72aa5ac18d423f5b12895b9cc048499e48fb472e9ea1a3c8"},"schema_version":"1.0","source":{"id":"physics/0604017","kind":"arxiv","version":2}},"canonical_sha256":"d6a50699d5482ac5e4620870e37048174239238612b794814a36e8589b7562b1","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"d6a50699d5482ac5e4620870e37048174239238612b794814a36e8589b7562b1","first_computed_at":"2026-05-18T01:05:07.988243Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:05:07.988243Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"YHIlthvEA1lOk6xhb7gFaRZ+N6tN19ac9loMn0SJqW3Pw6p+HcUyT2TaALMy2D9/fijZb8hCNK61Xq4rJHIkDQ==","signature_status":"signed_v1","signed_at":"2026-05-18T01:05:07.988915Z","signed_message":"canonical_sha256_bytes"},"source_id":"physics/0604017","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a4a36bffa3fd3a2a23819d16fe10271e9ff9f3d6e65e61160e34f32b1f3c63ba","sha256:ebc362a676e65d2ece3a26222c4bc12f9d8ee5d44dddb9035a4f09cc9fa7df4d"],"state_sha256":"e283dbb46bfea90861e7776d7e33898c22f9b5018ce082da3981e0ee649c2fa9"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"6YazyR51CU1Ef8eQvhMBwzdpf2cIRVMjr06K3V+Si6bZwqfsLPBxp8TazrxX1j9z/FTjwJr8uD3P/V/9B4akCQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-02T17:26:18.580405Z","bundle_sha256":"2b81ab2610216544b5b0366fe0e522f06aecb54105a272ecd2b13593e0a46fb2"}}