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A longer candidate (10.1146/annurev-physchem-090820-015427.Nick) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1146/annurev-physchem-090820-015427.Nick","detected_arxiv_id":null,"ref_index":7,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"recoverable_identifier","severity":"advisory","verdict_class":"incontrovertible","note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1073/pnas.0601242103.Changwei) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1073/pnas.0601242103.Changwei","detected_arxiv_id":null,"ref_index":11,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"unresolvable_identifier","severity":"critical","verdict_class":"cross_source","note":"Identifier '10.1002/(sici)1096-987x(19960115)17:1' is syntactically valid but the DOI registry (doi.org) returned 404, and Crossref / OpenAlex / internal corpus also have no record. The cited work could not be located through any authoritative source.","detected_doi":"10.1002/(sici)1096-987x(19960115)17:1","detected_arxiv_id":null,"ref_index":12,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"recoverable_identifier","severity":"advisory","verdict_class":"incontrovertible","note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1016/j.cplett.2023.140556.9) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1016/j.cplett.2023.140556.9","detected_arxiv_id":null,"ref_index":15,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"recoverable_identifier","severity":"advisory","verdict_class":"incontrovertible","note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1073/pnas.1901529116.E.J.Torres-Herrera) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1073/pnas.1901529116.E.J.Torres-Herrera","detected_arxiv_id":null,"ref_index":17,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"recoverable_identifier","severity":"advisory","verdict_class":"incontrovertible","note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1021/jacs.9b10968.A.E.Sitnitsky.Model) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1021/jacs.9b10968.A.E.Sitnitsky.Model","detected_arxiv_id":null,"ref_index":14,"audited_at":"2026-05-20T01:28:52.071935Z"},{"detector":"doi_compliance","finding_type":"recoverable_identifier","severity":"advisory","verdict_class":"incontrovertible","note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1063/5.0187621.Ying) was visible in the surrounding text but could not be confirmed against doi.org as printed.","detected_doi":"10.1063/5.0187621.Ying","detected_arxiv_id":null,"ref_index":22,"audited_at":"2026-05-20T01:28:52.071935Z"}],"snapshot_sha256":"318623287acb3f5d304fb8bfdcf370a54d58e0ac4798f2e3e8f237a9a8afe419"},"events":[{"event_id":4007,"event_type":"pith.integrity.v1","payload_sha256":"f87e086151e5d2f7c1534c15b69d09a2b1d3f386178ffe8e532620191c19dd49","signature_b64":"VsL4E3em2WM0x5b8ucvaRi5GaC8fuFLQ0w2SMTcwFvAk/LEthuBYgnWlzSSNvgOoG0bwT+UET3EzX08F9g9FCg==","signing_key_id":"pith-v1-2026-05","created_at":"2026-05-20T01:32:30.715017+00:00","payload":{"note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1063/5.0187621.Ying) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1063/ 1.1927529. Wen-Zhen Zhang, Yuan Gao, Jiabao Chen, et al. Quantum information scrambling and chemical reactions.Proc. Natl. Acad. Sci. U.S.A., 121:e2321668121, 2024a. doi: 10.1073/ pnas.2321668121. Wen-Zhen Zhang, Yuan Gao, Jia","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":22,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1063/ 1.1927529. Wen-Zhen Zhang, Yuan Gao, Jiabao Chen, et al. Quantum information scrambling and chemical reactions.Proc. Natl. Acad. Sci. U.S.A., 121:e2321668121, 2024a. doi: 10.1073/ pnas.2321668121. Wen-Zhen Zhang, Yuan Gao, Jia","reconstructed_doi":"10.1063/5.0187621.Ying"},"severity":"advisory","ref_index":22,"audited_at":"2026-05-20T01:28:52.071935Z","event_type":"pith.integrity.v1","detected_doi":"10.1063/5.0187621.Ying","detector_url":"https://pith.science/pith-integrity-protocol#doi_compliance","external_url":null,"finding_type":"recoverable_identifier","evidence_hash":"77afccba96399adbcba74a582b5aed245743deaac9c53869a33bf4a3ce91f31b","paper_version":1,"verdict_class":"incontrovertible","resolved_title":null,"detector_version":"1.0.0","detected_arxiv_id":null}},{"event_id":4006,"event_type":"pith.integrity.v1","payload_sha256":"337a007c90f3947efd9ff912a92915b60f96a31384aa7b9ccaa5279c23ee6d66","signature_b64":"nVxcPDVhQMbn1gv3NfU1wZKo5mDdBcnvaxo4NR0B0T7fGoCq5MrxF3D4W1j3saCVufwaTXjCB+t1MiCZwdunBw==","signing_key_id":"pith-v1-2026-05","created_at":"2026-05-20T01:32:30.713449+00:00","payload":{"note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1073/pnas.1901529116.E.J.Torres-Herrera) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1073/pnas.1901529116. E.J. Torres-Herrera and L.F. Santos. Dynamical manifestations of quantum chaos: corre- lation hole and bulge.Philosophical Transactions of the Royal Society A, 375:20160434,","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":17,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1073/pnas.1901529116. E.J. Torres-Herrera and L.F. Santos. 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A longer candidate (10.1016/j.cplett.2023.140556.9) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1016/j.cplett.2023.140556. 9 Qiming Sun, Timothy C. Berkelbach, Nick S. Blunt, Garnet H. Booth, Sandeep Guo, Zhen- dong Li, Jie Liu, Jeffrey McClain, Elvira R. Sayfutyarova, Sandeep Sharma, Sebastian Wouters, and Garnet Kin-Lic Chan","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":15,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1016/j.cplett.2023.140556. 9 Qiming Sun, Timothy C. Berkelbach, Nick S. Blunt, Garnet H. Booth, Sandeep Guo, Zhen- dong Li, Jie Liu, Jeffrey McClain, Elvira R. Sayfutyarova, Sandeep Sharma, Sebastian Wouters, and Garnet Kin-Lic Chan","reconstructed_doi":"10.1016/j.cplett.2023.140556.9"},"severity":"advisory","ref_index":15,"audited_at":"2026-05-20T01:28:52.071935Z","event_type":"pith.integrity.v1","detected_doi":"10.1016/j.cplett.2023.140556.9","detector_url":"https://pith.science/pith-integrity-protocol#doi_compliance","external_url":null,"finding_type":"recoverable_identifier","evidence_hash":"d3bb32e6c1c2fa03cb5de393254c41c225175f7b0ad60a79c13ccfcd12ca2111","paper_version":1,"verdict_class":"incontrovertible","resolved_title":null,"detector_version":"1.0.0","detected_arxiv_id":null}},{"event_id":4004,"event_type":"pith.integrity.v1","payload_sha256":"ba47de01dd9f107b5511bcf0507581a2d0a435a5bf9e33a97fcf6a4e0625455e","signature_b64":"5F6cAOqxQBUF9iItEfl1bNA9HzdFkgPwJAJ8djS6se5FKJzENzcpIsOd3nruZxgNUsm0E8ppDky45i9btODjAw==","signing_key_id":"pith-v1-2026-05","created_at":"2026-05-20T01:32:30.709938+00:00","payload":{"note":"DOI in the printed bibliography is fragmented by whitespace or line breaks. A longer candidate (10.1021/jacs.9b10968.A.E.Sitnitsky.Model) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1021/jacs.9b10968. A. E. Sitnitsky. Model for vibrationally enhanced tunneling of proton transfer in a hydrogen bond.Chem. Phys. Lett., 818:140,","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":14,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1021/jacs.9b10968. A. E. Sitnitsky. Model for vibrationally enhanced tunneling of proton transfer in a hydrogen bond.Chem. Phys. 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The cited work could not be located through any authoritative source.","snippet":"doi: 10.1002/(SICI)1096-987X(19960115)17:1⟨49:: AID-JCC5⟩3.0.CO;2-0. Bal´ azs Pozsgay et al. Adiabatic gauge potential and integrability breaking in quantum many-body systems.SciPost Phys., 17:075,","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"doi":"10.1002/(sici)1096-987x(19960115)17:1","arxiv_id":null,"ref_index":12,"raw_excerpt":"doi: 10.1002/(SICI)1096-987X(19960115)17:1⟨49:: AID-JCC5⟩3.0.CO;2-0. Bal´ azs Pozsgay et al. 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A longer candidate (10.1073/pnas.0601242103.Changwei) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1073/pnas. 0601242103. Changwei Peng, Pablo Y. Ayala, H. Bernhard Schlegel, and Michael J. Frisch. Using re- dundant internal coordinates to optimize equilibrium geometries and transition states. J. Comput. Chem., 17(1):49–56,","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":11,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1073/pnas. 0601242103. Changwei Peng, Pablo Y. Ayala, H. Bernhard Schlegel, and Michael J. Frisch. Using re- dundant internal coordinates to optimize equilibrium geometries and transition states. J. Comput. 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A longer candidate (10.1146/annurev-physchem-090820-015427.Nick) was visible in the surrounding text but could not be confirmed against doi.org as printed.","snippet":"doi: 10.1146/annurev-physchem-090820-015427. Nick Indriolo, Thomas R. Geballe, Takeshi Oka, and Benjamin J. McCall. H + 3 in diffuse interstellar clouds: A tracer for the cosmic-ray ionization rate.Astrophys. J., 671:1736– 1747,","arxiv_id":"2604.21005","detector":"doi_compliance","evidence":{"ref_index":7,"verdict_class":"incontrovertible","resolved_title":null,"printed_excerpt":"doi: 10.1146/annurev-physchem-090820-015427. Nick Indriolo, Thomas R. Geballe, Takeshi Oka, and Benjamin J. McCall. H + 3 in diffuse interstellar clouds: A tracer for the cosmic-ray ionization rate.Astrophys. 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