{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2018:2UDTPHHLYZYTC2THTPLSMVPS4T","short_pith_number":"pith:2UDTPHHL","schema_version":"1.0","canonical_sha256":"d507379cebc671316a679bd72655f2e4ce40ad31f9c6b2d005202ad763e64737","source":{"kind":"arxiv","id":"1808.06824","version":1},"attestation_state":"computed","paper":{"title":"Solvation Effects Alter the Photochemistry of 2-Thiocytosine","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ji\\v{r}\\'i \\v{S}poner, Miko{\\l}aj J. Janicki, Rafa{\\l} Szabla, Robert W. G\\'ora","submitted_at":"2018-08-21T10:02:22Z","abstract_excerpt":"Radiationless deactivation channels of 2-thiocytosine in aqueous environment are revisited by means of quantum-chemical simulations of excited-state absorption spectra, and investigations of potential energy surfaces of the chromophore clustered with two water molecules using the algebraic diagrammatic construction method to the second-order (ADC(2)), and multireference configuration interaction with single and double excitations (MR-CISD) methods. We argue that interactions of explicit water molecules with thiocarbonyl group might enable water-chromophore electron transfer (WCET) which leads "},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1808.06824","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-08-21T10:02:22Z","cross_cats_sorted":[],"title_canon_sha256":"0dd9a60c71cba7abf316c146e5175e5ddc8cc9570015c2f8c3cf3a34e7403c7d","abstract_canon_sha256":"a8d4e8deed80429a76d1f11fd1484e552c99a448090e0f68f47559b1b2025b78"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:07:38.954289Z","signature_b64":"/9XR62sBLEEY/msa4p/fV3R2/5asST8zxhZCLhkhZJ68AnC2HD7nNo+F7o8v2mZrUId645o+0owPMHmvRHi1Cg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d507379cebc671316a679bd72655f2e4ce40ad31f9c6b2d005202ad763e64737","last_reissued_at":"2026-05-18T00:07:38.953482Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:07:38.953482Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Solvation Effects Alter the Photochemistry of 2-Thiocytosine","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ji\\v{r}\\'i \\v{S}poner, Miko{\\l}aj J. Janicki, Rafa{\\l} Szabla, Robert W. G\\'ora","submitted_at":"2018-08-21T10:02:22Z","abstract_excerpt":"Radiationless deactivation channels of 2-thiocytosine in aqueous environment are revisited by means of quantum-chemical simulations of excited-state absorption spectra, and investigations of potential energy surfaces of the chromophore clustered with two water molecules using the algebraic diagrammatic construction method to the second-order (ADC(2)), and multireference configuration interaction with single and double excitations (MR-CISD) methods. We argue that interactions of explicit water molecules with thiocarbonyl group might enable water-chromophore electron transfer (WCET) which leads "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1808.06824","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1808.06824","created_at":"2026-05-18T00:07:38.953589+00:00"},{"alias_kind":"arxiv_version","alias_value":"1808.06824v1","created_at":"2026-05-18T00:07:38.953589+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1808.06824","created_at":"2026-05-18T00:07:38.953589+00:00"},{"alias_kind":"pith_short_12","alias_value":"2UDTPHHLYZYT","created_at":"2026-05-18T12:32:02.567920+00:00"},{"alias_kind":"pith_short_16","alias_value":"2UDTPHHLYZYTC2TH","created_at":"2026-05-18T12:32:02.567920+00:00"},{"alias_kind":"pith_short_8","alias_value":"2UDTPHHL","created_at":"2026-05-18T12:32:02.567920+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T","json":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T.json","graph_json":"https://pith.science/api/pith-number/2UDTPHHLYZYTC2THTPLSMVPS4T/graph.json","events_json":"https://pith.science/api/pith-number/2UDTPHHLYZYTC2THTPLSMVPS4T/events.json","paper":"https://pith.science/paper/2UDTPHHL"},"agent_actions":{"view_html":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T","download_json":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T.json","view_paper":"https://pith.science/paper/2UDTPHHL","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1808.06824&json=true","fetch_graph":"https://pith.science/api/pith-number/2UDTPHHLYZYTC2THTPLSMVPS4T/graph.json","fetch_events":"https://pith.science/api/pith-number/2UDTPHHLYZYTC2THTPLSMVPS4T/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T/action/timestamp_anchor","attest_storage":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T/action/storage_attestation","attest_author":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T/action/author_attestation","sign_citation":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T/action/citation_signature","submit_replication":"https://pith.science/pith/2UDTPHHLYZYTC2THTPLSMVPS4T/action/replication_record"}},"created_at":"2026-05-18T00:07:38.953589+00:00","updated_at":"2026-05-18T00:07:38.953589+00:00"}