{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2023:2Z6PYXUBJSQDFY2GQLECCGBFPN","short_pith_number":"pith:2Z6PYXUB","canonical_record":{"source":{"id":"2307.08957","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-07-18T03:51:38Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"d0e83d4a21564715976470b5d44bd69c9d1539eb5a6ba68f7581952c33aea3d9","abstract_canon_sha256":"be3bf62bf3076d18805267b3898961161335c8f04c43754bf7c26ba813d525fd"},"schema_version":"1.0"},"canonical_sha256":"d67cfc5e814ca032e34682c82118257b4d85be7c01beca72aaf32ac4a75eda33","source":{"kind":"arxiv","id":"2307.08957","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2307.08957","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"arxiv_version","alias_value":"2307.08957v1","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2307.08957","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_12","alias_value":"2Z6PYXUBJSQD","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_16","alias_value":"2Z6PYXUBJSQDFY2G","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_8","alias_value":"2Z6PYXUB","created_at":"2026-07-05T06:31:36Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2023:2Z6PYXUBJSQDFY2GQLECCGBFPN","target":"record","payload":{"canonical_record":{"source":{"id":"2307.08957","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-07-18T03:51:38Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"d0e83d4a21564715976470b5d44bd69c9d1539eb5a6ba68f7581952c33aea3d9","abstract_canon_sha256":"be3bf62bf3076d18805267b3898961161335c8f04c43754bf7c26ba813d525fd"},"schema_version":"1.0"},"canonical_sha256":"d67cfc5e814ca032e34682c82118257b4d85be7c01beca72aaf32ac4a75eda33","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T06:31:36.745044Z","signature_b64":"q7PPKa9Nvriy5KqPVeLBbIfPBjmiZfb55jVG/qRpl9geZzZ6WEtS+I+L5eb8qRWPEIV680Sgo8peDrLPF1ASDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d67cfc5e814ca032e34682c82118257b4d85be7c01beca72aaf32ac4a75eda33","last_reissued_at":"2026-07-05T06:31:36.744483Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T06:31:36.744483Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2307.08957","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T06:31:36Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"81ZoY1g+X5WEU7fNIlCKYG/2R4BRu/R+liWi26gKVc6vUskAy6X+rfZO+K1bXgywbhLDlbU2mEsC4R7imTQtAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-06T16:54:34.467919Z"},"content_sha256":"1aa61ac84dae2d9aecda55d10e14b495096af6dfd208e6f8f709a9a763b04f40","schema_version":"1.0","event_id":"sha256:1aa61ac84dae2d9aecda55d10e14b495096af6dfd208e6f8f709a9a763b04f40"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2023:2Z6PYXUBJSQDFY2GQLECCGBFPN","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Oxidation kinetics and non-Marcusian charge transfer in dimensionally confined semiconductors","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Jian Chen, Jinlan Wang, Li Shi, Ning Xu, Paolo Samor\\`i, Peng Wang, Songlin Li, Weiyang Zhang, Xudong Pei, Yi Shi, Zheng Han","submitted_at":"2023-07-18T03:51:38Z","abstract_excerpt":"Electrochemical reactions represent essential processes in fundamental chemistry that foster a wide range of applications. Although most electrochemical reactions in bulk substances can be well described by the classical Marcus-Gerischer charge transfer theory, the realistic reaction character and mechanism in dimensionally confined systems remain unknown. Here, we report the multiparametric survey on the kinetics of lateral photooxidation in structurally identical WS2 and MoS2 monolayers, where electrochemical oxidation occurs at the atomically thin monolayer edges. The oxidation rate is corr"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2307.08957","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2307.08957/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T06:31:36Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"114XRrHkrqpSIc4FsKnFUbIAvUq/tzxBtMokN8Z20JAOwnndyvm94X8fAoreX1PGxfAMu/npeEJhtVmQU3u0BA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-06T16:54:34.468553Z"},"content_sha256":"e7601bfa46b3dd536b90711d1af37d1de1ffc1978c5872deef962ecabf7cf0b0","schema_version":"1.0","event_id":"sha256:e7601bfa46b3dd536b90711d1af37d1de1ffc1978c5872deef962ecabf7cf0b0"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/bundle.json","state_url":"https://pith.science/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-06T16:54:34Z","links":{"resolver":"https://pith.science/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN","bundle":"https://pith.science/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/bundle.json","state":"https://pith.science/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/state.json","well_known_bundle":"https://pith.science/.well-known/pith/2Z6PYXUBJSQDFY2GQLECCGBFPN/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2023:2Z6PYXUBJSQDFY2GQLECCGBFPN","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"be3bf62bf3076d18805267b3898961161335c8f04c43754bf7c26ba813d525fd","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-07-18T03:51:38Z","title_canon_sha256":"d0e83d4a21564715976470b5d44bd69c9d1539eb5a6ba68f7581952c33aea3d9"},"schema_version":"1.0","source":{"id":"2307.08957","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2307.08957","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"arxiv_version","alias_value":"2307.08957v1","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2307.08957","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_12","alias_value":"2Z6PYXUBJSQD","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_16","alias_value":"2Z6PYXUBJSQDFY2G","created_at":"2026-07-05T06:31:36Z"},{"alias_kind":"pith_short_8","alias_value":"2Z6PYXUB","created_at":"2026-07-05T06:31:36Z"}],"graph_snapshots":[{"event_id":"sha256:e7601bfa46b3dd536b90711d1af37d1de1ffc1978c5872deef962ecabf7cf0b0","target":"graph","created_at":"2026-07-05T06:31:36Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2307.08957/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Electrochemical reactions represent essential processes in fundamental chemistry that foster a wide range of applications. Although most electrochemical reactions in bulk substances can be well described by the classical Marcus-Gerischer charge transfer theory, the realistic reaction character and mechanism in dimensionally confined systems remain unknown. Here, we report the multiparametric survey on the kinetics of lateral photooxidation in structurally identical WS2 and MoS2 monolayers, where electrochemical oxidation occurs at the atomically thin monolayer edges. The oxidation rate is corr","authors_text":"Jian Chen, Jinlan Wang, Li Shi, Ning Xu, Paolo Samor\\`i, Peng Wang, Songlin Li, Weiyang Zhang, Xudong Pei, Yi Shi, Zheng Han","cross_cats":["cond-mat.mes-hall"],"headline":"","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-07-18T03:51:38Z","title":"Oxidation kinetics and non-Marcusian charge transfer in dimensionally confined semiconductors"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2307.08957","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:1aa61ac84dae2d9aecda55d10e14b495096af6dfd208e6f8f709a9a763b04f40","target":"record","created_at":"2026-07-05T06:31:36Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"be3bf62bf3076d18805267b3898961161335c8f04c43754bf7c26ba813d525fd","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-07-18T03:51:38Z","title_canon_sha256":"d0e83d4a21564715976470b5d44bd69c9d1539eb5a6ba68f7581952c33aea3d9"},"schema_version":"1.0","source":{"id":"2307.08957","kind":"arxiv","version":1}},"canonical_sha256":"d67cfc5e814ca032e34682c82118257b4d85be7c01beca72aaf32ac4a75eda33","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"d67cfc5e814ca032e34682c82118257b4d85be7c01beca72aaf32ac4a75eda33","first_computed_at":"2026-07-05T06:31:36.744483Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T06:31:36.744483Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"q7PPKa9Nvriy5KqPVeLBbIfPBjmiZfb55jVG/qRpl9geZzZ6WEtS+I+L5eb8qRWPEIV680Sgo8peDrLPF1ASDw==","signature_status":"signed_v1","signed_at":"2026-07-05T06:31:36.745044Z","signed_message":"canonical_sha256_bytes"},"source_id":"2307.08957","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:1aa61ac84dae2d9aecda55d10e14b495096af6dfd208e6f8f709a9a763b04f40","sha256:e7601bfa46b3dd536b90711d1af37d1de1ffc1978c5872deef962ecabf7cf0b0"],"state_sha256":"d7dcc8e8e2cf4d1efb1b321c383fbe3495cc872862b232c947b174befda6aa3d"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"/KQEfuNh+PwUD3DNdt3fYrrjXNk4LsxiHFvBIueig2wtSRM7EhEqNbq736zzL8QjfoVyfmEmMVrgJpjzPsCGAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-06T16:54:34.472918Z","bundle_sha256":"1a425b4a390ad248c52c23021f9778cd4ac4beb1c2ad325f2f2bb7956cb4f2fa"}}