{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2012:3ADUAFGVMRLQPNEEI6FJZLZE2Z","short_pith_number":"pith:3ADUAFGV","canonical_record":{"source":{"id":"1210.6897","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2012-10-25T16:30:22Z","cross_cats_sorted":["physics.comp-ph"],"title_canon_sha256":"d84d87b198d0b471431aab0e93837cf1aa64b77de0dc9f193d047f67f601217c","abstract_canon_sha256":"abca23192bf0fbf6a561c45c06451c6dd09a60006f8601f6c27662a66e65c665"},"schema_version":"1.0"},"canonical_sha256":"d8074014d5645707b484478a9caf24d6544741a5f2077aef0e3ddcfbf8ddee5c","source":{"kind":"arxiv","id":"1210.6897","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1210.6897","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"arxiv_version","alias_value":"1210.6897v1","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1210.6897","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"pith_short_12","alias_value":"3ADUAFGVMRLQ","created_at":"2026-05-18T12:26:50Z"},{"alias_kind":"pith_short_16","alias_value":"3ADUAFGVMRLQPNEE","created_at":"2026-05-18T12:26:50Z"},{"alias_kind":"pith_short_8","alias_value":"3ADUAFGV","created_at":"2026-05-18T12:26:50Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2012:3ADUAFGVMRLQPNEEI6FJZLZE2Z","target":"record","payload":{"canonical_record":{"source":{"id":"1210.6897","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2012-10-25T16:30:22Z","cross_cats_sorted":["physics.comp-ph"],"title_canon_sha256":"d84d87b198d0b471431aab0e93837cf1aa64b77de0dc9f193d047f67f601217c","abstract_canon_sha256":"abca23192bf0fbf6a561c45c06451c6dd09a60006f8601f6c27662a66e65c665"},"schema_version":"1.0"},"canonical_sha256":"d8074014d5645707b484478a9caf24d6544741a5f2077aef0e3ddcfbf8ddee5c","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T03:42:22.882719Z","signature_b64":"7+M/ZYX8HPR5a6t4o3McUZRH0+SyaAlfzU0ryKQLzR1e91lZjM1MotI5oy1b+8Tc0kpg24Oov+jWWQf/g7JCDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d8074014d5645707b484478a9caf24d6544741a5f2077aef0e3ddcfbf8ddee5c","last_reissued_at":"2026-05-18T03:42:22.882086Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T03:42:22.882086Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1210.6897","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:42:22Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"J8hItcykZ/4qyOg8DjLLeR8PBD4kB3buLhAFegjGuB76PGxhiHoTKuDLnfGN/axk+tDoWJa12+bXeeA2yurBCA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-10T20:32:36.719494Z"},"content_sha256":"4d1ce3580793fe032bdf08eac32d8cba10d84188ab95232005d5be9682f5102b","schema_version":"1.0","event_id":"sha256:4d1ce3580793fe032bdf08eac32d8cba10d84188ab95232005d5be9682f5102b"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2012:3ADUAFGVMRLQPNEEI6FJZLZE2Z","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Numerical local \"hybrid\" functional treatment of selected diatomic molecules: comparison of energies and multipole moments to conventional hybrid functionals","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.comp-ph"],"primary_cat":"physics.chem-ph","authors_text":"Artem E. Masunov, Ivan A. Mikhailov, Olga A. Shukruto, Valentin V. Karasiev","submitted_at":"2012-10-25T16:30:22Z","abstract_excerpt":"New local \"hybrid\" functionals proposed by V. V. Karasiev in [J. Chem. Phys. {\\bf 118}, 8567 (2003)] are benchmarked against nonlocal hybrid functionals. Their performance is tested on the total and high occupied orbital energies, as well as the electric moments of selected diatomic molecules. The new functionals, along with the Hartree-Fock and non-hybrid functionals, are employed for finite-difference calculations, which are basis-independent. Basis set errors in the total energy and electric moments are calculated for the 6-311G, 6-311G++G(3df,3pd) and AUG-cc-pVnZ (n=3,4,6) basis sets used "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1210.6897","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:42:22Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"yXac+4wDXStHd5RfHTCAY902ilfLI8ThPZL0x/egdLuGZikRwYszKOCFELPa3HT8w0AwgyiFKRnS+DFHyBFODg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-10T20:32:36.719836Z"},"content_sha256":"386754a81a555e9932336abfc4b27f686ffdcd96bff857f9ae500c7bd31bb384","schema_version":"1.0","event_id":"sha256:386754a81a555e9932336abfc4b27f686ffdcd96bff857f9ae500c7bd31bb384"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/bundle.json","state_url":"https://pith.science/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-10T20:32:36Z","links":{"resolver":"https://pith.science/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z","bundle":"https://pith.science/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/bundle.json","state":"https://pith.science/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/state.json","well_known_bundle":"https://pith.science/.well-known/pith/3ADUAFGVMRLQPNEEI6FJZLZE2Z/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2012:3ADUAFGVMRLQPNEEI6FJZLZE2Z","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"abca23192bf0fbf6a561c45c06451c6dd09a60006f8601f6c27662a66e65c665","cross_cats_sorted":["physics.comp-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2012-10-25T16:30:22Z","title_canon_sha256":"d84d87b198d0b471431aab0e93837cf1aa64b77de0dc9f193d047f67f601217c"},"schema_version":"1.0","source":{"id":"1210.6897","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1210.6897","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"arxiv_version","alias_value":"1210.6897v1","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1210.6897","created_at":"2026-05-18T03:42:22Z"},{"alias_kind":"pith_short_12","alias_value":"3ADUAFGVMRLQ","created_at":"2026-05-18T12:26:50Z"},{"alias_kind":"pith_short_16","alias_value":"3ADUAFGVMRLQPNEE","created_at":"2026-05-18T12:26:50Z"},{"alias_kind":"pith_short_8","alias_value":"3ADUAFGV","created_at":"2026-05-18T12:26:50Z"}],"graph_snapshots":[{"event_id":"sha256:386754a81a555e9932336abfc4b27f686ffdcd96bff857f9ae500c7bd31bb384","target":"graph","created_at":"2026-05-18T03:42:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"New local \"hybrid\" functionals proposed by V. V. Karasiev in [J. Chem. Phys. {\\bf 118}, 8567 (2003)] are benchmarked against nonlocal hybrid functionals. Their performance is tested on the total and high occupied orbital energies, as well as the electric moments of selected diatomic molecules. The new functionals, along with the Hartree-Fock and non-hybrid functionals, are employed for finite-difference calculations, which are basis-independent. Basis set errors in the total energy and electric moments are calculated for the 6-311G, 6-311G++G(3df,3pd) and AUG-cc-pVnZ (n=3,4,6) basis sets used ","authors_text":"Artem E. Masunov, Ivan A. Mikhailov, Olga A. Shukruto, Valentin V. Karasiev","cross_cats":["physics.comp-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2012-10-25T16:30:22Z","title":"Numerical local \"hybrid\" functional treatment of selected diatomic molecules: comparison of energies and multipole moments to conventional hybrid functionals"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1210.6897","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:4d1ce3580793fe032bdf08eac32d8cba10d84188ab95232005d5be9682f5102b","target":"record","created_at":"2026-05-18T03:42:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"abca23192bf0fbf6a561c45c06451c6dd09a60006f8601f6c27662a66e65c665","cross_cats_sorted":["physics.comp-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2012-10-25T16:30:22Z","title_canon_sha256":"d84d87b198d0b471431aab0e93837cf1aa64b77de0dc9f193d047f67f601217c"},"schema_version":"1.0","source":{"id":"1210.6897","kind":"arxiv","version":1}},"canonical_sha256":"d8074014d5645707b484478a9caf24d6544741a5f2077aef0e3ddcfbf8ddee5c","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"d8074014d5645707b484478a9caf24d6544741a5f2077aef0e3ddcfbf8ddee5c","first_computed_at":"2026-05-18T03:42:22.882086Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:42:22.882086Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"7+M/ZYX8HPR5a6t4o3McUZRH0+SyaAlfzU0ryKQLzR1e91lZjM1MotI5oy1b+8Tc0kpg24Oov+jWWQf/g7JCDw==","signature_status":"signed_v1","signed_at":"2026-05-18T03:42:22.882719Z","signed_message":"canonical_sha256_bytes"},"source_id":"1210.6897","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:4d1ce3580793fe032bdf08eac32d8cba10d84188ab95232005d5be9682f5102b","sha256:386754a81a555e9932336abfc4b27f686ffdcd96bff857f9ae500c7bd31bb384"],"state_sha256":"9528e8f451e7e2b94c1b2a37672665fa82cb8d7fa297926a73238585bdc7ec6e"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"y5BlU2z84Y1KA5yfb+BF0qjzW5AEBNOWQLa1DHs7oqKcp93ilse3mdmNltJMpUK1Bg0s6ng2vjaWVJExgVJ8Cw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-10T20:32:36.721804Z","bundle_sha256":"e74e06fc7aa6d7b96a3bbd2199df3558ff9ed15b96c1ce390120b7dd2019853d"}}