{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2014:3DYNDD2AF3KOWDM3TAPORUWY3R","short_pith_number":"pith:3DYNDD2A","schema_version":"1.0","canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","source":{"kind":"arxiv","id":"1410.7866","version":2},"attestation_state":"computed","paper":{"title":"Valence-bond Non-equilibrium Solvation Model for a Twisting Monomethine Cyanine","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ross H. McKenzie, Sean McConnell, Seth Olsen","submitted_at":"2014-10-29T03:08:18Z","abstract_excerpt":"We propose and analyze a two-state valence-bond model of non-equilibrium solvation effects on the excited-state twisting reaction of monomethine cyanines. Suppression of this reaction is thought responsible for environment-dependent fluorescence yield enhancement in these dyes. Fluorescence is quenched because twisting is accompanied via the formation of dark twisted intramolecular charge-transfer (TICT) states. For monomethine cyanines, where the ground state is a superposition of structures with different bond and charge localization, there are two possible twisting pathways with different c"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1410.7866","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","cross_cats_sorted":[],"title_canon_sha256":"9ebb58dfde293b345fb1e8a53262076197404b5424a54beaa5f58a3f896117ca","abstract_canon_sha256":"3b6a667e86f312ad3487cd91cae37bacefac6c8b3f043c858a55647883926428"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:00:20.136432Z","signature_b64":"ZVMHs/lPNIeeDWoyENVesYl8XkqifmO0hj0iFqoemy1fD/4XT6Ddg6GQC22sh9K9Z4h37d0hx1bEUg5V6Hg9Bg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","last_reissued_at":"2026-05-18T01:00:20.135788Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:00:20.135788Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Valence-bond Non-equilibrium Solvation Model for a Twisting Monomethine Cyanine","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ross H. McKenzie, Sean McConnell, Seth Olsen","submitted_at":"2014-10-29T03:08:18Z","abstract_excerpt":"We propose and analyze a two-state valence-bond model of non-equilibrium solvation effects on the excited-state twisting reaction of monomethine cyanines. Suppression of this reaction is thought responsible for environment-dependent fluorescence yield enhancement in these dyes. Fluorescence is quenched because twisting is accompanied via the formation of dark twisted intramolecular charge-transfer (TICT) states. For monomethine cyanines, where the ground state is a superposition of structures with different bond and charge localization, there are two possible twisting pathways with different c"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1410.7866","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1410.7866","created_at":"2026-05-18T01:00:20.135889+00:00"},{"alias_kind":"arxiv_version","alias_value":"1410.7866v2","created_at":"2026-05-18T01:00:20.135889+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1410.7866","created_at":"2026-05-18T01:00:20.135889+00:00"},{"alias_kind":"pith_short_12","alias_value":"3DYNDD2AF3KO","created_at":"2026-05-18T12:28:11.866339+00:00"},{"alias_kind":"pith_short_16","alias_value":"3DYNDD2AF3KOWDM3","created_at":"2026-05-18T12:28:11.866339+00:00"},{"alias_kind":"pith_short_8","alias_value":"3DYNDD2A","created_at":"2026-05-18T12:28:11.866339+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R","json":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R.json","graph_json":"https://pith.science/api/pith-number/3DYNDD2AF3KOWDM3TAPORUWY3R/graph.json","events_json":"https://pith.science/api/pith-number/3DYNDD2AF3KOWDM3TAPORUWY3R/events.json","paper":"https://pith.science/paper/3DYNDD2A"},"agent_actions":{"view_html":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R","download_json":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R.json","view_paper":"https://pith.science/paper/3DYNDD2A","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1410.7866&json=true","fetch_graph":"https://pith.science/api/pith-number/3DYNDD2AF3KOWDM3TAPORUWY3R/graph.json","fetch_events":"https://pith.science/api/pith-number/3DYNDD2AF3KOWDM3TAPORUWY3R/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/action/timestamp_anchor","attest_storage":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/action/storage_attestation","attest_author":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/action/author_attestation","sign_citation":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/action/citation_signature","submit_replication":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/action/replication_record"}},"created_at":"2026-05-18T01:00:20.135889+00:00","updated_at":"2026-05-18T01:00:20.135889+00:00"}