{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2014:3DYNDD2AF3KOWDM3TAPORUWY3R","short_pith_number":"pith:3DYNDD2A","canonical_record":{"source":{"id":"1410.7866","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","cross_cats_sorted":[],"title_canon_sha256":"9ebb58dfde293b345fb1e8a53262076197404b5424a54beaa5f58a3f896117ca","abstract_canon_sha256":"3b6a667e86f312ad3487cd91cae37bacefac6c8b3f043c858a55647883926428"},"schema_version":"1.0"},"canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","source":{"kind":"arxiv","id":"1410.7866","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1410.7866","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"arxiv_version","alias_value":"1410.7866v2","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1410.7866","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"pith_short_12","alias_value":"3DYNDD2AF3KO","created_at":"2026-05-18T12:28:11Z"},{"alias_kind":"pith_short_16","alias_value":"3DYNDD2AF3KOWDM3","created_at":"2026-05-18T12:28:11Z"},{"alias_kind":"pith_short_8","alias_value":"3DYNDD2A","created_at":"2026-05-18T12:28:11Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2014:3DYNDD2AF3KOWDM3TAPORUWY3R","target":"record","payload":{"canonical_record":{"source":{"id":"1410.7866","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","cross_cats_sorted":[],"title_canon_sha256":"9ebb58dfde293b345fb1e8a53262076197404b5424a54beaa5f58a3f896117ca","abstract_canon_sha256":"3b6a667e86f312ad3487cd91cae37bacefac6c8b3f043c858a55647883926428"},"schema_version":"1.0"},"canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:00:20.136432Z","signature_b64":"ZVMHs/lPNIeeDWoyENVesYl8XkqifmO0hj0iFqoemy1fD/4XT6Ddg6GQC22sh9K9Z4h37d0hx1bEUg5V6Hg9Bg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","last_reissued_at":"2026-05-18T01:00:20.135788Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:00:20.135788Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1410.7866","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:00:20Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ltMwt81nrIR1g6xR7Gw7D/GrcqxMXbNiguslu5Q0MhFqMEBhXTKosymvcfSfehFbIlxm0bx24IE+BVWoX83mAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-20T00:28:09.343947Z"},"content_sha256":"4c014bfc834d758d2bf838c59e9fb533c170600d2b5f7d3d317469814c70fea9","schema_version":"1.0","event_id":"sha256:4c014bfc834d758d2bf838c59e9fb533c170600d2b5f7d3d317469814c70fea9"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2014:3DYNDD2AF3KOWDM3TAPORUWY3R","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Valence-bond Non-equilibrium Solvation Model for a Twisting Monomethine Cyanine","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Ross H. McKenzie, Sean McConnell, Seth Olsen","submitted_at":"2014-10-29T03:08:18Z","abstract_excerpt":"We propose and analyze a two-state valence-bond model of non-equilibrium solvation effects on the excited-state twisting reaction of monomethine cyanines. Suppression of this reaction is thought responsible for environment-dependent fluorescence yield enhancement in these dyes. Fluorescence is quenched because twisting is accompanied via the formation of dark twisted intramolecular charge-transfer (TICT) states. For monomethine cyanines, where the ground state is a superposition of structures with different bond and charge localization, there are two possible twisting pathways with different c"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1410.7866","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:00:20Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"fhJF1VkkF0nC5sj/DpBZcVkdzJR8yYY+uzZ1VbYGcnYIxiQjOB8u5+FkdHQxu1x3bY1OHrywRKX3OKI4B+0QDw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-20T00:28:09.344485Z"},"content_sha256":"047aae771da1b0f787234c60a233a4fcda6489a34894098c04f8c6816bd629c8","schema_version":"1.0","event_id":"sha256:047aae771da1b0f787234c60a233a4fcda6489a34894098c04f8c6816bd629c8"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/bundle.json","state_url":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-20T00:28:09Z","links":{"resolver":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R","bundle":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/bundle.json","state":"https://pith.science/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/state.json","well_known_bundle":"https://pith.science/.well-known/pith/3DYNDD2AF3KOWDM3TAPORUWY3R/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2014:3DYNDD2AF3KOWDM3TAPORUWY3R","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"3b6a667e86f312ad3487cd91cae37bacefac6c8b3f043c858a55647883926428","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","title_canon_sha256":"9ebb58dfde293b345fb1e8a53262076197404b5424a54beaa5f58a3f896117ca"},"schema_version":"1.0","source":{"id":"1410.7866","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1410.7866","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"arxiv_version","alias_value":"1410.7866v2","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1410.7866","created_at":"2026-05-18T01:00:20Z"},{"alias_kind":"pith_short_12","alias_value":"3DYNDD2AF3KO","created_at":"2026-05-18T12:28:11Z"},{"alias_kind":"pith_short_16","alias_value":"3DYNDD2AF3KOWDM3","created_at":"2026-05-18T12:28:11Z"},{"alias_kind":"pith_short_8","alias_value":"3DYNDD2A","created_at":"2026-05-18T12:28:11Z"}],"graph_snapshots":[{"event_id":"sha256:047aae771da1b0f787234c60a233a4fcda6489a34894098c04f8c6816bd629c8","target":"graph","created_at":"2026-05-18T01:00:20Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We propose and analyze a two-state valence-bond model of non-equilibrium solvation effects on the excited-state twisting reaction of monomethine cyanines. Suppression of this reaction is thought responsible for environment-dependent fluorescence yield enhancement in these dyes. Fluorescence is quenched because twisting is accompanied via the formation of dark twisted intramolecular charge-transfer (TICT) states. For monomethine cyanines, where the ground state is a superposition of structures with different bond and charge localization, there are two possible twisting pathways with different c","authors_text":"Ross H. McKenzie, Sean McConnell, Seth Olsen","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","title":"Valence-bond Non-equilibrium Solvation Model for a Twisting Monomethine Cyanine"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1410.7866","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:4c014bfc834d758d2bf838c59e9fb533c170600d2b5f7d3d317469814c70fea9","target":"record","created_at":"2026-05-18T01:00:20Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"3b6a667e86f312ad3487cd91cae37bacefac6c8b3f043c858a55647883926428","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-10-29T03:08:18Z","title_canon_sha256":"9ebb58dfde293b345fb1e8a53262076197404b5424a54beaa5f58a3f896117ca"},"schema_version":"1.0","source":{"id":"1410.7866","kind":"arxiv","version":2}},"canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"d8f0d18f402ed4eb0d9b981ee8d2d8dc6198a7148d93b70cfa3ed26459dbe676","first_computed_at":"2026-05-18T01:00:20.135788Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:00:20.135788Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"ZVMHs/lPNIeeDWoyENVesYl8XkqifmO0hj0iFqoemy1fD/4XT6Ddg6GQC22sh9K9Z4h37d0hx1bEUg5V6Hg9Bg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:00:20.136432Z","signed_message":"canonical_sha256_bytes"},"source_id":"1410.7866","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:4c014bfc834d758d2bf838c59e9fb533c170600d2b5f7d3d317469814c70fea9","sha256:047aae771da1b0f787234c60a233a4fcda6489a34894098c04f8c6816bd629c8"],"state_sha256":"4b5cb169c424af6f77cd90a32d209b503837981a64f37cfe5367db96da51f54b"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"nX4vL10I38gFNcdbcAVgpXrYnytj7rTue/6X0d2aRa8ajrRNcNyJzeS13A5HC9pF4XaSpRNBDFMFLCWG3zE/Bw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-20T00:28:09.350454Z","bundle_sha256":"795daeb65cd0b6461ec805385914d78f5a017d8340cc951fb08a2142e2e71c51"}}