{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:3SEJET7CAVPKTBYOFOGFQGNYT3","short_pith_number":"pith:3SEJET7C","canonical_record":{"source":{"id":"1608.05330","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-08-18T16:50:52Z","cross_cats_sorted":["cond-mat.mtrl-sci"],"title_canon_sha256":"4eecde3c81e3e8637d61b9bd603eee7821fe590fd039cd8fd4772f0dbfb0f267","abstract_canon_sha256":"3133b6425280bb60213ffdece4d89635aa039fe5330134ea89834e44213c12fe"},"schema_version":"1.0"},"canonical_sha256":"dc88924fe2055ea9870e2b8c5819b89edd6aab68886cb7fc05d0590caa1b4815","source":{"kind":"arxiv","id":"1608.05330","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1608.05330","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"arxiv_version","alias_value":"1608.05330v1","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1608.05330","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"pith_short_12","alias_value":"3SEJET7CAVPK","created_at":"2026-05-18T12:29:58Z"},{"alias_kind":"pith_short_16","alias_value":"3SEJET7CAVPKTBYO","created_at":"2026-05-18T12:29:58Z"},{"alias_kind":"pith_short_8","alias_value":"3SEJET7C","created_at":"2026-05-18T12:29:58Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:3SEJET7CAVPKTBYOFOGFQGNYT3","target":"record","payload":{"canonical_record":{"source":{"id":"1608.05330","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-08-18T16:50:52Z","cross_cats_sorted":["cond-mat.mtrl-sci"],"title_canon_sha256":"4eecde3c81e3e8637d61b9bd603eee7821fe590fd039cd8fd4772f0dbfb0f267","abstract_canon_sha256":"3133b6425280bb60213ffdece4d89635aa039fe5330134ea89834e44213c12fe"},"schema_version":"1.0"},"canonical_sha256":"dc88924fe2055ea9870e2b8c5819b89edd6aab68886cb7fc05d0590caa1b4815","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:52:49.774431Z","signature_b64":"yP/bRuqVOXspn/8OxNuMqa0QyFjyDKf530tTNC+29LHbXsa91d/stlBVrqCqcdhIZKDlrKUaDc14akECnCY9BQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"dc88924fe2055ea9870e2b8c5819b89edd6aab68886cb7fc05d0590caa1b4815","last_reissued_at":"2026-05-18T00:52:49.773727Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:52:49.773727Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1608.05330","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:52:49Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"myAwEptZkHyDHeEa6ZMo9PvjKrV0KuyX4srKuF+rXttpR1em6y3uhtVBd5oJNfhv/97jJsFMd3YVMH39+P47Dg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-11T06:42:04.324084Z"},"content_sha256":"44210f15700be4e8a4213739a12eb890da3bf4c7081de1a15ffe3ee0903b7046","schema_version":"1.0","event_id":"sha256:44210f15700be4e8a4213739a12eb890da3bf4c7081de1a15ffe3ee0903b7046"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:3SEJET7CAVPKTBYOFOGFQGNYT3","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Exotic Spin-Orbital Physics in Hybrid Oxides","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mtrl-sci"],"primary_cat":"cond-mat.str-el","authors_text":"Andrzej M. Ole\\'s, Mario Cuoco, Wojciech Brzezicki","submitted_at":"2016-08-18T16:50:52Z","abstract_excerpt":"We compare the effective spin-orbital super\\-exchange triggered by magnetic $3d$ impurities with $d^3$ and $d^2$ configurations and either no orbital degree of freedom (orbital dilution) or hole replacing a doublon (charge dilution) in a $4d^4$ Mott insulator with $S=1$ spins. Impurities causing orbital dilution act either as spin defects decoupled from the surrounding ions, or generate orbital polarons along $d^3$-$d^4$ hybrid bonds. The exchange on these bonds determines which orbital is occupied by a doublon on the host site. In case of charge dilution by $3d^2$ impurities additional $\\prop"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1608.05330","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:52:49Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"3pxHU6ADeJHrL4J5qiRDXKSPF8U+jIMTUedusoOSzzP/S6bmDyLcpD36H8Fr1e2jvdTLksjUk18h8feruZbFCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-11T06:42:04.324842Z"},"content_sha256":"5a9da59f14a5c554d778150b894432e3883ea1d0449577307210d9f574299744","schema_version":"1.0","event_id":"sha256:5a9da59f14a5c554d778150b894432e3883ea1d0449577307210d9f574299744"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/bundle.json","state_url":"https://pith.science/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-11T06:42:04Z","links":{"resolver":"https://pith.science/pith/3SEJET7CAVPKTBYOFOGFQGNYT3","bundle":"https://pith.science/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/bundle.json","state":"https://pith.science/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/state.json","well_known_bundle":"https://pith.science/.well-known/pith/3SEJET7CAVPKTBYOFOGFQGNYT3/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:3SEJET7CAVPKTBYOFOGFQGNYT3","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"3133b6425280bb60213ffdece4d89635aa039fe5330134ea89834e44213c12fe","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-08-18T16:50:52Z","title_canon_sha256":"4eecde3c81e3e8637d61b9bd603eee7821fe590fd039cd8fd4772f0dbfb0f267"},"schema_version":"1.0","source":{"id":"1608.05330","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1608.05330","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"arxiv_version","alias_value":"1608.05330v1","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1608.05330","created_at":"2026-05-18T00:52:49Z"},{"alias_kind":"pith_short_12","alias_value":"3SEJET7CAVPK","created_at":"2026-05-18T12:29:58Z"},{"alias_kind":"pith_short_16","alias_value":"3SEJET7CAVPKTBYO","created_at":"2026-05-18T12:29:58Z"},{"alias_kind":"pith_short_8","alias_value":"3SEJET7C","created_at":"2026-05-18T12:29:58Z"}],"graph_snapshots":[{"event_id":"sha256:5a9da59f14a5c554d778150b894432e3883ea1d0449577307210d9f574299744","target":"graph","created_at":"2026-05-18T00:52:49Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We compare the effective spin-orbital super\\-exchange triggered by magnetic $3d$ impurities with $d^3$ and $d^2$ configurations and either no orbital degree of freedom (orbital dilution) or hole replacing a doublon (charge dilution) in a $4d^4$ Mott insulator with $S=1$ spins. Impurities causing orbital dilution act either as spin defects decoupled from the surrounding ions, or generate orbital polarons along $d^3$-$d^4$ hybrid bonds. The exchange on these bonds determines which orbital is occupied by a doublon on the host site. In case of charge dilution by $3d^2$ impurities additional $\\prop","authors_text":"Andrzej M. Ole\\'s, Mario Cuoco, Wojciech Brzezicki","cross_cats":["cond-mat.mtrl-sci"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-08-18T16:50:52Z","title":"Exotic Spin-Orbital Physics in Hybrid Oxides"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1608.05330","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:44210f15700be4e8a4213739a12eb890da3bf4c7081de1a15ffe3ee0903b7046","target":"record","created_at":"2026-05-18T00:52:49Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"3133b6425280bb60213ffdece4d89635aa039fe5330134ea89834e44213c12fe","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-08-18T16:50:52Z","title_canon_sha256":"4eecde3c81e3e8637d61b9bd603eee7821fe590fd039cd8fd4772f0dbfb0f267"},"schema_version":"1.0","source":{"id":"1608.05330","kind":"arxiv","version":1}},"canonical_sha256":"dc88924fe2055ea9870e2b8c5819b89edd6aab68886cb7fc05d0590caa1b4815","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"dc88924fe2055ea9870e2b8c5819b89edd6aab68886cb7fc05d0590caa1b4815","first_computed_at":"2026-05-18T00:52:49.773727Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:52:49.773727Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"yP/bRuqVOXspn/8OxNuMqa0QyFjyDKf530tTNC+29LHbXsa91d/stlBVrqCqcdhIZKDlrKUaDc14akECnCY9BQ==","signature_status":"signed_v1","signed_at":"2026-05-18T00:52:49.774431Z","signed_message":"canonical_sha256_bytes"},"source_id":"1608.05330","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:44210f15700be4e8a4213739a12eb890da3bf4c7081de1a15ffe3ee0903b7046","sha256:5a9da59f14a5c554d778150b894432e3883ea1d0449577307210d9f574299744"],"state_sha256":"d69b475ecff9e46e4c45bcf4800997968c905573a9c5f73f313675c2e511e23a"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"jk/mM8WiLIFtVrnY20rN3ZMhY5FDGCgHjsxa0A6Qk+g6JojZa9hUEiNldv4XYlh6lgck9o0nexFgLPd8DsMzAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-11T06:42:04.328619Z","bundle_sha256":"9a5cdd056c91bc478f1d8c4fb564181099df0d6e2bad2859c7050b15fb9fcd37"}}