{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2022:4HD7LBCBM6CLYCBMZPYZ64RG42","short_pith_number":"pith:4HD7LBCB","schema_version":"1.0","canonical_sha256":"e1c7f584416784bc082ccbf19f7226e6bbc3bcad2f3e804daf2f05e37138a9a5","source":{"kind":"arxiv","id":"2205.05142","version":1},"attestation_state":"computed","paper":{"title":"Resonant Cavity Modification of Ground State Chemical Kinetics","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.other","quant-ph"],"primary_cat":"physics.chem-ph","authors_text":"Arkajit Mandal, David R. Reichman, Lachlan P. Lindoy","submitted_at":"2022-05-10T19:50:15Z","abstract_excerpt":"Recent experiments have suggested that ground state chemical kinetics can be suppressed or enhanced by coupling the vibrational degrees of freedom of a molecular system with a radiation mode inside an optical cavity. Experiments show that the chemical rate is strongly modified when the photon frequency is close to characteristic vibrational frequencies. The origin of this remarkable effect remains unknown. In this work, we develop an analytical rate theory for cavity-modified ground state chemical kinetics based on the Pollak-Grabert-H\\\"anggi rate theory. Unlike previous work, our theory cover"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2205.05142","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2022-05-10T19:50:15Z","cross_cats_sorted":["cond-mat.other","quant-ph"],"title_canon_sha256":"85092d3f9525df94873adceb00dae3591acfee19402c1ec0544cf24f2f6f45c9","abstract_canon_sha256":"d7f5c3abf5ec6d75c80dd29f306e1b08e5ff5c0bdc6360d26d46c7159b554147"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:43:01.774273Z","signature_b64":"mO2JGcbJe3/efxeZ6K6+7bhm3KNF3Pf7kXpBsaGbeNzPY9Zgf1Es0CIeHDTUycbAcvLcDgA5X2DGu37TQ3B0Bg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e1c7f584416784bc082ccbf19f7226e6bbc3bcad2f3e804daf2f05e37138a9a5","last_reissued_at":"2026-07-05T04:43:01.773845Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:43:01.773845Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Resonant Cavity Modification of Ground State Chemical Kinetics","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.other","quant-ph"],"primary_cat":"physics.chem-ph","authors_text":"Arkajit Mandal, David R. Reichman, Lachlan P. Lindoy","submitted_at":"2022-05-10T19:50:15Z","abstract_excerpt":"Recent experiments have suggested that ground state chemical kinetics can be suppressed or enhanced by coupling the vibrational degrees of freedom of a molecular system with a radiation mode inside an optical cavity. Experiments show that the chemical rate is strongly modified when the photon frequency is close to characteristic vibrational frequencies. The origin of this remarkable effect remains unknown. In this work, we develop an analytical rate theory for cavity-modified ground state chemical kinetics based on the Pollak-Grabert-H\\\"anggi rate theory. Unlike previous work, our theory cover"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2205.05142","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2205.05142/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2205.05142","created_at":"2026-07-05T04:43:01.773908+00:00"},{"alias_kind":"arxiv_version","alias_value":"2205.05142v1","created_at":"2026-07-05T04:43:01.773908+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2205.05142","created_at":"2026-07-05T04:43:01.773908+00:00"},{"alias_kind":"pith_short_12","alias_value":"4HD7LBCBM6CL","created_at":"2026-07-05T04:43:01.773908+00:00"},{"alias_kind":"pith_short_16","alias_value":"4HD7LBCBM6CLYCBM","created_at":"2026-07-05T04:43:01.773908+00:00"},{"alias_kind":"pith_short_8","alias_value":"4HD7LBCB","created_at":"2026-07-05T04:43:01.773908+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42","json":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42.json","graph_json":"https://pith.science/api/pith-number/4HD7LBCBM6CLYCBMZPYZ64RG42/graph.json","events_json":"https://pith.science/api/pith-number/4HD7LBCBM6CLYCBMZPYZ64RG42/events.json","paper":"https://pith.science/paper/4HD7LBCB"},"agent_actions":{"view_html":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42","download_json":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42.json","view_paper":"https://pith.science/paper/4HD7LBCB","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2205.05142&json=true","fetch_graph":"https://pith.science/api/pith-number/4HD7LBCBM6CLYCBMZPYZ64RG42/graph.json","fetch_events":"https://pith.science/api/pith-number/4HD7LBCBM6CLYCBMZPYZ64RG42/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42/action/timestamp_anchor","attest_storage":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42/action/storage_attestation","attest_author":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42/action/author_attestation","sign_citation":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42/action/citation_signature","submit_replication":"https://pith.science/pith/4HD7LBCBM6CLYCBMZPYZ64RG42/action/replication_record"}},"created_at":"2026-07-05T04:43:01.773908+00:00","updated_at":"2026-07-05T04:43:01.773908+00:00"}