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Using density functional theory with the PBEsol$+U$ approach, we describe a novel octahedral engineering avenue to control the $B$ 3d and O $2p$ orbital polarization through enhancement of the $B$O$_6$ rotation \"sense\" rather than solely through conventional changes to t"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1304.0982","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-03T15:21:52Z","cross_cats_sorted":[],"title_canon_sha256":"c824a104fe0cdf2fc3fdff9b0f69989216acf7a0ff5bcfe6b78d4e728177fecc","abstract_canon_sha256":"773319716503548aa275a6822e49a1578494ffc71825223af7fe1aefae5053ed"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:50:43.513577Z","signature_b64":"lvqnLIegHWvXtL8ROQGYdRFIWuFMWtrJTskl29T33FkqPHBUbzjOKQPDJlbB3DaDGejwTm10+rd9VYA9rh5mBw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e46d36aa6f2a79fe59235b96536ea6f18fb39118f975c0881900eba0895c9b19","last_reissued_at":"2026-05-18T01:50:43.512869Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:50:43.512869Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Octahedral Engineering of Orbital Polarizations in Charge Transfer Oxides","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Antonio Cammarata, James M. 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