{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2013:4T5MXIPBQ466IOIQKDC3W4INZK","short_pith_number":"pith:4T5MXIPB","canonical_record":{"source":{"id":"1304.5116","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-18T13:10:12Z","cross_cats_sorted":[],"title_canon_sha256":"798415a82597f68ea1dbb55642debb78ec9ad88ca5b126eefc7679cff952cda1","abstract_canon_sha256":"7e67094bf5fb6e13bcf302e427b1be535748a5e894617ff1e688093a99edade3"},"schema_version":"1.0"},"canonical_sha256":"e4facba1e1873de4391050c5bb710dca9404695a9c1aa2c9e40423b3695d2503","source":{"kind":"arxiv","id":"1304.5116","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1304.5116","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"arxiv_version","alias_value":"1304.5116v1","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1304.5116","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"pith_short_12","alias_value":"4T5MXIPBQ466","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_16","alias_value":"4T5MXIPBQ466IOIQ","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_8","alias_value":"4T5MXIPB","created_at":"2026-05-18T12:27:34Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2013:4T5MXIPBQ466IOIQKDC3W4INZK","target":"record","payload":{"canonical_record":{"source":{"id":"1304.5116","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-18T13:10:12Z","cross_cats_sorted":[],"title_canon_sha256":"798415a82597f68ea1dbb55642debb78ec9ad88ca5b126eefc7679cff952cda1","abstract_canon_sha256":"7e67094bf5fb6e13bcf302e427b1be535748a5e894617ff1e688093a99edade3"},"schema_version":"1.0"},"canonical_sha256":"e4facba1e1873de4391050c5bb710dca9404695a9c1aa2c9e40423b3695d2503","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T03:14:19.611942Z","signature_b64":"bQteDGwL/sgL+KoQnCdgJVjyLUfu/QdbbZvvwUvQjpg9RuM2AR23YP9LzKlopmmBtGjI7ztnP7WO30JWc0frBg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e4facba1e1873de4391050c5bb710dca9404695a9c1aa2c9e40423b3695d2503","last_reissued_at":"2026-05-18T03:14:19.611299Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T03:14:19.611299Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1304.5116","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:14:19Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Umm1+6Pa6+bpN/z7kUU42QuSR89m68VfRSmZBeGrGZvVdVopZESeED0NjvS25dOA68Xr6yAy155oz5VZ83sOBQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-25T16:25:31.691923Z"},"content_sha256":"694614de9bdea69a3b486056f736b88255f44b3543a3f36176ea3aac635c8341","schema_version":"1.0","event_id":"sha256:694614de9bdea69a3b486056f736b88255f44b3543a3f36176ea3aac635c8341"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2013:4T5MXIPBQ466IOIQKDC3W4INZK","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Experimental evidence for the coupling of Li-motion and structural distortions in LiMnPO$_4$","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Bernd B\\\"uchner, Christian Rudisch, Hans-Joachim Grafe, Jochen Geck, M. v. Zimmermann, Nadja Wizent, R\\\"udiger Klingeler, Sven Partzsch","submitted_at":"2013-04-18T13:10:12Z","abstract_excerpt":"We present a detailed $^7$Li- and $^{31}$P-NMR study on single crystalline LiMnPO$_4$ in the paramagnetic and antiferromagnetic phase (AFM, $T_N \\sim$ 34 K). This allows us to determine the spin directions in the field-induced spin-flop phase. In addition, the anisotropic dipolar hyperfine coupling tensor of the $^7$Li- and $^{31}$P-nuclei is also fully determined by orientation and temperature dependent NMR experiments and compared to the calculated values from crystal structure data. Deviations of the experimental values from the theoretical ones are discussed in terms of Mn disorder which i"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1304.5116","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:14:19Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"0AN6YEtzVvAByERenTFilz20A3jmJPgenK+ZTTk7YfSIAF/N70RsnDMm+2/pGY4zxf2KjUjjTC8qP+eAjDyxCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-25T16:25:31.692581Z"},"content_sha256":"073fa55adb0eeb6bd3849197a44dedf8883ae1c3bf8f101f9159acb53b0a2b5a","schema_version":"1.0","event_id":"sha256:073fa55adb0eeb6bd3849197a44dedf8883ae1c3bf8f101f9159acb53b0a2b5a"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/4T5MXIPBQ466IOIQKDC3W4INZK/bundle.json","state_url":"https://pith.science/pith/4T5MXIPBQ466IOIQKDC3W4INZK/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/4T5MXIPBQ466IOIQKDC3W4INZK/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-25T16:25:31Z","links":{"resolver":"https://pith.science/pith/4T5MXIPBQ466IOIQKDC3W4INZK","bundle":"https://pith.science/pith/4T5MXIPBQ466IOIQKDC3W4INZK/bundle.json","state":"https://pith.science/pith/4T5MXIPBQ466IOIQKDC3W4INZK/state.json","well_known_bundle":"https://pith.science/.well-known/pith/4T5MXIPBQ466IOIQKDC3W4INZK/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2013:4T5MXIPBQ466IOIQKDC3W4INZK","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"7e67094bf5fb6e13bcf302e427b1be535748a5e894617ff1e688093a99edade3","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-18T13:10:12Z","title_canon_sha256":"798415a82597f68ea1dbb55642debb78ec9ad88ca5b126eefc7679cff952cda1"},"schema_version":"1.0","source":{"id":"1304.5116","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1304.5116","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"arxiv_version","alias_value":"1304.5116v1","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1304.5116","created_at":"2026-05-18T03:14:19Z"},{"alias_kind":"pith_short_12","alias_value":"4T5MXIPBQ466","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_16","alias_value":"4T5MXIPBQ466IOIQ","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_8","alias_value":"4T5MXIPB","created_at":"2026-05-18T12:27:34Z"}],"graph_snapshots":[{"event_id":"sha256:073fa55adb0eeb6bd3849197a44dedf8883ae1c3bf8f101f9159acb53b0a2b5a","target":"graph","created_at":"2026-05-18T03:14:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We present a detailed $^7$Li- and $^{31}$P-NMR study on single crystalline LiMnPO$_4$ in the paramagnetic and antiferromagnetic phase (AFM, $T_N \\sim$ 34 K). This allows us to determine the spin directions in the field-induced spin-flop phase. In addition, the anisotropic dipolar hyperfine coupling tensor of the $^7$Li- and $^{31}$P-nuclei is also fully determined by orientation and temperature dependent NMR experiments and compared to the calculated values from crystal structure data. Deviations of the experimental values from the theoretical ones are discussed in terms of Mn disorder which i","authors_text":"Bernd B\\\"uchner, Christian Rudisch, Hans-Joachim Grafe, Jochen Geck, M. v. Zimmermann, Nadja Wizent, R\\\"udiger Klingeler, Sven Partzsch","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-18T13:10:12Z","title":"Experimental evidence for the coupling of Li-motion and structural distortions in LiMnPO$_4$"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1304.5116","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:694614de9bdea69a3b486056f736b88255f44b3543a3f36176ea3aac635c8341","target":"record","created_at":"2026-05-18T03:14:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"7e67094bf5fb6e13bcf302e427b1be535748a5e894617ff1e688093a99edade3","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-04-18T13:10:12Z","title_canon_sha256":"798415a82597f68ea1dbb55642debb78ec9ad88ca5b126eefc7679cff952cda1"},"schema_version":"1.0","source":{"id":"1304.5116","kind":"arxiv","version":1}},"canonical_sha256":"e4facba1e1873de4391050c5bb710dca9404695a9c1aa2c9e40423b3695d2503","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"e4facba1e1873de4391050c5bb710dca9404695a9c1aa2c9e40423b3695d2503","first_computed_at":"2026-05-18T03:14:19.611299Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:14:19.611299Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"bQteDGwL/sgL+KoQnCdgJVjyLUfu/QdbbZvvwUvQjpg9RuM2AR23YP9LzKlopmmBtGjI7ztnP7WO30JWc0frBg==","signature_status":"signed_v1","signed_at":"2026-05-18T03:14:19.611942Z","signed_message":"canonical_sha256_bytes"},"source_id":"1304.5116","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:694614de9bdea69a3b486056f736b88255f44b3543a3f36176ea3aac635c8341","sha256:073fa55adb0eeb6bd3849197a44dedf8883ae1c3bf8f101f9159acb53b0a2b5a"],"state_sha256":"84788d80265c5a6e1137d27da76230ab682b299f06b00f6734531cc65761e8dd"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Tr/oDBvpyE3O74H0DC+BxDPt9t3Kubs6vBlw2PLn6FRmEEuy82tAm8sEBXQRhKz/ycY27cNlJP3+R4AW+cfXDg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-25T16:25:31.696075Z","bundle_sha256":"4cf30cba6bd228ed416336b442a0cf4f09068901d17222834e4c94424ce96bc3"}}