{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2026:5AB42U52HHRT3KPC3RN4P55M3F","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"9d12b54ac4a5f03c45311c06be8c1fdd1f4fcd967134befd6526f1a13342f1c6","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2026-08-05T10:58:49Z","title_canon_sha256":"449ffa536f4227b1dc3fff799f82b485946c1c1783ad4d339af8b7139ac4f38a"},"schema_version":"1.0","source":{"id":"2608.04690","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2608.04690","created_at":"2026-08-06T01:46:30Z"},{"alias_kind":"arxiv_version","alias_value":"2608.04690v1","created_at":"2026-08-06T01:46:30Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2608.04690","created_at":"2026-08-06T01:46:30Z"},{"alias_kind":"pith_short_12","alias_value":"5AB42U52HHRT","created_at":"2026-08-06T01:46:30Z"},{"alias_kind":"pith_short_16","alias_value":"5AB42U52HHRT3KPC","created_at":"2026-08-06T01:46:30Z"},{"alias_kind":"pith_short_8","alias_value":"5AB42U52","created_at":"2026-08-06T01:46:30Z"}],"graph_snapshots":[{"event_id":"sha256:46fd649628167be4f8ab50425528fe10975a4e1f84524ead83cddd56f9312521","target":"graph","created_at":"2026-08-06T01:46:30Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2608.04690/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Lithium lanthanum zirconate (LLZO) garnets are among the most promising solid electrolytes for next-generation batteries owing to their high ionic conductivity, chemical stability, and compatibility with lithium metal. Raman spectroscopy is commonly employed to distinguish the highly conductive cubic phase from the poorly conductive tetragonal phase of LLZO, yet the atomistic origin of these spectral differences and their direct connection to Li-ion transport remain unresolved. Here, we close this gap by comparing computed and experimental Raman spectra for the tetragonal, cubic, and Ta-doped ","authors_text":"David A. Egger, Hyunwon Chu, Jennifer L.M. Rupp, Manuel Grumet, Takeru Miyagawa, Waldemar Kaiser, Willis O'Leary","cross_cats":[],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2026-08-05T10:58:49Z","title":"Raman Signatures of Lithium Ion Dynamics in LLZO Garnet Electrolytes: Atomistic Insights from MD-Raman Calculations"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2608.04690","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:b072dd754344cb85448ebbfea30c0b5749c8285a4ce735c946193e66d936b4b6","target":"record","created_at":"2026-08-06T01:46:30Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"9d12b54ac4a5f03c45311c06be8c1fdd1f4fcd967134befd6526f1a13342f1c6","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2026-08-05T10:58:49Z","title_canon_sha256":"449ffa536f4227b1dc3fff799f82b485946c1c1783ad4d339af8b7139ac4f38a"},"schema_version":"1.0","source":{"id":"2608.04690","kind":"arxiv","version":1}},"canonical_sha256":"e803cd53ba39e33da9e2dc5bc7f7acd96209d2e54b575a122cab117502195f03","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"e803cd53ba39e33da9e2dc5bc7f7acd96209d2e54b575a122cab117502195f03","first_computed_at":"2026-08-06T01:46:30.644311Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-08-06T01:46:30.644311Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"as4D9+k52xibXLl1WCJoLrGThqsS6+Yo3SPOC8uVTw/y8+2IEaW5mAx48Py4gCaFQysq9m/6pRujKmr3MAaqAg==","signature_status":"signed_v1","signed_at":"2026-08-06T01:46:30.645737Z","signed_message":"canonical_sha256_bytes"},"source_id":"2608.04690","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:b072dd754344cb85448ebbfea30c0b5749c8285a4ce735c946193e66d936b4b6","sha256:46fd649628167be4f8ab50425528fe10975a4e1f84524ead83cddd56f9312521"],"state_sha256":"a579dae4bc7f3438a2f2b20e5cad8dea8645a7d56894dd1cbe459c51e18d0647"}