{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2021:5CSLQ23AW3LLMXN2TH5J73RC5S","short_pith_number":"pith:5CSLQ23A","schema_version":"1.0","canonical_sha256":"e8a4b86b60b6d6b65dba99fa9fee22ec894e1fe6925e41c2ae16eba5f3ed23c2","source":{"kind":"arxiv","id":"2112.05852","version":1},"attestation_state":"computed","paper":{"title":"Synthesis and crystal growth of novel layered bismuthides ATM2Bi2, (A = K, Rb; TM = Zn, Cd) with significant electron-deficient structure","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":["cond-mat.str-el"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Andrey Shilov, Bernd B\\\"uchner, Dmitri Efremov, Igor Morozov, Kirill Pervakov, Konstantin Lyssenko, Saicharan Aswartham, Vladimir Vlasenko","submitted_at":"2021-12-10T22:11:15Z","abstract_excerpt":"Layered bismuthides of the family ATM2Bi2 are showing very interesting structural and physical properties. Here, we report crystal growth and characterization of new ternary layered bismuthides: RbCd2Bi2, RbZn2Bi2 and KZn2Bi2. Single crystals were grown by self-flux technique. As grown crystals were characterized by combination of powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy and single crystal X-ray diffraction. All novel compounds crystallize in layered ThCr2Si2 structure type with plate-like morphology with weak bonding between layers. Signific"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2112.05852","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2021-12-10T22:11:15Z","cross_cats_sorted":["cond-mat.str-el"],"title_canon_sha256":"943d154b513f2e92156919d63e09908dcf69f6bdcd8d2ec1fd3cffca5083c748","abstract_canon_sha256":"d383e1e4dd959ad4131db3eeb10b9f8490808c9b5cf6f7a0b0cbad73b96caa26"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T03:40:07.614676Z","signature_b64":"rc0b8bWiEhfGaTMqxwdqDA0NTFg7jSdaYcD23m8RYMeYesW2wPglfOVJNJhRML8rcKSpLppk51XjyF7ASfdABQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e8a4b86b60b6d6b65dba99fa9fee22ec894e1fe6925e41c2ae16eba5f3ed23c2","last_reissued_at":"2026-07-05T03:40:07.614219Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T03:40:07.614219Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Synthesis and crystal growth of novel layered bismuthides ATM2Bi2, (A = K, Rb; TM = Zn, Cd) with significant electron-deficient structure","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":["cond-mat.str-el"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Andrey Shilov, Bernd B\\\"uchner, Dmitri Efremov, Igor Morozov, Kirill Pervakov, Konstantin Lyssenko, Saicharan Aswartham, Vladimir Vlasenko","submitted_at":"2021-12-10T22:11:15Z","abstract_excerpt":"Layered bismuthides of the family ATM2Bi2 are showing very interesting structural and physical properties. Here, we report crystal growth and characterization of new ternary layered bismuthides: RbCd2Bi2, RbZn2Bi2 and KZn2Bi2. Single crystals were grown by self-flux technique. As grown crystals were characterized by combination of powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy and single crystal X-ray diffraction. All novel compounds crystallize in layered ThCr2Si2 structure type with plate-like morphology with weak bonding between layers. Signific"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2112.05852","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2112.05852/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2112.05852","created_at":"2026-07-05T03:40:07.614274+00:00"},{"alias_kind":"arxiv_version","alias_value":"2112.05852v1","created_at":"2026-07-05T03:40:07.614274+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2112.05852","created_at":"2026-07-05T03:40:07.614274+00:00"},{"alias_kind":"pith_short_12","alias_value":"5CSLQ23AW3LL","created_at":"2026-07-05T03:40:07.614274+00:00"},{"alias_kind":"pith_short_16","alias_value":"5CSLQ23AW3LLMXN2","created_at":"2026-07-05T03:40:07.614274+00:00"},{"alias_kind":"pith_short_8","alias_value":"5CSLQ23A","created_at":"2026-07-05T03:40:07.614274+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S","json":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S.json","graph_json":"https://pith.science/api/pith-number/5CSLQ23AW3LLMXN2TH5J73RC5S/graph.json","events_json":"https://pith.science/api/pith-number/5CSLQ23AW3LLMXN2TH5J73RC5S/events.json","paper":"https://pith.science/paper/5CSLQ23A"},"agent_actions":{"view_html":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S","download_json":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S.json","view_paper":"https://pith.science/paper/5CSLQ23A","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2112.05852&json=true","fetch_graph":"https://pith.science/api/pith-number/5CSLQ23AW3LLMXN2TH5J73RC5S/graph.json","fetch_events":"https://pith.science/api/pith-number/5CSLQ23AW3LLMXN2TH5J73RC5S/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S/action/timestamp_anchor","attest_storage":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S/action/storage_attestation","attest_author":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S/action/author_attestation","sign_citation":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S/action/citation_signature","submit_replication":"https://pith.science/pith/5CSLQ23AW3LLMXN2TH5J73RC5S/action/replication_record"}},"created_at":"2026-07-05T03:40:07.614274+00:00","updated_at":"2026-07-05T03:40:07.614274+00:00"}