{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2013:5DOZSLH64UYVWAFTS2I6S6WVHB","short_pith_number":"pith:5DOZSLH6","canonical_record":{"source":{"id":"1303.1291","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-03-06T10:31:03Z","cross_cats_sorted":[],"title_canon_sha256":"701e4c539954856bbebd3709f34a6466fc91d2f1fd784dfe466b34ede3e81a41","abstract_canon_sha256":"5c6bf30ff7261fd8a7e0dba780bf0528051b005dcb28f92089fec60b4c2f3b13"},"schema_version":"1.0"},"canonical_sha256":"e8dd992cfee5315b00b39691e97ad5386b30d67ecedc6ee35a950416b3b58636","source":{"kind":"arxiv","id":"1303.1291","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1303.1291","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"arxiv_version","alias_value":"1303.1291v1","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1303.1291","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"pith_short_12","alias_value":"5DOZSLH64UYV","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_16","alias_value":"5DOZSLH64UYVWAFT","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_8","alias_value":"5DOZSLH6","created_at":"2026-05-18T12:27:34Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2013:5DOZSLH64UYVWAFTS2I6S6WVHB","target":"record","payload":{"canonical_record":{"source":{"id":"1303.1291","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-03-06T10:31:03Z","cross_cats_sorted":[],"title_canon_sha256":"701e4c539954856bbebd3709f34a6466fc91d2f1fd784dfe466b34ede3e81a41","abstract_canon_sha256":"5c6bf30ff7261fd8a7e0dba780bf0528051b005dcb28f92089fec60b4c2f3b13"},"schema_version":"1.0"},"canonical_sha256":"e8dd992cfee5315b00b39691e97ad5386b30d67ecedc6ee35a950416b3b58636","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T03:31:43.933991Z","signature_b64":"Ykkp6gYZ+sfnUEBnzRJXN+wFUrl4JHJvaUFX4y/2TJIY5/ZTObCP4BgsREzyQ57v9nWUI7FNZ8Sx2f2Fk0AbCQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e8dd992cfee5315b00b39691e97ad5386b30d67ecedc6ee35a950416b3b58636","last_reissued_at":"2026-05-18T03:31:43.933087Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T03:31:43.933087Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1303.1291","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:31:43Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"2wBayPVrDpvggnifdCjD1Wth4P2GK5ZdQSvHCZRclbcuKUA5svOtBF+tBiO5aMNAq9l4a3/tcFbi6pZJ871gAw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T19:06:41.874387Z"},"content_sha256":"334e43d6fb62107335ade9ec5cc44d289cf6007b4ac92e4420971fdb0f7148e4","schema_version":"1.0","event_id":"sha256:334e43d6fb62107335ade9ec5cc44d289cf6007b4ac92e4420971fdb0f7148e4"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2013:5DOZSLH64UYVWAFTS2I6S6WVHB","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Sharp Raman Anomalies and Broken Adiabaticity at a Pressure Induced Transition from Band to Topological Insulator in Sb2Se3","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Achintya Bera, A. K. Sood, D.V. S. Muthu, Koushik Pal, Prasenjit Guptasarma, Somaditya Sen, U.V. Waghmare","submitted_at":"2013-03-06T10:31:03Z","abstract_excerpt":"The nontrivial electronic topology of a topological insulator is thus far known to display signatures in a robust metallic state at the surface. Here, we establish vibrational anomalies in Raman spectra of the bulk that signify changes in electronic topology: an E2 g phonon softens unusually and its linewidth exhibits an asymmetric peak at the pressure induced electronic topological transition (ETT) in Sb2Se3 crystal. Our first-principles calculations confirm the electronic transition from band to topological insulating state with reversal of parity of electronic bands passing through a metall"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1303.1291","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:31:43Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"jii+LwxCu7672xC4bLOcHIgzwtbvHFq3tmjaF8VRGe/4NRFAGmzkEYz8NNT/Ps8zFTuW4ye/0vBppldTXZxhBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T19:06:41.875124Z"},"content_sha256":"643a61131bfd42b6de0b4f66bc58d0728f65aae41648e24b2a129ed11799b7c8","schema_version":"1.0","event_id":"sha256:643a61131bfd42b6de0b4f66bc58d0728f65aae41648e24b2a129ed11799b7c8"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/bundle.json","state_url":"https://pith.science/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-08T19:06:41Z","links":{"resolver":"https://pith.science/pith/5DOZSLH64UYVWAFTS2I6S6WVHB","bundle":"https://pith.science/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/bundle.json","state":"https://pith.science/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/state.json","well_known_bundle":"https://pith.science/.well-known/pith/5DOZSLH64UYVWAFTS2I6S6WVHB/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2013:5DOZSLH64UYVWAFTS2I6S6WVHB","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"5c6bf30ff7261fd8a7e0dba780bf0528051b005dcb28f92089fec60b4c2f3b13","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-03-06T10:31:03Z","title_canon_sha256":"701e4c539954856bbebd3709f34a6466fc91d2f1fd784dfe466b34ede3e81a41"},"schema_version":"1.0","source":{"id":"1303.1291","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1303.1291","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"arxiv_version","alias_value":"1303.1291v1","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1303.1291","created_at":"2026-05-18T03:31:43Z"},{"alias_kind":"pith_short_12","alias_value":"5DOZSLH64UYV","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_16","alias_value":"5DOZSLH64UYVWAFT","created_at":"2026-05-18T12:27:34Z"},{"alias_kind":"pith_short_8","alias_value":"5DOZSLH6","created_at":"2026-05-18T12:27:34Z"}],"graph_snapshots":[{"event_id":"sha256:643a61131bfd42b6de0b4f66bc58d0728f65aae41648e24b2a129ed11799b7c8","target":"graph","created_at":"2026-05-18T03:31:43Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The nontrivial electronic topology of a topological insulator is thus far known to display signatures in a robust metallic state at the surface. Here, we establish vibrational anomalies in Raman spectra of the bulk that signify changes in electronic topology: an E2 g phonon softens unusually and its linewidth exhibits an asymmetric peak at the pressure induced electronic topological transition (ETT) in Sb2Se3 crystal. Our first-principles calculations confirm the electronic transition from band to topological insulating state with reversal of parity of electronic bands passing through a metall","authors_text":"Achintya Bera, A. K. Sood, D.V. S. Muthu, Koushik Pal, Prasenjit Guptasarma, Somaditya Sen, U.V. Waghmare","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-03-06T10:31:03Z","title":"Sharp Raman Anomalies and Broken Adiabaticity at a Pressure Induced Transition from Band to Topological Insulator in Sb2Se3"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1303.1291","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:334e43d6fb62107335ade9ec5cc44d289cf6007b4ac92e4420971fdb0f7148e4","target":"record","created_at":"2026-05-18T03:31:43Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"5c6bf30ff7261fd8a7e0dba780bf0528051b005dcb28f92089fec60b4c2f3b13","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2013-03-06T10:31:03Z","title_canon_sha256":"701e4c539954856bbebd3709f34a6466fc91d2f1fd784dfe466b34ede3e81a41"},"schema_version":"1.0","source":{"id":"1303.1291","kind":"arxiv","version":1}},"canonical_sha256":"e8dd992cfee5315b00b39691e97ad5386b30d67ecedc6ee35a950416b3b58636","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"e8dd992cfee5315b00b39691e97ad5386b30d67ecedc6ee35a950416b3b58636","first_computed_at":"2026-05-18T03:31:43.933087Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:31:43.933087Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"Ykkp6gYZ+sfnUEBnzRJXN+wFUrl4JHJvaUFX4y/2TJIY5/ZTObCP4BgsREzyQ57v9nWUI7FNZ8Sx2f2Fk0AbCQ==","signature_status":"signed_v1","signed_at":"2026-05-18T03:31:43.933991Z","signed_message":"canonical_sha256_bytes"},"source_id":"1303.1291","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:334e43d6fb62107335ade9ec5cc44d289cf6007b4ac92e4420971fdb0f7148e4","sha256:643a61131bfd42b6de0b4f66bc58d0728f65aae41648e24b2a129ed11799b7c8"],"state_sha256":"a88e58503332c63480c4d5825a99db3fa00dda34c128c804ba0268c94d166fb0"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"SFsoH+jebjJyXlexT+aAA44wOwb80BUO2UANrEMzJaw+cTasg2r1KfpZ9NvdglaLlhGi7dk/FtIOAUg9TtyzDA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-08T19:06:41.877931Z","bundle_sha256":"2bfaf752c0449a384e5580f504614ca72a83f0b6686affc7bd2b50322b322d46"}}