{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2006:5HN7TFANH7QTE4BL5MRTSIEI7M","short_pith_number":"pith:5HN7TFAN","canonical_record":{"source":{"id":"cond-mat/0603220","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T17:32:29Z","cross_cats_sorted":[],"title_canon_sha256":"f094a328b1cf9e782e16a1f86aa58082fee91e5aeff26a175663be7a5b4d54a8","abstract_canon_sha256":"5b1cff90d238c7542554f2228a59ea7c72005422707d5cc2bca1c2b9bb889da5"},"schema_version":"1.0"},"canonical_sha256":"e9dbf9940d3fe132702beb23392088fb3d300da4ff125d371021f615bc8e8e70","source":{"kind":"arxiv","id":"cond-mat/0603220","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0603220","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0603220v2","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0603220","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_12","alias_value":"5HN7TFANH7QT","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_16","alias_value":"5HN7TFANH7QTE4BL","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_8","alias_value":"5HN7TFAN","created_at":"2026-07-04T17:00:12Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2006:5HN7TFANH7QTE4BL5MRTSIEI7M","target":"record","payload":{"canonical_record":{"source":{"id":"cond-mat/0603220","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T17:32:29Z","cross_cats_sorted":[],"title_canon_sha256":"f094a328b1cf9e782e16a1f86aa58082fee91e5aeff26a175663be7a5b4d54a8","abstract_canon_sha256":"5b1cff90d238c7542554f2228a59ea7c72005422707d5cc2bca1c2b9bb889da5"},"schema_version":"1.0"},"canonical_sha256":"e9dbf9940d3fe132702beb23392088fb3d300da4ff125d371021f615bc8e8e70","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-04T17:00:12.351849Z","signature_b64":"Bz+7ZKxS1lQW+ZKD9E/UJWZAy8gwPMGXwTMTjoIaGwEoBMVYxezzFBzio0G5fO67BlfJaShbm6CAM4ZJHSoHAQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"e9dbf9940d3fe132702beb23392088fb3d300da4ff125d371021f615bc8e8e70","last_reissued_at":"2026-07-04T17:00:12.351509Z","signature_status":"signed_v1","first_computed_at":"2026-07-04T17:00:12.351509Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"cond-mat/0603220","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T17:00:12Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Dah3IEKFb97qIaNH68kZYU41vEJ33sKcYyWsNgVBOruwEz93m6o8kb4ZnVATD0iDxkyxlnMr/onvCPyp5n7sCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-10T13:06:50.891285Z"},"content_sha256":"2e51a8a8fd6834fdb74d0ce0423a6c42ff6cf3fa8aa42a2a4c541cef04807b74","schema_version":"1.0","event_id":"sha256:2e51a8a8fd6834fdb74d0ce0423a6c42ff6cf3fa8aa42a2a4c541cef04807b74"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2006:5HN7TFANH7QTE4BL5MRTSIEI7M","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Nonlinear electrochemical relaxation around conductors","license":"","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Kevin T. Chu, Martin Z. Bazant","submitted_at":"2006-03-08T17:32:29Z","abstract_excerpt":"We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In order to go beyond the circuit approximation for thin double layers, our analysis is based on the Poisson-Nernst-Planck (PNP) equations of dilute solution theory. Unlike most previous studies, however, we focus on the nonlinear regime, where the applied voltage across the conductor is larger than the thermal voltage. In such strong electric fields, the classic"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0603220","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/cond-mat/0603220/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T17:00:12Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"284i8o0/2BefHARRmiigfdOM0QGWU12zqWWkTiHlg/UcKWu9WloP5KYKhisADNYPFI7RJqLK+y7kIjkD8AkGDQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-10T13:06:50.891828Z"},"content_sha256":"dc43ac829335d4451eb8238248ab750afcdb4b2a4d72c607562af832d3a5fd02","schema_version":"1.0","event_id":"sha256:dc43ac829335d4451eb8238248ab750afcdb4b2a4d72c607562af832d3a5fd02"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/bundle.json","state_url":"https://pith.science/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-10T13:06:50Z","links":{"resolver":"https://pith.science/pith/5HN7TFANH7QTE4BL5MRTSIEI7M","bundle":"https://pith.science/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/bundle.json","state":"https://pith.science/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/state.json","well_known_bundle":"https://pith.science/.well-known/pith/5HN7TFANH7QTE4BL5MRTSIEI7M/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2006:5HN7TFANH7QTE4BL5MRTSIEI7M","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"5b1cff90d238c7542554f2228a59ea7c72005422707d5cc2bca1c2b9bb889da5","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T17:32:29Z","title_canon_sha256":"f094a328b1cf9e782e16a1f86aa58082fee91e5aeff26a175663be7a5b4d54a8"},"schema_version":"1.0","source":{"id":"cond-mat/0603220","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0603220","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0603220v2","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0603220","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_12","alias_value":"5HN7TFANH7QT","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_16","alias_value":"5HN7TFANH7QTE4BL","created_at":"2026-07-04T17:00:12Z"},{"alias_kind":"pith_short_8","alias_value":"5HN7TFAN","created_at":"2026-07-04T17:00:12Z"}],"graph_snapshots":[{"event_id":"sha256:dc43ac829335d4451eb8238248ab750afcdb4b2a4d72c607562af832d3a5fd02","target":"graph","created_at":"2026-07-04T17:00:12Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/cond-mat/0603220/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In order to go beyond the circuit approximation for thin double layers, our analysis is based on the Poisson-Nernst-Planck (PNP) equations of dilute solution theory. Unlike most previous studies, however, we focus on the nonlinear regime, where the applied voltage across the conductor is larger than the thermal voltage. In such strong electric fields, the classic","authors_text":"Kevin T. Chu, Martin Z. Bazant","cross_cats":[],"headline":"","license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T17:32:29Z","title":"Nonlinear electrochemical relaxation around conductors"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0603220","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:2e51a8a8fd6834fdb74d0ce0423a6c42ff6cf3fa8aa42a2a4c541cef04807b74","target":"record","created_at":"2026-07-04T17:00:12Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"5b1cff90d238c7542554f2228a59ea7c72005422707d5cc2bca1c2b9bb889da5","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-03-08T17:32:29Z","title_canon_sha256":"f094a328b1cf9e782e16a1f86aa58082fee91e5aeff26a175663be7a5b4d54a8"},"schema_version":"1.0","source":{"id":"cond-mat/0603220","kind":"arxiv","version":2}},"canonical_sha256":"e9dbf9940d3fe132702beb23392088fb3d300da4ff125d371021f615bc8e8e70","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"e9dbf9940d3fe132702beb23392088fb3d300da4ff125d371021f615bc8e8e70","first_computed_at":"2026-07-04T17:00:12.351509Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-04T17:00:12.351509Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"Bz+7ZKxS1lQW+ZKD9E/UJWZAy8gwPMGXwTMTjoIaGwEoBMVYxezzFBzio0G5fO67BlfJaShbm6CAM4ZJHSoHAQ==","signature_status":"signed_v1","signed_at":"2026-07-04T17:00:12.351849Z","signed_message":"canonical_sha256_bytes"},"source_id":"cond-mat/0603220","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:2e51a8a8fd6834fdb74d0ce0423a6c42ff6cf3fa8aa42a2a4c541cef04807b74","sha256:dc43ac829335d4451eb8238248ab750afcdb4b2a4d72c607562af832d3a5fd02"],"state_sha256":"a2c94cad8002b238993ed162360f8dea37f5a728cea4c472dbe8f7c896432d7c"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Av3rQj3j0I0XOh/2PpD7DZCMEW8fCSGdTe68+LIWpMWKHONcyMY049YJLnEOHw+802IAP5GiqpWzzQj1vbh6AA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-10T13:06:50.897868Z","bundle_sha256":"92f575fb9ebb5605ed91c94153a1fa01c223cd01d7255efc5f786d12363f2759"}}