{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2025:5SCRGMG2I3JYIOWAPEWIP7SBCW","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"4f192b7d26d70511ff95679ce0fd2d987c1fdb787b07e40dcf5bf1cb4e86ab60","cross_cats_sorted":["physics.chem-ph"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2025-05-22T12:32:20Z","title_canon_sha256":"5d1a5e394f3b4db8a2fde353623d8623eea3e77f804c1461cea54295d05b037a"},"schema_version":"1.0","source":{"id":"2505.16597","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2505.16597","created_at":"2026-07-05T11:18:22Z"},{"alias_kind":"arxiv_version","alias_value":"2505.16597v1","created_at":"2026-07-05T11:18:22Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2505.16597","created_at":"2026-07-05T11:18:22Z"},{"alias_kind":"pith_short_12","alias_value":"5SCRGMG2I3JY","created_at":"2026-07-05T11:18:22Z"},{"alias_kind":"pith_short_16","alias_value":"5SCRGMG2I3JYIOWA","created_at":"2026-07-05T11:18:22Z"},{"alias_kind":"pith_short_8","alias_value":"5SCRGMG2","created_at":"2026-07-05T11:18:22Z"}],"graph_snapshots":[{"event_id":"sha256:2aa3074e9112434f1ecf940a304a078e69fac19809dab63f0abb896515ed3916","target":"graph","created_at":"2026-07-05T11:18:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2505.16597/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"With the advancement of nanoscience, silver/silver chloride (Ag/AgCl) electrodes have become widely utilised in microscale and nanoscale fluidic experiments, because of their stability. However, our findings reveal that the dissolution of AgCl from the electrode in \\ch{Cl-}-rich solutions can lead to significant silver contamination, through the formation of silver complexes, \\ch{[AgCl_{n+1}]^{n-}}. We demonstrate the electrodeposition of silver particles on graphene in KCl aqueous solution, with AgCl dissolution from the electrode as the sole source of silver. This unexpected electrodepositio","authors_text":"Artem Mishchenko, Chuhongxu Chen, Guilin Chen, Ivan Timokhin, Pablo D{\\i}az-Nunez, Qian Yang, Stephen Tipper, Zakhar Bedran, Zhijia Zhang, Ziwei Wang","cross_cats":["physics.chem-ph"],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2025-05-22T12:32:20Z","title":"Silver Electrodeposition from Ag/AgCl Electrodes: Implications for Nanoscience"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2505.16597","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:9322b82e03111d0edad2e56f5ce41db5d862f82cccf8a162af7bb44d98ee7d98","target":"record","created_at":"2026-07-05T11:18:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"4f192b7d26d70511ff95679ce0fd2d987c1fdb787b07e40dcf5bf1cb4e86ab60","cross_cats_sorted":["physics.chem-ph"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2025-05-22T12:32:20Z","title_canon_sha256":"5d1a5e394f3b4db8a2fde353623d8623eea3e77f804c1461cea54295d05b037a"},"schema_version":"1.0","source":{"id":"2505.16597","kind":"arxiv","version":1}},"canonical_sha256":"ec851330da46d3843ac0792c87fe41159887f5ce729e0c454f530ee4a4025707","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"ec851330da46d3843ac0792c87fe41159887f5ce729e0c454f530ee4a4025707","first_computed_at":"2026-07-05T11:18:22.063667Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T11:18:22.063667Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"SK/XXr9SUYQDQBfO4LyuLScBQkJVx3Qd8Ptc+EMxKMG/2ip2yBYPrbZVx8gea8dr+bPhuPQZTRYJCWsvZpnxBw==","signature_status":"signed_v1","signed_at":"2026-07-05T11:18:22.064144Z","signed_message":"canonical_sha256_bytes"},"source_id":"2505.16597","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:9322b82e03111d0edad2e56f5ce41db5d862f82cccf8a162af7bb44d98ee7d98","sha256:2aa3074e9112434f1ecf940a304a078e69fac19809dab63f0abb896515ed3916"],"state_sha256":"e4ed5d65da4e0f5d96a61bdd4f8524cd3ad61b37a18aed219b782831f6b45e1c"}