{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2014:5V3CMJYZCQAIUNAOJSAY7CE2D2","short_pith_number":"pith:5V3CMJYZ","schema_version":"1.0","canonical_sha256":"ed7626271914008a340e4c818f889a1e939429fde057abc3e00d74b385a30d4b","source":{"kind":"arxiv","id":"1403.0966","version":1},"attestation_state":"computed","paper":{"title":"Voltage tuning of vibrational mode energies in single-molecule junctions","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"D. Natelson, J. B. Neaton, L. Kronik, P. Doak, Y. Li","submitted_at":"2014-03-04T22:18:58Z","abstract_excerpt":"Vibrational modes of molecules are fundamental properties determined by intramolecular bonding, atomic masses, and molecular geometry, and often serve as important channels for dissipation in nanoscale processes. Although single-molecule junctions have been employed to manipulate electronic structure and related functional properties of molecules, electrical control of vibrational mode energies has remained elusive. Here we use simultaneous transport and surface-enhanced Raman spectroscopy measurements to demonstrate large, reversible, voltage-driven shifts of vibrational mode energies of C60 "},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1403.0966","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-04T22:18:58Z","cross_cats_sorted":[],"title_canon_sha256":"9066dbe4225290b0a467d21650645f1be4a2147f5a5f66980d30aaa9ede50398","abstract_canon_sha256":"7af1da789023b1adc58e71f0b8117ea2acae8c50f44989e457625b73720bdf15"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:57:06.018246Z","signature_b64":"mrNWBK0N7pIur76AWv0PefxOwFh2ApaB82pvsgbKTLxcKEGbgG+tZ4bbUGzeyw+dzie0mKOWo7024n1weKnuDA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"ed7626271914008a340e4c818f889a1e939429fde057abc3e00d74b385a30d4b","last_reissued_at":"2026-05-18T02:57:06.017623Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:57:06.017623Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Voltage tuning of vibrational mode energies in single-molecule junctions","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"D. Natelson, J. B. Neaton, L. Kronik, P. Doak, Y. Li","submitted_at":"2014-03-04T22:18:58Z","abstract_excerpt":"Vibrational modes of molecules are fundamental properties determined by intramolecular bonding, atomic masses, and molecular geometry, and often serve as important channels for dissipation in nanoscale processes. Although single-molecule junctions have been employed to manipulate electronic structure and related functional properties of molecules, electrical control of vibrational mode energies has remained elusive. Here we use simultaneous transport and surface-enhanced Raman spectroscopy measurements to demonstrate large, reversible, voltage-driven shifts of vibrational mode energies of C60 "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.0966","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1403.0966","created_at":"2026-05-18T02:57:06.017713+00:00"},{"alias_kind":"arxiv_version","alias_value":"1403.0966v1","created_at":"2026-05-18T02:57:06.017713+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.0966","created_at":"2026-05-18T02:57:06.017713+00:00"},{"alias_kind":"pith_short_12","alias_value":"5V3CMJYZCQAI","created_at":"2026-05-18T12:28:16.859392+00:00"},{"alias_kind":"pith_short_16","alias_value":"5V3CMJYZCQAIUNAO","created_at":"2026-05-18T12:28:16.859392+00:00"},{"alias_kind":"pith_short_8","alias_value":"5V3CMJYZ","created_at":"2026-05-18T12:28:16.859392+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2","json":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2.json","graph_json":"https://pith.science/api/pith-number/5V3CMJYZCQAIUNAOJSAY7CE2D2/graph.json","events_json":"https://pith.science/api/pith-number/5V3CMJYZCQAIUNAOJSAY7CE2D2/events.json","paper":"https://pith.science/paper/5V3CMJYZ"},"agent_actions":{"view_html":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2","download_json":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2.json","view_paper":"https://pith.science/paper/5V3CMJYZ","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1403.0966&json=true","fetch_graph":"https://pith.science/api/pith-number/5V3CMJYZCQAIUNAOJSAY7CE2D2/graph.json","fetch_events":"https://pith.science/api/pith-number/5V3CMJYZCQAIUNAOJSAY7CE2D2/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2/action/timestamp_anchor","attest_storage":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2/action/storage_attestation","attest_author":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2/action/author_attestation","sign_citation":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2/action/citation_signature","submit_replication":"https://pith.science/pith/5V3CMJYZCQAIUNAOJSAY7CE2D2/action/replication_record"}},"created_at":"2026-05-18T02:57:06.017713+00:00","updated_at":"2026-05-18T02:57:06.017713+00:00"}