{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2024:6CTD5ENM2JBUUPVH2CTTIROQ6G","short_pith_number":"pith:6CTD5ENM","canonical_record":{"source":{"id":"2409.02067","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.optics","submitted_at":"2024-09-03T17:15:06Z","cross_cats_sorted":[],"title_canon_sha256":"af41ade335e31e433c23cacfb04da0cc516b520ec29cce042a1d931b744a17b6","abstract_canon_sha256":"69de7614d456dc5fe4d9255617dc125d21358a45401a2e5e2fef85bd1e16d502"},"schema_version":"1.0"},"canonical_sha256":"f0a63e91acd2434a3ea7d0a73445d0f18fd90b705fcb4f4f5cdb2ee9f46c3e47","source":{"kind":"arxiv","id":"2409.02067","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2409.02067","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"arxiv_version","alias_value":"2409.02067v1","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2409.02067","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_12","alias_value":"6CTD5ENM2JBU","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_16","alias_value":"6CTD5ENM2JBUUPVH","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_8","alias_value":"6CTD5ENM","created_at":"2026-07-05T09:02:38Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2024:6CTD5ENM2JBUUPVH2CTTIROQ6G","target":"record","payload":{"canonical_record":{"source":{"id":"2409.02067","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.optics","submitted_at":"2024-09-03T17:15:06Z","cross_cats_sorted":[],"title_canon_sha256":"af41ade335e31e433c23cacfb04da0cc516b520ec29cce042a1d931b744a17b6","abstract_canon_sha256":"69de7614d456dc5fe4d9255617dc125d21358a45401a2e5e2fef85bd1e16d502"},"schema_version":"1.0"},"canonical_sha256":"f0a63e91acd2434a3ea7d0a73445d0f18fd90b705fcb4f4f5cdb2ee9f46c3e47","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T09:02:38.230758Z","signature_b64":"cIkoYiOrFuh3pcDvVpjuoABIstveZOR6TGZLk+Q6IOUsZyJ3He6P78FrUowNJ5CWFG0dK/pKer6HUdqPRD09DQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"f0a63e91acd2434a3ea7d0a73445d0f18fd90b705fcb4f4f5cdb2ee9f46c3e47","last_reissued_at":"2026-07-05T09:02:38.230022Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T09:02:38.230022Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2409.02067","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T09:02:38Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"c6Nba3zXPsFbvCWDgfnubNtjO645+Y9d76HB5haeZjEy/XRMJ33oqVO370y1QjBW9peqQSH4ebFUbAbHKN9gBA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-08T11:47:00.520447Z"},"content_sha256":"6de5f4717463067beccf874c202c6f4526dc468ce231aca4ba8d9196c632211f","schema_version":"1.0","event_id":"sha256:6de5f4717463067beccf874c202c6f4526dc468ce231aca4ba8d9196c632211f"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2024:6CTD5ENM2JBUUPVH2CTTIROQ6G","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Efficient and Tunable Photochemical Charge Transfer via Long-Lived Bloch Surface Wave Polaritons","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"physics.optics","authors_text":"Bernardo Salcido-Santacruz, Evripidis Michail, Kamyar Rashidi, Matthew Y. Sfeir, Vinod M. Menon, Yamuna Paudel","submitted_at":"2024-09-03T17:15:06Z","abstract_excerpt":"Achieving precise control of photoinduced molecular charge transfer reactions underpins key emerging technologies. As such, the use of hybrid light-matter molecular exciton-polariton states has been proposed as a scheme to directly modify the efficiency and rate of such reactions. However, the efficacy of polariton-driven photochemistry remains an open question. Here, we demonstrate conditions under which photoinduced polaritonic charge transfer can be achieved and directly visualized using momentum resolved ultrafast spectroscopy. Key conditions for charge transfer are satisfied using Bloch s"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2409.02067","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2409.02067/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T09:02:38Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"VrBDX4VHO8mSz7INupxk9nPflkFMcvDIfh8J9fyOWWRD4pD+oVBVdy+k8KG3aQI3fqQYV0d5kLk0LkZOUEzHAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-08T11:47:00.520966Z"},"content_sha256":"93470a88bf572a06ffff1a2a583289641dd70a25313f420e928676e07ccb0ee0","schema_version":"1.0","event_id":"sha256:93470a88bf572a06ffff1a2a583289641dd70a25313f420e928676e07ccb0ee0"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/bundle.json","state_url":"https://pith.science/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-08T11:47:00Z","links":{"resolver":"https://pith.science/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G","bundle":"https://pith.science/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/bundle.json","state":"https://pith.science/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/state.json","well_known_bundle":"https://pith.science/.well-known/pith/6CTD5ENM2JBUUPVH2CTTIROQ6G/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2024:6CTD5ENM2JBUUPVH2CTTIROQ6G","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"69de7614d456dc5fe4d9255617dc125d21358a45401a2e5e2fef85bd1e16d502","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.optics","submitted_at":"2024-09-03T17:15:06Z","title_canon_sha256":"af41ade335e31e433c23cacfb04da0cc516b520ec29cce042a1d931b744a17b6"},"schema_version":"1.0","source":{"id":"2409.02067","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2409.02067","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"arxiv_version","alias_value":"2409.02067v1","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2409.02067","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_12","alias_value":"6CTD5ENM2JBU","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_16","alias_value":"6CTD5ENM2JBUUPVH","created_at":"2026-07-05T09:02:38Z"},{"alias_kind":"pith_short_8","alias_value":"6CTD5ENM","created_at":"2026-07-05T09:02:38Z"}],"graph_snapshots":[{"event_id":"sha256:93470a88bf572a06ffff1a2a583289641dd70a25313f420e928676e07ccb0ee0","target":"graph","created_at":"2026-07-05T09:02:38Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2409.02067/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Achieving precise control of photoinduced molecular charge transfer reactions underpins key emerging technologies. As such, the use of hybrid light-matter molecular exciton-polariton states has been proposed as a scheme to directly modify the efficiency and rate of such reactions. However, the efficacy of polariton-driven photochemistry remains an open question. Here, we demonstrate conditions under which photoinduced polaritonic charge transfer can be achieved and directly visualized using momentum resolved ultrafast spectroscopy. Key conditions for charge transfer are satisfied using Bloch s","authors_text":"Bernardo Salcido-Santacruz, Evripidis Michail, Kamyar Rashidi, Matthew Y. Sfeir, Vinod M. Menon, Yamuna Paudel","cross_cats":[],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.optics","submitted_at":"2024-09-03T17:15:06Z","title":"Efficient and Tunable Photochemical Charge Transfer via Long-Lived Bloch Surface Wave Polaritons"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2409.02067","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:6de5f4717463067beccf874c202c6f4526dc468ce231aca4ba8d9196c632211f","target":"record","created_at":"2026-07-05T09:02:38Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"69de7614d456dc5fe4d9255617dc125d21358a45401a2e5e2fef85bd1e16d502","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.optics","submitted_at":"2024-09-03T17:15:06Z","title_canon_sha256":"af41ade335e31e433c23cacfb04da0cc516b520ec29cce042a1d931b744a17b6"},"schema_version":"1.0","source":{"id":"2409.02067","kind":"arxiv","version":1}},"canonical_sha256":"f0a63e91acd2434a3ea7d0a73445d0f18fd90b705fcb4f4f5cdb2ee9f46c3e47","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"f0a63e91acd2434a3ea7d0a73445d0f18fd90b705fcb4f4f5cdb2ee9f46c3e47","first_computed_at":"2026-07-05T09:02:38.230022Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T09:02:38.230022Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"cIkoYiOrFuh3pcDvVpjuoABIstveZOR6TGZLk+Q6IOUsZyJ3He6P78FrUowNJ5CWFG0dK/pKer6HUdqPRD09DQ==","signature_status":"signed_v1","signed_at":"2026-07-05T09:02:38.230758Z","signed_message":"canonical_sha256_bytes"},"source_id":"2409.02067","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:6de5f4717463067beccf874c202c6f4526dc468ce231aca4ba8d9196c632211f","sha256:93470a88bf572a06ffff1a2a583289641dd70a25313f420e928676e07ccb0ee0"],"state_sha256":"3e6c7712778af62cd973895d159d72566f76964ab8228ff9f80a75b059980b39"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Wwv/bcXp1RjQv4LXbnqhvMK37y12fRTiek93q4WX4jyuUQ9dQgJ+IbCXdNRMbL6HIbZkPZfsOK+m7nog84o3DA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-08T11:47:00.524494Z","bundle_sha256":"a478144797e0607a9a1e4501ccc9a86163bf25f32328e145db35fc0726c62c4b"}}