{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2022:6KBKDK24EHK5Y6M4K6CWN7ZUVQ","short_pith_number":"pith:6KBKDK24","canonical_record":{"source":{"id":"2204.10355","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2022-04-21T18:26:05Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"cb13ebb94d932bbf38a3288592b2ab25789bc916934aac5aab69152d1cf3b112","abstract_canon_sha256":"845bdcd9230892b66b744f765a2b93247ca58cb6dcb335310f7884a12cfb2190"},"schema_version":"1.0"},"canonical_sha256":"f282a1ab5c21d5dc799c578566ff34ac223223e217209e5db6e55f73d673273d","source":{"kind":"arxiv","id":"2204.10355","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2204.10355","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"arxiv_version","alias_value":"2204.10355v1","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2204.10355","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_12","alias_value":"6KBKDK24EHK5","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_16","alias_value":"6KBKDK24EHK5Y6M4","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_8","alias_value":"6KBKDK24","created_at":"2026-07-05T04:16:55Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2022:6KBKDK24EHK5Y6M4K6CWN7ZUVQ","target":"record","payload":{"canonical_record":{"source":{"id":"2204.10355","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2022-04-21T18:26:05Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"cb13ebb94d932bbf38a3288592b2ab25789bc916934aac5aab69152d1cf3b112","abstract_canon_sha256":"845bdcd9230892b66b744f765a2b93247ca58cb6dcb335310f7884a12cfb2190"},"schema_version":"1.0"},"canonical_sha256":"f282a1ab5c21d5dc799c578566ff34ac223223e217209e5db6e55f73d673273d","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:16:55.942344Z","signature_b64":"ZWdBy9d/CM3E1O/xRKoB4t5pMJwA0kdQBXNfr0oysurjaIspLtxS/IyFAaeK+Uj6Lg2pL5S1YlAFP6wd3DERAQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"f282a1ab5c21d5dc799c578566ff34ac223223e217209e5db6e55f73d673273d","last_reissued_at":"2026-07-05T04:16:55.941926Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:16:55.941926Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2204.10355","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:16:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"vcGC5dtKCa9XlQDva2lZ5hSUQtoJruDG2AMDsCk5d4qH2KC/6AXb7hRKSUMrTM0pCoJ0tLeIvtz7lY0ezCWKCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-04T12:38:58.926224Z"},"content_sha256":"7b087a9e20e67f5f17c188c53cb14566dd1331c322ca7afe842a6b1fdaa339d9","schema_version":"1.0","event_id":"sha256:7b087a9e20e67f5f17c188c53cb14566dd1331c322ca7afe842a6b1fdaa339d9"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2022:6KBKDK24EHK5Y6M4K6CWN7ZUVQ","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Symmetry-Breaking and Self-Sorting in Block Copolymer-based Multicomponent Nanocomposites","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.soft","authors_text":"Alfredo Alexander-Katz, Hejin Huang, Le Ma, Peter Ercius, Ting Xu","submitted_at":"2022-04-21T18:26:05Z","abstract_excerpt":"Co-assembly of inorganic nanoparticles (NPs) and nanostructured polymer matrix represents an intricate interplay of enthalpic or entropic forces. Particle size largely affects the phase behavior of the nanocomposite. Theoretical studies indicate that new morphologies would emerge when the particles become comparable to the soft matrix's size, but this has rarely been supported experimentally. By designing a multicomponent blend composed of NPs, block copolymer-based supramolecules, and small molecules, a 3-D ordered lattice beyond the native BCP's morphology was recently reported when the part"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2204.10355","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2204.10355/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:16:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"GihojLn4w77dKKcI1b7eWW1cb9NLQl+WBwzKwQ0yFgppYqlUtdunxJyq1CIXx8E63xwx5MSn2eqfSYeoKPjuDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-04T12:38:58.926776Z"},"content_sha256":"ed07dd398717699e441e533332217f8deda202d3be23b5480d086015345e3da3","schema_version":"1.0","event_id":"sha256:ed07dd398717699e441e533332217f8deda202d3be23b5480d086015345e3da3"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/bundle.json","state_url":"https://pith.science/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-04T12:38:58Z","links":{"resolver":"https://pith.science/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ","bundle":"https://pith.science/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/bundle.json","state":"https://pith.science/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/state.json","well_known_bundle":"https://pith.science/.well-known/pith/6KBKDK24EHK5Y6M4K6CWN7ZUVQ/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2022:6KBKDK24EHK5Y6M4K6CWN7ZUVQ","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"845bdcd9230892b66b744f765a2b93247ca58cb6dcb335310f7884a12cfb2190","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2022-04-21T18:26:05Z","title_canon_sha256":"cb13ebb94d932bbf38a3288592b2ab25789bc916934aac5aab69152d1cf3b112"},"schema_version":"1.0","source":{"id":"2204.10355","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2204.10355","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"arxiv_version","alias_value":"2204.10355v1","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2204.10355","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_12","alias_value":"6KBKDK24EHK5","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_16","alias_value":"6KBKDK24EHK5Y6M4","created_at":"2026-07-05T04:16:55Z"},{"alias_kind":"pith_short_8","alias_value":"6KBKDK24","created_at":"2026-07-05T04:16:55Z"}],"graph_snapshots":[{"event_id":"sha256:ed07dd398717699e441e533332217f8deda202d3be23b5480d086015345e3da3","target":"graph","created_at":"2026-07-05T04:16:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2204.10355/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Co-assembly of inorganic nanoparticles (NPs) and nanostructured polymer matrix represents an intricate interplay of enthalpic or entropic forces. Particle size largely affects the phase behavior of the nanocomposite. Theoretical studies indicate that new morphologies would emerge when the particles become comparable to the soft matrix's size, but this has rarely been supported experimentally. By designing a multicomponent blend composed of NPs, block copolymer-based supramolecules, and small molecules, a 3-D ordered lattice beyond the native BCP's morphology was recently reported when the part","authors_text":"Alfredo Alexander-Katz, Hejin Huang, Le Ma, Peter Ercius, Ting Xu","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2022-04-21T18:26:05Z","title":"Symmetry-Breaking and Self-Sorting in Block Copolymer-based Multicomponent Nanocomposites"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2204.10355","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:7b087a9e20e67f5f17c188c53cb14566dd1331c322ca7afe842a6b1fdaa339d9","target":"record","created_at":"2026-07-05T04:16:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"845bdcd9230892b66b744f765a2b93247ca58cb6dcb335310f7884a12cfb2190","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2022-04-21T18:26:05Z","title_canon_sha256":"cb13ebb94d932bbf38a3288592b2ab25789bc916934aac5aab69152d1cf3b112"},"schema_version":"1.0","source":{"id":"2204.10355","kind":"arxiv","version":1}},"canonical_sha256":"f282a1ab5c21d5dc799c578566ff34ac223223e217209e5db6e55f73d673273d","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"f282a1ab5c21d5dc799c578566ff34ac223223e217209e5db6e55f73d673273d","first_computed_at":"2026-07-05T04:16:55.941926Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T04:16:55.941926Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"ZWdBy9d/CM3E1O/xRKoB4t5pMJwA0kdQBXNfr0oysurjaIspLtxS/IyFAaeK+Uj6Lg2pL5S1YlAFP6wd3DERAQ==","signature_status":"signed_v1","signed_at":"2026-07-05T04:16:55.942344Z","signed_message":"canonical_sha256_bytes"},"source_id":"2204.10355","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:7b087a9e20e67f5f17c188c53cb14566dd1331c322ca7afe842a6b1fdaa339d9","sha256:ed07dd398717699e441e533332217f8deda202d3be23b5480d086015345e3da3"],"state_sha256":"cc87d5e7702a6a448480fa6405e72513dab4521a24b55d273c4a1d7bb3e0f641"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"hGS5T11M5vR/IM1tpUTpw9IBganOqkdvDY6CN/lNx0LntjGjzkT/ZncNCNh6vxnMnsFszkIVhTUaM+X21OqQAg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-04T12:38:58.931596Z","bundle_sha256":"102087dcc24f90e5235a09bf673c8dce8449afc8e4eef612d8bf4cb9f0879b76"}}