{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2013:6KEPXHNFEY5AF257DDVQOKRNWP","short_pith_number":"pith:6KEPXHNF","schema_version":"1.0","canonical_sha256":"f288fb9da5263a02ebbf18eb072a2db3f156e14cf3b5b6f696b0eac53e54c3fc","source":{"kind":"arxiv","id":"1302.0372","version":1},"attestation_state":"computed","paper":{"title":"Variational calculation of highly excited rovibrational energy levels of H2O2","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"astro-ph.EP","authors_text":"Igor N. Kozin, Jacek Koput, Jonathan Tennyson, Oleg L. Polyansky, Pawel Malyszek, Roman I. Ovsyannikov, Sergei N. Yurchenko","submitted_at":"2013-02-02T13:14:24Z","abstract_excerpt":"Results are presented for highly accurate ab initio variational calculation of the rotation - vibration energy levels of H2O2 in its electronic ground state. These results use a recently computed potential energy surface and the variational nuclear-motion programmes WARV4, which uses an exact kinetic energy (EKE) operator, and TROVE, which uses a numerical expansion for the kinetic energy. The TROVE calculations are performed for levels with high values of rotational excitation, $J$ up to 35. The purely \\ai\\ calculations of the rovibrational energy levels reproduce the observed levels with a s"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1302.0372","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.EP","submitted_at":"2013-02-02T13:14:24Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"a6dfa633bf9e44329b1d014b73d2507be732aab74d2f9fe1fd9e561ac7625d28","abstract_canon_sha256":"f5007277cee5fb6b78fe3f822c494b5aff7b0b939f98e62df40f1110f9c3bde8"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:49:02.101279Z","signature_b64":"/R7Z5eidACy3ndCHxMzgvrb8l/Jce5j31U1578CoyyuFyBLRwXDCXXWuwMfKJI6LfGfisqybdBdmknRinKpjDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"f288fb9da5263a02ebbf18eb072a2db3f156e14cf3b5b6f696b0eac53e54c3fc","last_reissued_at":"2026-05-18T02:49:02.100845Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:49:02.100845Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Variational calculation of highly excited rovibrational energy levels of H2O2","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"astro-ph.EP","authors_text":"Igor N. Kozin, Jacek Koput, Jonathan Tennyson, Oleg L. Polyansky, Pawel Malyszek, Roman I. Ovsyannikov, Sergei N. Yurchenko","submitted_at":"2013-02-02T13:14:24Z","abstract_excerpt":"Results are presented for highly accurate ab initio variational calculation of the rotation - vibration energy levels of H2O2 in its electronic ground state. These results use a recently computed potential energy surface and the variational nuclear-motion programmes WARV4, which uses an exact kinetic energy (EKE) operator, and TROVE, which uses a numerical expansion for the kinetic energy. The TROVE calculations are performed for levels with high values of rotational excitation, $J$ up to 35. The purely \\ai\\ calculations of the rovibrational energy levels reproduce the observed levels with a s"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1302.0372","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1302.0372","created_at":"2026-05-18T02:49:02.100901+00:00"},{"alias_kind":"arxiv_version","alias_value":"1302.0372v1","created_at":"2026-05-18T02:49:02.100901+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1302.0372","created_at":"2026-05-18T02:49:02.100901+00:00"},{"alias_kind":"pith_short_12","alias_value":"6KEPXHNFEY5A","created_at":"2026-05-18T12:27:36.564083+00:00"},{"alias_kind":"pith_short_16","alias_value":"6KEPXHNFEY5AF257","created_at":"2026-05-18T12:27:36.564083+00:00"},{"alias_kind":"pith_short_8","alias_value":"6KEPXHNF","created_at":"2026-05-18T12:27:36.564083+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP","json":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP.json","graph_json":"https://pith.science/api/pith-number/6KEPXHNFEY5AF257DDVQOKRNWP/graph.json","events_json":"https://pith.science/api/pith-number/6KEPXHNFEY5AF257DDVQOKRNWP/events.json","paper":"https://pith.science/paper/6KEPXHNF"},"agent_actions":{"view_html":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP","download_json":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP.json","view_paper":"https://pith.science/paper/6KEPXHNF","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1302.0372&json=true","fetch_graph":"https://pith.science/api/pith-number/6KEPXHNFEY5AF257DDVQOKRNWP/graph.json","fetch_events":"https://pith.science/api/pith-number/6KEPXHNFEY5AF257DDVQOKRNWP/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP/action/timestamp_anchor","attest_storage":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP/action/storage_attestation","attest_author":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP/action/author_attestation","sign_citation":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP/action/citation_signature","submit_replication":"https://pith.science/pith/6KEPXHNFEY5AF257DDVQOKRNWP/action/replication_record"}},"created_at":"2026-05-18T02:49:02.100901+00:00","updated_at":"2026-05-18T02:49:02.100901+00:00"}