{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2022:6ZMCNRLF2KMJGQKZ3GHLNOYR7L","short_pith_number":"pith:6ZMCNRLF","canonical_record":{"source":{"id":"2205.00375","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-05-01T01:23:10Z","cross_cats_sorted":["physics.chem-ph","quant-ph"],"title_canon_sha256":"c8dfd53c39e2e1ddd7b47d88a7cf79bd5aba286021ed0b819964b7a65ad10114","abstract_canon_sha256":"05233222fbafa8d5f59506eb7d77ee6478f6b7e99c8866be26325a00455bca0f"},"schema_version":"1.0"},"canonical_sha256":"f65826c565d298934159d98eb6bb11face4f14ed7ecdf843e5e7f5e8eef11644","source":{"kind":"arxiv","id":"2205.00375","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2205.00375","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"arxiv_version","alias_value":"2205.00375v2","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2205.00375","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_12","alias_value":"6ZMCNRLF2KMJ","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_16","alias_value":"6ZMCNRLF2KMJGQKZ","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_8","alias_value":"6ZMCNRLF","created_at":"2026-07-05T05:31:48Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2022:6ZMCNRLF2KMJGQKZ3GHLNOYR7L","target":"record","payload":{"canonical_record":{"source":{"id":"2205.00375","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-05-01T01:23:10Z","cross_cats_sorted":["physics.chem-ph","quant-ph"],"title_canon_sha256":"c8dfd53c39e2e1ddd7b47d88a7cf79bd5aba286021ed0b819964b7a65ad10114","abstract_canon_sha256":"05233222fbafa8d5f59506eb7d77ee6478f6b7e99c8866be26325a00455bca0f"},"schema_version":"1.0"},"canonical_sha256":"f65826c565d298934159d98eb6bb11face4f14ed7ecdf843e5e7f5e8eef11644","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T05:31:48.645969Z","signature_b64":"AJ9NADwocAAo5ZX9WTQlqbK+FJwjXAIUoarhl4GaNqvPS0zcLomsY9x+sy1IPjmuXYQ3brNG4OLclUD4AMPhAA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"f65826c565d298934159d98eb6bb11face4f14ed7ecdf843e5e7f5e8eef11644","last_reissued_at":"2026-07-05T05:31:48.645416Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T05:31:48.645416Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2205.00375","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:31:48Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"pof4l5g/6vrVA7oqmBA7UdEtTUxDbAa9JSFC42keZNBBRxgH7q0OG282J1zvzHR7c9rQw0LsRqc85QkVahtxCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-06T02:14:02.660504Z"},"content_sha256":"2e58b2afe6c4e84a52716271f437bd96a46c0f760bf3e91f154b00500a83e830","schema_version":"1.0","event_id":"sha256:2e58b2afe6c4e84a52716271f437bd96a46c0f760bf3e91f154b00500a83e830"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2022:6ZMCNRLF2KMJGQKZ3GHLNOYR7L","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Computational Insights into Electronic Excitations, Spin-Orbit Coupling Effects, and Spin Decoherence in Cr(IV)-based Molecular Qubits","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph","quant-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Aleksander L. Wysocki, Karolina Janicka, Kyungwha Park","submitted_at":"2022-05-01T01:23:10Z","abstract_excerpt":"The great success of point defects and dopants in semiconductors for quantum information processing has invigorated a search for molecules with analogous properties. Flexibility and tunability of desired properties in a large chemical space have great advantages over solid-state systems. The properties analogous to point defects were demonstrated in Cr(IV)-based molecular family, Cr(IV)(aryl)$_4$, where the electronic spin states were optically initialized, read out, and controlled. Despite this kick-start, there is still a large room for enhancing properties crucial for molecular qubits. Here"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2205.00375","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2205.00375/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:31:48Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"gc1IeZkAPzSXcHsW1GmN/wufLA9YIyHyUkLf4V9M1WSOqnOBYidebgU3HDW/nI1+s+Vd+QX4Y/kFn5C/yONFDw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-06T02:14:02.661002Z"},"content_sha256":"b0196547000c9808e347b02ff5c032e9f28ca55758ae22e5c8b50083466db14c","schema_version":"1.0","event_id":"sha256:b0196547000c9808e347b02ff5c032e9f28ca55758ae22e5c8b50083466db14c"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/bundle.json","state_url":"https://pith.science/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-06T02:14:02Z","links":{"resolver":"https://pith.science/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L","bundle":"https://pith.science/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/bundle.json","state":"https://pith.science/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/state.json","well_known_bundle":"https://pith.science/.well-known/pith/6ZMCNRLF2KMJGQKZ3GHLNOYR7L/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2022:6ZMCNRLF2KMJGQKZ3GHLNOYR7L","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"05233222fbafa8d5f59506eb7d77ee6478f6b7e99c8866be26325a00455bca0f","cross_cats_sorted":["physics.chem-ph","quant-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-05-01T01:23:10Z","title_canon_sha256":"c8dfd53c39e2e1ddd7b47d88a7cf79bd5aba286021ed0b819964b7a65ad10114"},"schema_version":"1.0","source":{"id":"2205.00375","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2205.00375","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"arxiv_version","alias_value":"2205.00375v2","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2205.00375","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_12","alias_value":"6ZMCNRLF2KMJ","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_16","alias_value":"6ZMCNRLF2KMJGQKZ","created_at":"2026-07-05T05:31:48Z"},{"alias_kind":"pith_short_8","alias_value":"6ZMCNRLF","created_at":"2026-07-05T05:31:48Z"}],"graph_snapshots":[{"event_id":"sha256:b0196547000c9808e347b02ff5c032e9f28ca55758ae22e5c8b50083466db14c","target":"graph","created_at":"2026-07-05T05:31:48Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2205.00375/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The great success of point defects and dopants in semiconductors for quantum information processing has invigorated a search for molecules with analogous properties. Flexibility and tunability of desired properties in a large chemical space have great advantages over solid-state systems. The properties analogous to point defects were demonstrated in Cr(IV)-based molecular family, Cr(IV)(aryl)$_4$, where the electronic spin states were optically initialized, read out, and controlled. Despite this kick-start, there is still a large room for enhancing properties crucial for molecular qubits. Here","authors_text":"Aleksander L. Wysocki, Karolina Janicka, Kyungwha Park","cross_cats":["physics.chem-ph","quant-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-05-01T01:23:10Z","title":"Computational Insights into Electronic Excitations, Spin-Orbit Coupling Effects, and Spin Decoherence in Cr(IV)-based Molecular Qubits"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2205.00375","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:2e58b2afe6c4e84a52716271f437bd96a46c0f760bf3e91f154b00500a83e830","target":"record","created_at":"2026-07-05T05:31:48Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"05233222fbafa8d5f59506eb7d77ee6478f6b7e99c8866be26325a00455bca0f","cross_cats_sorted":["physics.chem-ph","quant-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-05-01T01:23:10Z","title_canon_sha256":"c8dfd53c39e2e1ddd7b47d88a7cf79bd5aba286021ed0b819964b7a65ad10114"},"schema_version":"1.0","source":{"id":"2205.00375","kind":"arxiv","version":2}},"canonical_sha256":"f65826c565d298934159d98eb6bb11face4f14ed7ecdf843e5e7f5e8eef11644","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"f65826c565d298934159d98eb6bb11face4f14ed7ecdf843e5e7f5e8eef11644","first_computed_at":"2026-07-05T05:31:48.645416Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T05:31:48.645416Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"AJ9NADwocAAo5ZX9WTQlqbK+FJwjXAIUoarhl4GaNqvPS0zcLomsY9x+sy1IPjmuXYQ3brNG4OLclUD4AMPhAA==","signature_status":"signed_v1","signed_at":"2026-07-05T05:31:48.645969Z","signed_message":"canonical_sha256_bytes"},"source_id":"2205.00375","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:2e58b2afe6c4e84a52716271f437bd96a46c0f760bf3e91f154b00500a83e830","sha256:b0196547000c9808e347b02ff5c032e9f28ca55758ae22e5c8b50083466db14c"],"state_sha256":"9dbdb71b8c8d0695425097e911ed3c391be81f3ad71c563d4d428fac5d1f8eff"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"bxUKxRwwYOpbXizxJISxyt3c9jq6mN5mr7GDXeSyejoriC+UbpkexrAo8ogBzYxHwFA59jwze3MzGBMP5JtaBw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-06T02:14:02.665277Z","bundle_sha256":"4ea3361fd45bcfa50d50ef4c3cc1b81aa67b2db93b1c94b87126df5064e83061"}}