{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2009:7RSSMUXIPFH5ZDSE3XIL4X3Z62","short_pith_number":"pith:7RSSMUXI","canonical_record":{"source":{"id":"0908.3203","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2009-08-21T20:39:24Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"0a62ccadd6946e382c34a6f57f252bd3ad717d60251189ef726379973e859387","abstract_canon_sha256":"a045b3c16839afe6925c04854176fc03b3685224093e14a4487358c575c3b561"},"schema_version":"1.0"},"canonical_sha256":"fc652652e8794fdc8e44ddd0be5f79f68ef42325295396a6c07454d4d1dba76d","source":{"kind":"arxiv","id":"0908.3203","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0908.3203","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"arxiv_version","alias_value":"0908.3203v1","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0908.3203","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"pith_short_12","alias_value":"7RSSMUXIPFH5","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_16","alias_value":"7RSSMUXIPFH5ZDSE","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_8","alias_value":"7RSSMUXI","created_at":"2026-05-18T12:25:58Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2009:7RSSMUXIPFH5ZDSE3XIL4X3Z62","target":"record","payload":{"canonical_record":{"source":{"id":"0908.3203","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2009-08-21T20:39:24Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"0a62ccadd6946e382c34a6f57f252bd3ad717d60251189ef726379973e859387","abstract_canon_sha256":"a045b3c16839afe6925c04854176fc03b3685224093e14a4487358c575c3b561"},"schema_version":"1.0"},"canonical_sha256":"fc652652e8794fdc8e44ddd0be5f79f68ef42325295396a6c07454d4d1dba76d","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T03:23:58.040542Z","signature_b64":"uuRmzhoCtojdXsjUDneoRrLoySa96jk/pW45dEqZ0DUQ65puLT/Nf5AaDJlk9pdCHbSWkmp8acOztKdQXEVRAA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"fc652652e8794fdc8e44ddd0be5f79f68ef42325295396a6c07454d4d1dba76d","last_reissued_at":"2026-05-18T03:23:58.039973Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T03:23:58.039973Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"0908.3203","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:23:58Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"fOWBzODQT6UtzJKUNDK3rUAHajKJFJi/urqoXlDRMtWenS5iO7UIjjM7eIXNjyHml5m2sx4itO8VNsHOqPZqCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-02T05:03:03.230813Z"},"content_sha256":"61af991f7778f42355756ea898501ff187c7c083344d76a187f56a7fa2e0c202","schema_version":"1.0","event_id":"sha256:61af991f7778f42355756ea898501ff187c7c083344d76a187f56a7fa2e0c202"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2009:7RSSMUXIPFH5ZDSE3XIL4X3Z62","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Experimental verification of a self-consistent theory of the first-, second-, and third-order (non)linear optical response","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.optics","authors_text":"Javier Perez-Moreno, Juefei Zhou, Koen Clays, Mark G. Kuzyk, Sheng-Ting Hung, Shiva K. Ramini","submitted_at":"2009-08-21T20:39:24Z","abstract_excerpt":"We show that a combination of linear absorption spectroscopy, hyper-Rayleigh scattering, and a theoretical analysis using sum rules to reduce the size of the parameter space leads to a prediction of the two-photon absorption cross-section of the dye AF455 that agrees with two-photon absorption spectroscopy. Our procedure, which demands self-consistency between several measurement techniques and does not use adjustable parameters, provides a means for determining transition moments between the dominant excited states based strictly on experimental characterization. This is made possible by our "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0908.3203","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:23:58Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"O5Ik8aqlHgMA4Ke8oBiUNwzrUYZiW5kNpZKmszYJmNW2eKbtGumD80osURbGP8rYdE2UkB/nX/c869XqTezuCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-02T05:03:03.231164Z"},"content_sha256":"06dc16780f541e0c1e0233e55688077a99708e1c5847e16bda6146ed07edf3e7","schema_version":"1.0","event_id":"sha256:06dc16780f541e0c1e0233e55688077a99708e1c5847e16bda6146ed07edf3e7"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/bundle.json","state_url":"https://pith.science/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-02T05:03:03Z","links":{"resolver":"https://pith.science/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62","bundle":"https://pith.science/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/bundle.json","state":"https://pith.science/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/state.json","well_known_bundle":"https://pith.science/.well-known/pith/7RSSMUXIPFH5ZDSE3XIL4X3Z62/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2009:7RSSMUXIPFH5ZDSE3XIL4X3Z62","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"a045b3c16839afe6925c04854176fc03b3685224093e14a4487358c575c3b561","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2009-08-21T20:39:24Z","title_canon_sha256":"0a62ccadd6946e382c34a6f57f252bd3ad717d60251189ef726379973e859387"},"schema_version":"1.0","source":{"id":"0908.3203","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0908.3203","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"arxiv_version","alias_value":"0908.3203v1","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0908.3203","created_at":"2026-05-18T03:23:58Z"},{"alias_kind":"pith_short_12","alias_value":"7RSSMUXIPFH5","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_16","alias_value":"7RSSMUXIPFH5ZDSE","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_8","alias_value":"7RSSMUXI","created_at":"2026-05-18T12:25:58Z"}],"graph_snapshots":[{"event_id":"sha256:06dc16780f541e0c1e0233e55688077a99708e1c5847e16bda6146ed07edf3e7","target":"graph","created_at":"2026-05-18T03:23:58Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We show that a combination of linear absorption spectroscopy, hyper-Rayleigh scattering, and a theoretical analysis using sum rules to reduce the size of the parameter space leads to a prediction of the two-photon absorption cross-section of the dye AF455 that agrees with two-photon absorption spectroscopy. Our procedure, which demands self-consistency between several measurement techniques and does not use adjustable parameters, provides a means for determining transition moments between the dominant excited states based strictly on experimental characterization. This is made possible by our ","authors_text":"Javier Perez-Moreno, Juefei Zhou, Koen Clays, Mark G. Kuzyk, Sheng-Ting Hung, Shiva K. Ramini","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2009-08-21T20:39:24Z","title":"Experimental verification of a self-consistent theory of the first-, second-, and third-order (non)linear optical response"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0908.3203","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:61af991f7778f42355756ea898501ff187c7c083344d76a187f56a7fa2e0c202","target":"record","created_at":"2026-05-18T03:23:58Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"a045b3c16839afe6925c04854176fc03b3685224093e14a4487358c575c3b561","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2009-08-21T20:39:24Z","title_canon_sha256":"0a62ccadd6946e382c34a6f57f252bd3ad717d60251189ef726379973e859387"},"schema_version":"1.0","source":{"id":"0908.3203","kind":"arxiv","version":1}},"canonical_sha256":"fc652652e8794fdc8e44ddd0be5f79f68ef42325295396a6c07454d4d1dba76d","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"fc652652e8794fdc8e44ddd0be5f79f68ef42325295396a6c07454d4d1dba76d","first_computed_at":"2026-05-18T03:23:58.039973Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:23:58.039973Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"uuRmzhoCtojdXsjUDneoRrLoySa96jk/pW45dEqZ0DUQ65puLT/Nf5AaDJlk9pdCHbSWkmp8acOztKdQXEVRAA==","signature_status":"signed_v1","signed_at":"2026-05-18T03:23:58.040542Z","signed_message":"canonical_sha256_bytes"},"source_id":"0908.3203","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:61af991f7778f42355756ea898501ff187c7c083344d76a187f56a7fa2e0c202","sha256:06dc16780f541e0c1e0233e55688077a99708e1c5847e16bda6146ed07edf3e7"],"state_sha256":"e29817a03cef62a80465a9334afd731b081fa7fbfd7ef182a736178f56581828"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"9oMS+uCKGlXEDNW0rMyYpjNDukntsWZ6MNExU3OYwfUkDrCANiARqPN30a5Qp6hddSAJJ+/CFfd7rc56Auq5Bw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-02T05:03:03.233149Z","bundle_sha256":"321574911c3c39f8d3937c8c76d0abec3d1041fbfd9bce0acb51613cbbc1ab41"}}