{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2006:7SZQOZ73E7ZVTDD76X3WZQEA34","short_pith_number":"pith:7SZQOZ73","schema_version":"1.0","canonical_sha256":"fcb30767fb27f3598c7ff5f76cc080df33f04a68bdb7038a9e0a0cc4eb4379d5","source":{"kind":"arxiv","id":"physics/0610041","version":1},"attestation_state":"computed","paper":{"title":"A high-resolution infrared spectroscopic investigation of the halogen atom-HCN entrance channel complexes solvated in superfluid helium droplets","license":"","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atm-clus","authors_text":"Jeremy M. Merritt, Jochen K\\\"upper, Roger E. Miller","submitted_at":"2006-10-06T17:58:58Z","abstract_excerpt":"Rotationally resolved infrared spectra are reported for the X-HCN (X = Cl, Br, I) binary complexes solvated in helium nanodroplets. These results are directly compared with that obtained previously for the corresponding X-HF complexes [J. M. Merritt, J. K\\\"upper, and R. E. Miller, PCCP, 7, 67 (2005)]. For bromine and iodine atoms complexed with HCN, two linear structures are observed and assigned to the $^{2}\\Sigma_{1/2}$ and $^{2}\\Pi_{3/2}$ ground electronic states of the nitrogen and hydrogen bound geometries, respectively. Experiments for HCN + chlorine atoms give rise to only a single band"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"physics/0610041","kind":"arxiv","version":1},"metadata":{"license":"","primary_cat":"physics.atm-clus","submitted_at":"2006-10-06T17:58:58Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"3b408628e8afb88edc17571750fa6ee110fabb892b88b8a26362c2b3387229fd","abstract_canon_sha256":"e3541d8b3dda85601c84a10220d5cf4be7a31f79df7e2f15fbf5f75730e84618"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:11:27.855411Z","signature_b64":"enRFaPrT9yoMIq47m4b5fLNIIfq7OAjprhvcTzYcXBxZWlgdon4+UJZnPVgn7rOpCXfIbd08Rj1C54UmtSf8DA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"fcb30767fb27f3598c7ff5f76cc080df33f04a68bdb7038a9e0a0cc4eb4379d5","last_reissued_at":"2026-05-18T01:11:27.854758Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:11:27.854758Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"A high-resolution infrared spectroscopic investigation of the halogen atom-HCN entrance channel complexes solvated in superfluid helium droplets","license":"","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atm-clus","authors_text":"Jeremy M. Merritt, Jochen K\\\"upper, Roger E. Miller","submitted_at":"2006-10-06T17:58:58Z","abstract_excerpt":"Rotationally resolved infrared spectra are reported for the X-HCN (X = Cl, Br, I) binary complexes solvated in helium nanodroplets. These results are directly compared with that obtained previously for the corresponding X-HF complexes [J. M. Merritt, J. K\\\"upper, and R. E. Miller, PCCP, 7, 67 (2005)]. For bromine and iodine atoms complexed with HCN, two linear structures are observed and assigned to the $^{2}\\Sigma_{1/2}$ and $^{2}\\Pi_{3/2}$ ground electronic states of the nitrogen and hydrogen bound geometries, respectively. Experiments for HCN + chlorine atoms give rise to only a single band"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0610041","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"physics/0610041","created_at":"2026-05-18T01:11:27.854870+00:00"},{"alias_kind":"arxiv_version","alias_value":"physics/0610041v1","created_at":"2026-05-18T01:11:27.854870+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0610041","created_at":"2026-05-18T01:11:27.854870+00:00"},{"alias_kind":"pith_short_12","alias_value":"7SZQOZ73E7ZV","created_at":"2026-05-18T12:25:53.939244+00:00"},{"alias_kind":"pith_short_16","alias_value":"7SZQOZ73E7ZVTDD7","created_at":"2026-05-18T12:25:53.939244+00:00"},{"alias_kind":"pith_short_8","alias_value":"7SZQOZ73","created_at":"2026-05-18T12:25:53.939244+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34","json":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34.json","graph_json":"https://pith.science/api/pith-number/7SZQOZ73E7ZVTDD76X3WZQEA34/graph.json","events_json":"https://pith.science/api/pith-number/7SZQOZ73E7ZVTDD76X3WZQEA34/events.json","paper":"https://pith.science/paper/7SZQOZ73"},"agent_actions":{"view_html":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34","download_json":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34.json","view_paper":"https://pith.science/paper/7SZQOZ73","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=physics/0610041&json=true","fetch_graph":"https://pith.science/api/pith-number/7SZQOZ73E7ZVTDD76X3WZQEA34/graph.json","fetch_events":"https://pith.science/api/pith-number/7SZQOZ73E7ZVTDD76X3WZQEA34/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34/action/timestamp_anchor","attest_storage":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34/action/storage_attestation","attest_author":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34/action/author_attestation","sign_citation":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34/action/citation_signature","submit_replication":"https://pith.science/pith/7SZQOZ73E7ZVTDD76X3WZQEA34/action/replication_record"}},"created_at":"2026-05-18T01:11:27.854870+00:00","updated_at":"2026-05-18T01:11:27.854870+00:00"}