{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2024:A2QT4GQVTULCMHFQ7YFRO3AO5M","short_pith_number":"pith:A2QT4GQV","canonical_record":{"source":{"id":"2404.01718","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2024-04-02T08:08:29Z","cross_cats_sorted":[],"title_canon_sha256":"7b65ca8490ac03205abea8dec5d36bce4134debbd6bab169b8df38cce778cc24","abstract_canon_sha256":"19ffa937dc2ec4a83bca656202cec6fd496927677f3923f56cf51bf33d30c8db"},"schema_version":"1.0"},"canonical_sha256":"06a13e1a159d16261cb0fe0b176c0eeb2d714de00d6229e54535df87b15b0f01","source":{"kind":"arxiv","id":"2404.01718","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2404.01718","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"arxiv_version","alias_value":"2404.01718v1","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2404.01718","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_12","alias_value":"A2QT4GQVTULC","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_16","alias_value":"A2QT4GQVTULCMHFQ","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_8","alias_value":"A2QT4GQV","created_at":"2026-07-05T08:03:18Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2024:A2QT4GQVTULCMHFQ7YFRO3AO5M","target":"record","payload":{"canonical_record":{"source":{"id":"2404.01718","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2024-04-02T08:08:29Z","cross_cats_sorted":[],"title_canon_sha256":"7b65ca8490ac03205abea8dec5d36bce4134debbd6bab169b8df38cce778cc24","abstract_canon_sha256":"19ffa937dc2ec4a83bca656202cec6fd496927677f3923f56cf51bf33d30c8db"},"schema_version":"1.0"},"canonical_sha256":"06a13e1a159d16261cb0fe0b176c0eeb2d714de00d6229e54535df87b15b0f01","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T08:03:18.687114Z","signature_b64":"EH+m6kb1QeToOqKEPpf502L6WhCbyAz84rJdNP66QT+wX7yIKHF0OfM4+r24/+UZIhHhh00T329QpnT7KqD6Aw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"06a13e1a159d16261cb0fe0b176c0eeb2d714de00d6229e54535df87b15b0f01","last_reissued_at":"2026-07-05T08:03:18.686674Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T08:03:18.686674Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2404.01718","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T08:03:18Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"OXdbYFdkLIrnvU3GHQ3gcOxWiwCGPQtw43ZOoQBGgozcYpMR3cI9Qw9EEKqwB7a21OuOJ2e/vvMUXmExP9X3BQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-23T14:26:37.134526Z"},"content_sha256":"9f25fe46cbb87cea0002352af6e68314cf3af13d4b68bce596b9d4ea33035fed","schema_version":"1.0","event_id":"sha256:9f25fe46cbb87cea0002352af6e68314cf3af13d4b68bce596b9d4ea33035fed"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2024:A2QT4GQVTULCMHFQ7YFRO3AO5M","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Optical Spectra of Plasmon-Exciton Core-Shell Nanoparticles: An Anisotropic Classical Model Eliminates Discrepancies with Experiments","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.optics","authors_text":"Alexey D. Kondorskiy","submitted_at":"2024-04-02T08:08:29Z","abstract_excerpt":"The optical properties of the hybrid core--shell nanostructures composed of a metallic core and an organic shell of molecular J-aggregates are determined by the electromagnetic coupling between plasmons localized at the surface of the metallic core and Frenkel excitons in the shell. In cases of strong and ultra-strong plasmon--exciton coupling, the use of the traditional isotropic classical oscillator model to describe the J-aggregate permittivity may lead to drastic discrepancies between theoretical predictions and the available experimental spectra of hybrid nanoparticles. We show that these"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2404.01718","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2404.01718/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T08:03:18Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"vMkBxwBFYoSOhml6PJ8rfnO2Ne9FM5k94oy2wqr99f6MC0H7hCkCKxvbQDxY+4e8A76gq8/PsQGfZP+4V4+0Dg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-23T14:26:37.134903Z"},"content_sha256":"9d8de974c871c686f88e9756c129f7ed514af26020974d97bb87f5da105d72c2","schema_version":"1.0","event_id":"sha256:9d8de974c871c686f88e9756c129f7ed514af26020974d97bb87f5da105d72c2"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/bundle.json","state_url":"https://pith.science/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-23T14:26:37Z","links":{"resolver":"https://pith.science/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M","bundle":"https://pith.science/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/bundle.json","state":"https://pith.science/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/state.json","well_known_bundle":"https://pith.science/.well-known/pith/A2QT4GQVTULCMHFQ7YFRO3AO5M/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2024:A2QT4GQVTULCMHFQ7YFRO3AO5M","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"19ffa937dc2ec4a83bca656202cec6fd496927677f3923f56cf51bf33d30c8db","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2024-04-02T08:08:29Z","title_canon_sha256":"7b65ca8490ac03205abea8dec5d36bce4134debbd6bab169b8df38cce778cc24"},"schema_version":"1.0","source":{"id":"2404.01718","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2404.01718","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"arxiv_version","alias_value":"2404.01718v1","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2404.01718","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_12","alias_value":"A2QT4GQVTULC","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_16","alias_value":"A2QT4GQVTULCMHFQ","created_at":"2026-07-05T08:03:18Z"},{"alias_kind":"pith_short_8","alias_value":"A2QT4GQV","created_at":"2026-07-05T08:03:18Z"}],"graph_snapshots":[{"event_id":"sha256:9d8de974c871c686f88e9756c129f7ed514af26020974d97bb87f5da105d72c2","target":"graph","created_at":"2026-07-05T08:03:18Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2404.01718/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The optical properties of the hybrid core--shell nanostructures composed of a metallic core and an organic shell of molecular J-aggregates are determined by the electromagnetic coupling between plasmons localized at the surface of the metallic core and Frenkel excitons in the shell. In cases of strong and ultra-strong plasmon--exciton coupling, the use of the traditional isotropic classical oscillator model to describe the J-aggregate permittivity may lead to drastic discrepancies between theoretical predictions and the available experimental spectra of hybrid nanoparticles. We show that these","authors_text":"Alexey D. Kondorskiy","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2024-04-02T08:08:29Z","title":"Optical Spectra of Plasmon-Exciton Core-Shell Nanoparticles: An Anisotropic Classical Model Eliminates Discrepancies with Experiments"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2404.01718","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:9f25fe46cbb87cea0002352af6e68314cf3af13d4b68bce596b9d4ea33035fed","target":"record","created_at":"2026-07-05T08:03:18Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"19ffa937dc2ec4a83bca656202cec6fd496927677f3923f56cf51bf33d30c8db","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.optics","submitted_at":"2024-04-02T08:08:29Z","title_canon_sha256":"7b65ca8490ac03205abea8dec5d36bce4134debbd6bab169b8df38cce778cc24"},"schema_version":"1.0","source":{"id":"2404.01718","kind":"arxiv","version":1}},"canonical_sha256":"06a13e1a159d16261cb0fe0b176c0eeb2d714de00d6229e54535df87b15b0f01","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"06a13e1a159d16261cb0fe0b176c0eeb2d714de00d6229e54535df87b15b0f01","first_computed_at":"2026-07-05T08:03:18.686674Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T08:03:18.686674Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"EH+m6kb1QeToOqKEPpf502L6WhCbyAz84rJdNP66QT+wX7yIKHF0OfM4+r24/+UZIhHhh00T329QpnT7KqD6Aw==","signature_status":"signed_v1","signed_at":"2026-07-05T08:03:18.687114Z","signed_message":"canonical_sha256_bytes"},"source_id":"2404.01718","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:9f25fe46cbb87cea0002352af6e68314cf3af13d4b68bce596b9d4ea33035fed","sha256:9d8de974c871c686f88e9756c129f7ed514af26020974d97bb87f5da105d72c2"],"state_sha256":"77155198bf2ab02b6468912c68f69bda30279bdd76a622531f05b1d4585a348b"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"c8XN+BNL8Zqa9zKWRrcSu+k1kr6omPZkZhcCk395WsTmoDSUCLekv8XbrirELhp5ImF0QRTYgnUmPsCBOwe+Dg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-23T14:26:37.137581Z","bundle_sha256":"b12a71ec867e95604fcee156551386ef05caa58a066fd41333331936eee36aec"}}