{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2011:ASWGQFJEAJJLWWE4M7TTK6CGDG","short_pith_number":"pith:ASWGQFJE","canonical_record":{"source":{"id":"1103.3586","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.CO","submitted_at":"2011-03-18T10:07:26Z","cross_cats_sorted":[],"title_canon_sha256":"14cf136db750a886818922e51be4ac1186e63f9943577bd8047394de71b59c8e","abstract_canon_sha256":"22ecdec60e5e29cf4af56962dae23fd5f518fc7320406f7341d7802f8983d295"},"schema_version":"1.0"},"canonical_sha256":"04ac6815240252bb589c67e735784619b03e1a5b109d40439f6b44347bf0f5de","source":{"kind":"arxiv","id":"1103.3586","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1103.3586","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"arxiv_version","alias_value":"1103.3586v1","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1103.3586","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"pith_short_12","alias_value":"ASWGQFJEAJJL","created_at":"2026-05-18T12:26:24Z"},{"alias_kind":"pith_short_16","alias_value":"ASWGQFJEAJJLWWE4","created_at":"2026-05-18T12:26:24Z"},{"alias_kind":"pith_short_8","alias_value":"ASWGQFJE","created_at":"2026-05-18T12:26:24Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2011:ASWGQFJEAJJLWWE4M7TTK6CGDG","target":"record","payload":{"canonical_record":{"source":{"id":"1103.3586","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.CO","submitted_at":"2011-03-18T10:07:26Z","cross_cats_sorted":[],"title_canon_sha256":"14cf136db750a886818922e51be4ac1186e63f9943577bd8047394de71b59c8e","abstract_canon_sha256":"22ecdec60e5e29cf4af56962dae23fd5f518fc7320406f7341d7802f8983d295"},"schema_version":"1.0"},"canonical_sha256":"04ac6815240252bb589c67e735784619b03e1a5b109d40439f6b44347bf0f5de","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T04:26:32.330142Z","signature_b64":"2xl7Dg5uFuJLkKnzeehVdEA5eSqb4swaAGpLECPvdqsWA+XnFHuMKZPKZPMCynr5DfoFfihBFAZcy+lNfQxfCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"04ac6815240252bb589c67e735784619b03e1a5b109d40439f6b44347bf0f5de","last_reissued_at":"2026-05-18T04:26:32.329667Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T04:26:32.329667Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1103.3586","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T04:26:32Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"DOuOgoLmOwEVYm7wziJuTeqz4x/Gu8p7vhQAE1OVUPRkwgbOeXWZQ4IRSZKJuAoMjKm/kbhUxoJrRNc3wWAFAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-16T15:14:40.120288Z"},"content_sha256":"a4987aaaea959f87125613e4ab8c12c67061fac80056a269aade1e79c2b4e285","schema_version":"1.0","event_id":"sha256:a4987aaaea959f87125613e4ab8c12c67061fac80056a269aade1e79c2b4e285"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2011:ASWGQFJEAJJLWWE4M7TTK6CGDG","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Vibrational level population of H$_2$ and H$_2^+$ in the early Universe","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"astro-ph.CO","authors_text":"Carla M. Coppola, Daniele Galli, Francesco Palla, Mario Capitelli, Savino Longo","submitted_at":"2011-03-18T10:07:26Z","abstract_excerpt":"We formulate a vibrationally resolved kinetics for molecular hydrogen and its cation in the primordial Universe chemistry. Formation, destruction and relaxation processes for each vibrational level are studied and included as chemical pathways of the present model. The fractional abundance of each vibrational level as a function of the redshift is given: a strong deviation from the Boltzmann distribution is found at low $z$. A discussion of the results is provided, also evaluating the effects of relaxation processes on the level populations. Analytical fits for some LTE rate coefficients are g"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1103.3586","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T04:26:32Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"lnUnAeydOxsgvq1RHz2HsWF8+/4IZfqhadcYBNUevj9CepEtmjE61b5gmJ1ZquYuMpC8ugR+DDBeehBdBj9RAQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-16T15:14:40.120822Z"},"content_sha256":"5933c0881e2c2078d59d8c9ec350667848079427f125f5f39ad5bd279d908f4c","schema_version":"1.0","event_id":"sha256:5933c0881e2c2078d59d8c9ec350667848079427f125f5f39ad5bd279d908f4c"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/bundle.json","state_url":"https://pith.science/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-16T15:14:40Z","links":{"resolver":"https://pith.science/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG","bundle":"https://pith.science/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/bundle.json","state":"https://pith.science/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/state.json","well_known_bundle":"https://pith.science/.well-known/pith/ASWGQFJEAJJLWWE4M7TTK6CGDG/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2011:ASWGQFJEAJJLWWE4M7TTK6CGDG","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"22ecdec60e5e29cf4af56962dae23fd5f518fc7320406f7341d7802f8983d295","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.CO","submitted_at":"2011-03-18T10:07:26Z","title_canon_sha256":"14cf136db750a886818922e51be4ac1186e63f9943577bd8047394de71b59c8e"},"schema_version":"1.0","source":{"id":"1103.3586","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1103.3586","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"arxiv_version","alias_value":"1103.3586v1","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1103.3586","created_at":"2026-05-18T04:26:32Z"},{"alias_kind":"pith_short_12","alias_value":"ASWGQFJEAJJL","created_at":"2026-05-18T12:26:24Z"},{"alias_kind":"pith_short_16","alias_value":"ASWGQFJEAJJLWWE4","created_at":"2026-05-18T12:26:24Z"},{"alias_kind":"pith_short_8","alias_value":"ASWGQFJE","created_at":"2026-05-18T12:26:24Z"}],"graph_snapshots":[{"event_id":"sha256:5933c0881e2c2078d59d8c9ec350667848079427f125f5f39ad5bd279d908f4c","target":"graph","created_at":"2026-05-18T04:26:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We formulate a vibrationally resolved kinetics for molecular hydrogen and its cation in the primordial Universe chemistry. Formation, destruction and relaxation processes for each vibrational level are studied and included as chemical pathways of the present model. The fractional abundance of each vibrational level as a function of the redshift is given: a strong deviation from the Boltzmann distribution is found at low $z$. A discussion of the results is provided, also evaluating the effects of relaxation processes on the level populations. Analytical fits for some LTE rate coefficients are g","authors_text":"Carla M. Coppola, Daniele Galli, Francesco Palla, Mario Capitelli, Savino Longo","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.CO","submitted_at":"2011-03-18T10:07:26Z","title":"Vibrational level population of H$_2$ and H$_2^+$ in the early Universe"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1103.3586","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a4987aaaea959f87125613e4ab8c12c67061fac80056a269aade1e79c2b4e285","target":"record","created_at":"2026-05-18T04:26:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"22ecdec60e5e29cf4af56962dae23fd5f518fc7320406f7341d7802f8983d295","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"astro-ph.CO","submitted_at":"2011-03-18T10:07:26Z","title_canon_sha256":"14cf136db750a886818922e51be4ac1186e63f9943577bd8047394de71b59c8e"},"schema_version":"1.0","source":{"id":"1103.3586","kind":"arxiv","version":1}},"canonical_sha256":"04ac6815240252bb589c67e735784619b03e1a5b109d40439f6b44347bf0f5de","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"04ac6815240252bb589c67e735784619b03e1a5b109d40439f6b44347bf0f5de","first_computed_at":"2026-05-18T04:26:32.329667Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T04:26:32.329667Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"2xl7Dg5uFuJLkKnzeehVdEA5eSqb4swaAGpLECPvdqsWA+XnFHuMKZPKZPMCynr5DfoFfihBFAZcy+lNfQxfCg==","signature_status":"signed_v1","signed_at":"2026-05-18T04:26:32.330142Z","signed_message":"canonical_sha256_bytes"},"source_id":"1103.3586","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a4987aaaea959f87125613e4ab8c12c67061fac80056a269aade1e79c2b4e285","sha256:5933c0881e2c2078d59d8c9ec350667848079427f125f5f39ad5bd279d908f4c"],"state_sha256":"573f5535b2176b70f0cfd87fa764a050a9522cae99ce62c89ec8ae24113fdcae"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"+2gZ6YIAgeD7Cj6FsQpW3NB04gSsRORKc7QVgn1T4u6UQ/2I/DggAMMvJu1l2vjRKYHz9zfvy3gsN7FdfvuvBw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-16T15:14:40.125346Z","bundle_sha256":"a49dfda0c7afa01f76c99512b7763d1811f800391de4c15487ebb9b855e6fdba"}}