{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:B53M6SNV5OVXBCVIJ3S7ZCP4OT","short_pith_number":"pith:B53M6SNV","canonical_record":{"source":{"id":"1607.04858","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-07-17T11:56:26Z","cross_cats_sorted":[],"title_canon_sha256":"1837391945a15b6478378497a6185ad67782b42df608192153026d2c0164bcdf","abstract_canon_sha256":"3e680690bec78e65c280476ae8855d12bdcb52f292eed87237e94d11ae048a50"},"schema_version":"1.0"},"canonical_sha256":"0f76cf49b5ebab708aa84ee5fc89fc74ff6384c5c72d93dbb679db0eda83830b","source":{"kind":"arxiv","id":"1607.04858","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1607.04858","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"arxiv_version","alias_value":"1607.04858v2","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1607.04858","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"pith_short_12","alias_value":"B53M6SNV5OVX","created_at":"2026-05-18T12:30:07Z"},{"alias_kind":"pith_short_16","alias_value":"B53M6SNV5OVXBCVI","created_at":"2026-05-18T12:30:07Z"},{"alias_kind":"pith_short_8","alias_value":"B53M6SNV","created_at":"2026-05-18T12:30:07Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:B53M6SNV5OVXBCVIJ3S7ZCP4OT","target":"record","payload":{"canonical_record":{"source":{"id":"1607.04858","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-07-17T11:56:26Z","cross_cats_sorted":[],"title_canon_sha256":"1837391945a15b6478378497a6185ad67782b42df608192153026d2c0164bcdf","abstract_canon_sha256":"3e680690bec78e65c280476ae8855d12bdcb52f292eed87237e94d11ae048a50"},"schema_version":"1.0"},"canonical_sha256":"0f76cf49b5ebab708aa84ee5fc89fc74ff6384c5c72d93dbb679db0eda83830b","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:51:16.875922Z","signature_b64":"PaKYvtIInXmOvkBuNW62joeDZB2CVxxfNmJ0LDbzH44Wt8H8+ic23wSnMfM0OKMjfpJbDHrRCb/mUnP5cztLAg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"0f76cf49b5ebab708aa84ee5fc89fc74ff6384c5c72d93dbb679db0eda83830b","last_reissued_at":"2026-05-18T00:51:16.875220Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:51:16.875220Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1607.04858","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:51:16Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"U58Isua/ywBxM++WtWBVCSXRlZa0jSigTk+68DBUYdnYZYxj0Iixn87aaXKozHqEXrVfYROLu1KYddyricAQDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-04T23:08:23.899858Z"},"content_sha256":"48169f29389b4d2c90e0eae9cb82b17cfdbd3411e36af40cac8853806fbf08ef","schema_version":"1.0","event_id":"sha256:48169f29389b4d2c90e0eae9cb82b17cfdbd3411e36af40cac8853806fbf08ef"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:B53M6SNV5OVXBCVIJ3S7ZCP4OT","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Chemical Reaction Rates from Ring Polymer Molecular Dynamics: Theory and Practical Applications","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"F. Javier Aoiz, Hua Guo, Yury V. Suleimanov","submitted_at":"2016-07-17T11:56:26Z","abstract_excerpt":"This Feature Article presents an overview of the current status of Ring Polymer Molecular Dynamics (RPMD) rate theory. We first analyze the RPMD approach and its connection to quantum transition-state theory. We then focus on its practical applications to prototypical chemical reactions in the gas phase, which demonstrate how accurate and reliable RPMD is for calculating thermal chemical reaction rate coefficients in multifarious cases. This review serves as an important checkpoint in RPMD rate theory development, which shows that RPMD is shifting from being just one of recent novel ideas to a"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1607.04858","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:51:16Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"FuiwcxpCrGf7kabGS3f438xQwSA7gRBKdLpE4eE2ryghdEKNM5NS+eifovQUPu9+C8ijsd936cUA93bjbf94BQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-04T23:08:23.900409Z"},"content_sha256":"d2fdeb9d21fa4da30d52e8d99dac9834d1b3fe63572d526b6aa9258fdbc46e1e","schema_version":"1.0","event_id":"sha256:d2fdeb9d21fa4da30d52e8d99dac9834d1b3fe63572d526b6aa9258fdbc46e1e"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/bundle.json","state_url":"https://pith.science/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-04T23:08:23Z","links":{"resolver":"https://pith.science/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT","bundle":"https://pith.science/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/bundle.json","state":"https://pith.science/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/state.json","well_known_bundle":"https://pith.science/.well-known/pith/B53M6SNV5OVXBCVIJ3S7ZCP4OT/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:B53M6SNV5OVXBCVIJ3S7ZCP4OT","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"3e680690bec78e65c280476ae8855d12bdcb52f292eed87237e94d11ae048a50","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-07-17T11:56:26Z","title_canon_sha256":"1837391945a15b6478378497a6185ad67782b42df608192153026d2c0164bcdf"},"schema_version":"1.0","source":{"id":"1607.04858","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1607.04858","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"arxiv_version","alias_value":"1607.04858v2","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1607.04858","created_at":"2026-05-18T00:51:16Z"},{"alias_kind":"pith_short_12","alias_value":"B53M6SNV5OVX","created_at":"2026-05-18T12:30:07Z"},{"alias_kind":"pith_short_16","alias_value":"B53M6SNV5OVXBCVI","created_at":"2026-05-18T12:30:07Z"},{"alias_kind":"pith_short_8","alias_value":"B53M6SNV","created_at":"2026-05-18T12:30:07Z"}],"graph_snapshots":[{"event_id":"sha256:d2fdeb9d21fa4da30d52e8d99dac9834d1b3fe63572d526b6aa9258fdbc46e1e","target":"graph","created_at":"2026-05-18T00:51:16Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"This Feature Article presents an overview of the current status of Ring Polymer Molecular Dynamics (RPMD) rate theory. We first analyze the RPMD approach and its connection to quantum transition-state theory. We then focus on its practical applications to prototypical chemical reactions in the gas phase, which demonstrate how accurate and reliable RPMD is for calculating thermal chemical reaction rate coefficients in multifarious cases. This review serves as an important checkpoint in RPMD rate theory development, which shows that RPMD is shifting from being just one of recent novel ideas to a","authors_text":"F. Javier Aoiz, Hua Guo, Yury V. Suleimanov","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-07-17T11:56:26Z","title":"Chemical Reaction Rates from Ring Polymer Molecular Dynamics: Theory and Practical Applications"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1607.04858","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:48169f29389b4d2c90e0eae9cb82b17cfdbd3411e36af40cac8853806fbf08ef","target":"record","created_at":"2026-05-18T00:51:16Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"3e680690bec78e65c280476ae8855d12bdcb52f292eed87237e94d11ae048a50","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-07-17T11:56:26Z","title_canon_sha256":"1837391945a15b6478378497a6185ad67782b42df608192153026d2c0164bcdf"},"schema_version":"1.0","source":{"id":"1607.04858","kind":"arxiv","version":2}},"canonical_sha256":"0f76cf49b5ebab708aa84ee5fc89fc74ff6384c5c72d93dbb679db0eda83830b","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"0f76cf49b5ebab708aa84ee5fc89fc74ff6384c5c72d93dbb679db0eda83830b","first_computed_at":"2026-05-18T00:51:16.875220Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:51:16.875220Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"PaKYvtIInXmOvkBuNW62joeDZB2CVxxfNmJ0LDbzH44Wt8H8+ic23wSnMfM0OKMjfpJbDHrRCb/mUnP5cztLAg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:51:16.875922Z","signed_message":"canonical_sha256_bytes"},"source_id":"1607.04858","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:48169f29389b4d2c90e0eae9cb82b17cfdbd3411e36af40cac8853806fbf08ef","sha256:d2fdeb9d21fa4da30d52e8d99dac9834d1b3fe63572d526b6aa9258fdbc46e1e"],"state_sha256":"cfb14f333f73581b2f91695b918cbc9c81e2e4675669adf09d1a38fee0983ba3"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"SGLWy+izc8G3RoV8jlBhXkbgw1wXfP1fUX+xNPFivDji2UsdvHQxU7a6Fs/J/35B9j9w4x0Y5kPRIrHqzVH+BA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-04T23:08:23.903140Z","bundle_sha256":"f82ec7ebcf7c4e5fd9d855fb786897d1332128c5cf09f26e86c3b03861f3debd"}}