{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2022:BOBWSTYYI2L276T5NZHEYXLEMZ","short_pith_number":"pith:BOBWSTYY","schema_version":"1.0","canonical_sha256":"0b83694f184697affa7d6e4e4c5d646668660d29a0458cae52b02a12d5dc328f","source":{"kind":"arxiv","id":"2207.13073","version":1},"attestation_state":"computed","paper":{"title":"Three-dimensional operando optical imaging of single particle and electrolyte heterogeneities inside Li-ion batteries","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Alexis Grimaud, Angus Mathieson, Fei Xia, Florian Dorchies, Hilton B. de Aguiar, Jean-Marie Tarascon, Jeffrey Mc Hugh, Jien Hwee Tan, Lorenzo Valzania, Michael De Volder, Raj Pandya, Sylvain Gigan, Thomas G. Parton","submitted_at":"2022-06-27T15:23:42Z","abstract_excerpt":"Understanding (de)lithiation heterogeneities in battery materials is key to ensuring optimal electrochemical performance and developing better energy storage devices. However, this remains challenging due to the complex three dimensional morphology of microscopic electrode particles, the involvement of both solid and liquid phase reactants, and range of relevant timescales (seconds to hours). Here, we overcome this problem and demonstrate the use of bench-top laser scanning confocal microscopy for simultaneous three-dimensional operando measurement of lithium ion dynamics in single particles, "},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2207.13073","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-06-27T15:23:42Z","cross_cats_sorted":[],"title_canon_sha256":"b23f03a8cacc88033c2f3b9034ab231f745a09f6b87fc4aaf4704fb43af3498e","abstract_canon_sha256":"0cc12b9d5dfc00295f225209dafa7e2e53773d9ebb8fd33af91262823baad001"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:43:55.044692Z","signature_b64":"/78Rb4HP3IlXm5+BeIsU8kpxH3YuCSksWEn4AemFJKuHtK0Ljcine1wYbdjpn7KpMl5BBJf76p2M86JtiH0EAQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"0b83694f184697affa7d6e4e4c5d646668660d29a0458cae52b02a12d5dc328f","last_reissued_at":"2026-07-05T04:43:55.044211Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:43:55.044211Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Three-dimensional operando optical imaging of single particle and electrolyte heterogeneities inside Li-ion batteries","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Alexis Grimaud, Angus Mathieson, Fei Xia, Florian Dorchies, Hilton B. de Aguiar, Jean-Marie Tarascon, Jeffrey Mc Hugh, Jien Hwee Tan, Lorenzo Valzania, Michael De Volder, Raj Pandya, Sylvain Gigan, Thomas G. Parton","submitted_at":"2022-06-27T15:23:42Z","abstract_excerpt":"Understanding (de)lithiation heterogeneities in battery materials is key to ensuring optimal electrochemical performance and developing better energy storage devices. However, this remains challenging due to the complex three dimensional morphology of microscopic electrode particles, the involvement of both solid and liquid phase reactants, and range of relevant timescales (seconds to hours). Here, we overcome this problem and demonstrate the use of bench-top laser scanning confocal microscopy for simultaneous three-dimensional operando measurement of lithium ion dynamics in single particles, "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2207.13073","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2207.13073/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2207.13073","created_at":"2026-07-05T04:43:55.044279+00:00"},{"alias_kind":"arxiv_version","alias_value":"2207.13073v1","created_at":"2026-07-05T04:43:55.044279+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2207.13073","created_at":"2026-07-05T04:43:55.044279+00:00"},{"alias_kind":"pith_short_12","alias_value":"BOBWSTYYI2L2","created_at":"2026-07-05T04:43:55.044279+00:00"},{"alias_kind":"pith_short_16","alias_value":"BOBWSTYYI2L276T5","created_at":"2026-07-05T04:43:55.044279+00:00"},{"alias_kind":"pith_short_8","alias_value":"BOBWSTYY","created_at":"2026-07-05T04:43:55.044279+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ","json":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ.json","graph_json":"https://pith.science/api/pith-number/BOBWSTYYI2L276T5NZHEYXLEMZ/graph.json","events_json":"https://pith.science/api/pith-number/BOBWSTYYI2L276T5NZHEYXLEMZ/events.json","paper":"https://pith.science/paper/BOBWSTYY"},"agent_actions":{"view_html":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ","download_json":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ.json","view_paper":"https://pith.science/paper/BOBWSTYY","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2207.13073&json=true","fetch_graph":"https://pith.science/api/pith-number/BOBWSTYYI2L276T5NZHEYXLEMZ/graph.json","fetch_events":"https://pith.science/api/pith-number/BOBWSTYYI2L276T5NZHEYXLEMZ/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ/action/timestamp_anchor","attest_storage":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ/action/storage_attestation","attest_author":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ/action/author_attestation","sign_citation":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ/action/citation_signature","submit_replication":"https://pith.science/pith/BOBWSTYYI2L276T5NZHEYXLEMZ/action/replication_record"}},"created_at":"2026-07-05T04:43:55.044279+00:00","updated_at":"2026-07-05T04:43:55.044279+00:00"}