{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2019:BOPRI22HGPOJG4XSHZKYVTH77Y","short_pith_number":"pith:BOPRI22H","canonical_record":{"source":{"id":"1905.03596","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2019-05-09T13:18:32Z","cross_cats_sorted":[],"title_canon_sha256":"19243949189ff0d323c291d7a8de0e87821fb76a5c930dbe91cf44718d08ed88","abstract_canon_sha256":"748f769d7461fe90c084d40a95c625a181575b4e8522429ec441a51431ce8dc6"},"schema_version":"1.0"},"canonical_sha256":"0b9f146b4733dc9372f23e558accfffe0cc8305afbbbce98584915bbbe250b6f","source":{"kind":"arxiv","id":"1905.03596","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1905.03596","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"arxiv_version","alias_value":"1905.03596v1","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1905.03596","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"pith_short_12","alias_value":"BOPRI22HGPOJ","created_at":"2026-05-18T12:33:12Z"},{"alias_kind":"pith_short_16","alias_value":"BOPRI22HGPOJG4XS","created_at":"2026-05-18T12:33:12Z"},{"alias_kind":"pith_short_8","alias_value":"BOPRI22H","created_at":"2026-05-18T12:33:12Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2019:BOPRI22HGPOJG4XSHZKYVTH77Y","target":"record","payload":{"canonical_record":{"source":{"id":"1905.03596","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2019-05-09T13:18:32Z","cross_cats_sorted":[],"title_canon_sha256":"19243949189ff0d323c291d7a8de0e87821fb76a5c930dbe91cf44718d08ed88","abstract_canon_sha256":"748f769d7461fe90c084d40a95c625a181575b4e8522429ec441a51431ce8dc6"},"schema_version":"1.0"},"canonical_sha256":"0b9f146b4733dc9372f23e558accfffe0cc8305afbbbce98584915bbbe250b6f","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-17T23:46:37.255470Z","signature_b64":"3j1+PRufn/A/rDbrX7N7oMFwPX3Ay4jLbGRXCccAAqyc+nEAtGBq2qYwf70GexFISPalFq9UlohhnBZ7OYepDQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"0b9f146b4733dc9372f23e558accfffe0cc8305afbbbce98584915bbbe250b6f","last_reissued_at":"2026-05-17T23:46:37.254761Z","signature_status":"signed_v1","first_computed_at":"2026-05-17T23:46:37.254761Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1905.03596","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:46:37Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"S/B/AB0Talfye9O+ZvZyjbR0a82YjeStHXJ0dU6ZA2f8H2zdhVovM9CHI82n1fB3eskBV6AcVLmLTLBY4B5UAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T20:45:20.216779Z"},"content_sha256":"c10a792ac6b00a3871ad8d15aef6dc09ef2103785667195370e5dbc89e378e05","schema_version":"1.0","event_id":"sha256:c10a792ac6b00a3871ad8d15aef6dc09ef2103785667195370e5dbc89e378e05"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2019:BOPRI22HGPOJG4XSHZKYVTH77Y","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Multiple orbital effects in laser-induced electron diffraction of aligned molecules","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Angel Rubio, Arnaud Rouz\\'ee, Biagio Frusteri, Faruk Kre\\v{c}ini\\'c, Felix Brau{\\ss}e, Jean-Gabriel Brisset, Marc J.J. Vrakking, Philipp Wopperer, Umberto De Giovannini","submitted_at":"2019-05-09T13:18:32Z","abstract_excerpt":"Photoelectron Angular Distributions (PADs) resulting from 800 nm and 1300 nm strong field ionization of impulsively aligned CF$_3$I molecules were analyzed using time-dependent density functional theory (TDDFT). The normalized difference between the PADs for aligned and anti-aligned molecules displays large modulations in the high-energy re-collision plateau that are assigned to the diffraction of back-scattered photoelectrons. The TDDFT calculations reveal that, in spite of their 2.6 eV energy difference, ionization from the HOMO-1 orbital contributes to the diffraction pattern on the same fo"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1905.03596","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:46:37Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"iZqtui/bTUXt2ceazjHFAWav3sfB3fpLJ5ylG2aeiJyjRwWx4q6Z/YqPgqmVo2tha20KvFuYFt0inR21ngwvDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T20:45:20.217507Z"},"content_sha256":"a19b12650f7073fed45b8ecc6e5d2e858b829e79883dd7994902e73bee394ca7","schema_version":"1.0","event_id":"sha256:a19b12650f7073fed45b8ecc6e5d2e858b829e79883dd7994902e73bee394ca7"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/bundle.json","state_url":"https://pith.science/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-07T20:45:20Z","links":{"resolver":"https://pith.science/pith/BOPRI22HGPOJG4XSHZKYVTH77Y","bundle":"https://pith.science/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/bundle.json","state":"https://pith.science/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/state.json","well_known_bundle":"https://pith.science/.well-known/pith/BOPRI22HGPOJG4XSHZKYVTH77Y/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2019:BOPRI22HGPOJG4XSHZKYVTH77Y","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"748f769d7461fe90c084d40a95c625a181575b4e8522429ec441a51431ce8dc6","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2019-05-09T13:18:32Z","title_canon_sha256":"19243949189ff0d323c291d7a8de0e87821fb76a5c930dbe91cf44718d08ed88"},"schema_version":"1.0","source":{"id":"1905.03596","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1905.03596","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"arxiv_version","alias_value":"1905.03596v1","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1905.03596","created_at":"2026-05-17T23:46:37Z"},{"alias_kind":"pith_short_12","alias_value":"BOPRI22HGPOJ","created_at":"2026-05-18T12:33:12Z"},{"alias_kind":"pith_short_16","alias_value":"BOPRI22HGPOJG4XS","created_at":"2026-05-18T12:33:12Z"},{"alias_kind":"pith_short_8","alias_value":"BOPRI22H","created_at":"2026-05-18T12:33:12Z"}],"graph_snapshots":[{"event_id":"sha256:a19b12650f7073fed45b8ecc6e5d2e858b829e79883dd7994902e73bee394ca7","target":"graph","created_at":"2026-05-17T23:46:37Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Photoelectron Angular Distributions (PADs) resulting from 800 nm and 1300 nm strong field ionization of impulsively aligned CF$_3$I molecules were analyzed using time-dependent density functional theory (TDDFT). The normalized difference between the PADs for aligned and anti-aligned molecules displays large modulations in the high-energy re-collision plateau that are assigned to the diffraction of back-scattered photoelectrons. The TDDFT calculations reveal that, in spite of their 2.6 eV energy difference, ionization from the HOMO-1 orbital contributes to the diffraction pattern on the same fo","authors_text":"Angel Rubio, Arnaud Rouz\\'ee, Biagio Frusteri, Faruk Kre\\v{c}ini\\'c, Felix Brau{\\ss}e, Jean-Gabriel Brisset, Marc J.J. Vrakking, Philipp Wopperer, Umberto De Giovannini","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2019-05-09T13:18:32Z","title":"Multiple orbital effects in laser-induced electron diffraction of aligned molecules"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1905.03596","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:c10a792ac6b00a3871ad8d15aef6dc09ef2103785667195370e5dbc89e378e05","target":"record","created_at":"2026-05-17T23:46:37Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"748f769d7461fe90c084d40a95c625a181575b4e8522429ec441a51431ce8dc6","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2019-05-09T13:18:32Z","title_canon_sha256":"19243949189ff0d323c291d7a8de0e87821fb76a5c930dbe91cf44718d08ed88"},"schema_version":"1.0","source":{"id":"1905.03596","kind":"arxiv","version":1}},"canonical_sha256":"0b9f146b4733dc9372f23e558accfffe0cc8305afbbbce98584915bbbe250b6f","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"0b9f146b4733dc9372f23e558accfffe0cc8305afbbbce98584915bbbe250b6f","first_computed_at":"2026-05-17T23:46:37.254761Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-17T23:46:37.254761Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"3j1+PRufn/A/rDbrX7N7oMFwPX3Ay4jLbGRXCccAAqyc+nEAtGBq2qYwf70GexFISPalFq9UlohhnBZ7OYepDQ==","signature_status":"signed_v1","signed_at":"2026-05-17T23:46:37.255470Z","signed_message":"canonical_sha256_bytes"},"source_id":"1905.03596","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:c10a792ac6b00a3871ad8d15aef6dc09ef2103785667195370e5dbc89e378e05","sha256:a19b12650f7073fed45b8ecc6e5d2e858b829e79883dd7994902e73bee394ca7"],"state_sha256":"d809df8a9a2ffe9ad6dc2f397e713c20d6efd2aefa7e60758ca0900b997c3937"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ejwxD85rm+tGl+V3wvxRjU1USNNiYLKuDZfd0Xikd6wZQWKsGm+8ZnGwy6igtMWN1vLXnU8JAQnuAYCx359xAQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-07T20:45:20.221044Z","bundle_sha256":"95eeba3c55be55b32a2cd7b2cab896a2aefa02922b50a38a9512313c67ca4065"}}