{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2023:BY347PHIOBSCIIFR7TKGAT64FT","short_pith_number":"pith:BY347PHI","canonical_record":{"source":{"id":"2309.05800","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-09-11T20:08:38Z","cross_cats_sorted":[],"title_canon_sha256":"8e3416cabb612b4c506b743dd1ff380a2b57e664c8b62c341355dbb43fbc90ac","abstract_canon_sha256":"a00fa5a77fdfc3958ffa509c94fd989e610e31d62d69bdd2275188f83191717b"},"schema_version":"1.0"},"canonical_sha256":"0e37cfbce870642420b1fcd4604fdc2ce5ec82f59ff349fd2388c4da4a6242b4","source":{"kind":"arxiv","id":"2309.05800","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2309.05800","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"arxiv_version","alias_value":"2309.05800v1","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2309.05800","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_12","alias_value":"BY347PHIOBSC","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_16","alias_value":"BY347PHIOBSCIIFR","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_8","alias_value":"BY347PHI","created_at":"2026-07-05T06:49:46Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2023:BY347PHIOBSCIIFR7TKGAT64FT","target":"record","payload":{"canonical_record":{"source":{"id":"2309.05800","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-09-11T20:08:38Z","cross_cats_sorted":[],"title_canon_sha256":"8e3416cabb612b4c506b743dd1ff380a2b57e664c8b62c341355dbb43fbc90ac","abstract_canon_sha256":"a00fa5a77fdfc3958ffa509c94fd989e610e31d62d69bdd2275188f83191717b"},"schema_version":"1.0"},"canonical_sha256":"0e37cfbce870642420b1fcd4604fdc2ce5ec82f59ff349fd2388c4da4a6242b4","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T06:49:46.832832Z","signature_b64":"8xBnviN66yWMSSZ0C/CtYxXHfen5xzGkOBPrArVswNdEXFk9s4sgzKLSDz1UcETs4y/If63GEFet+hC5THQTDg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"0e37cfbce870642420b1fcd4604fdc2ce5ec82f59ff349fd2388c4da4a6242b4","last_reissued_at":"2026-07-05T06:49:46.832385Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T06:49:46.832385Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2309.05800","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T06:49:46Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"MgS78hmKuIMI1FsSdlwUaXR2Dj0xQ6Ck9jBGxIW/ADKcwJ+z4rWDS1J0qSu6MQC2azpFVbahoebfJbglFs21Cw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T17:18:40.273310Z"},"content_sha256":"739fbcc05529d29ee81ed78121322a5e04dcc0269a88c3b53276fbb0e9ddf71d","schema_version":"1.0","event_id":"sha256:739fbcc05529d29ee81ed78121322a5e04dcc0269a88c3b53276fbb0e9ddf71d"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2023:BY347PHIOBSCIIFR7TKGAT64FT","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Selective formation of metastable polymorphs in solid-state synthesis","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Bin Ouyang, Christopher J. Bartel, Gerbrand Ceder, Haoyan Huo, KyuJung Jun, Leighanne C. Gallington, Nathan J. Szymanski, Tanjin He, Yan Zeng","submitted_at":"2023-09-11T20:08:38Z","abstract_excerpt":"Metastable polymorphs often result from the interplay between thermodynamics and kinetics. Despite advances in predictive synthesis for solution-based techniques, there remains a lack of methods to design solid-state reactions targeting metastable materials. Here, we introduce a theoretical framework to predict and control polymorph selectivity in solid-state reactions. This framework presents reaction energy as a rarely used handle for polymorph selection, which influences the role of surface energy in promoting the nucleation of metastable phases. Through in situ characterization and density"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2309.05800","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2309.05800/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T06:49:46Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BbOW77HsuqJYjHG6g5O1afos59rkPpVQRV/YrOTjmzokcYM84eIEHgP1Iv+m6MikwssndUO9VObuPVgZ2GnvAw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T17:18:40.273773Z"},"content_sha256":"965551f6073faa51e42e029efbbc63db34be1343f526766f9ee5a3bb745b1316","schema_version":"1.0","event_id":"sha256:965551f6073faa51e42e029efbbc63db34be1343f526766f9ee5a3bb745b1316"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/BY347PHIOBSCIIFR7TKGAT64FT/bundle.json","state_url":"https://pith.science/pith/BY347PHIOBSCIIFR7TKGAT64FT/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/BY347PHIOBSCIIFR7TKGAT64FT/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-06T17:18:40Z","links":{"resolver":"https://pith.science/pith/BY347PHIOBSCIIFR7TKGAT64FT","bundle":"https://pith.science/pith/BY347PHIOBSCIIFR7TKGAT64FT/bundle.json","state":"https://pith.science/pith/BY347PHIOBSCIIFR7TKGAT64FT/state.json","well_known_bundle":"https://pith.science/.well-known/pith/BY347PHIOBSCIIFR7TKGAT64FT/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2023:BY347PHIOBSCIIFR7TKGAT64FT","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"a00fa5a77fdfc3958ffa509c94fd989e610e31d62d69bdd2275188f83191717b","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-09-11T20:08:38Z","title_canon_sha256":"8e3416cabb612b4c506b743dd1ff380a2b57e664c8b62c341355dbb43fbc90ac"},"schema_version":"1.0","source":{"id":"2309.05800","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2309.05800","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"arxiv_version","alias_value":"2309.05800v1","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2309.05800","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_12","alias_value":"BY347PHIOBSC","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_16","alias_value":"BY347PHIOBSCIIFR","created_at":"2026-07-05T06:49:46Z"},{"alias_kind":"pith_short_8","alias_value":"BY347PHI","created_at":"2026-07-05T06:49:46Z"}],"graph_snapshots":[{"event_id":"sha256:965551f6073faa51e42e029efbbc63db34be1343f526766f9ee5a3bb745b1316","target":"graph","created_at":"2026-07-05T06:49:46Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2309.05800/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Metastable polymorphs often result from the interplay between thermodynamics and kinetics. Despite advances in predictive synthesis for solution-based techniques, there remains a lack of methods to design solid-state reactions targeting metastable materials. Here, we introduce a theoretical framework to predict and control polymorph selectivity in solid-state reactions. This framework presents reaction energy as a rarely used handle for polymorph selection, which influences the role of surface energy in promoting the nucleation of metastable phases. Through in situ characterization and density","authors_text":"Bin Ouyang, Christopher J. Bartel, Gerbrand Ceder, Haoyan Huo, KyuJung Jun, Leighanne C. Gallington, Nathan J. Szymanski, Tanjin He, Yan Zeng","cross_cats":[],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-09-11T20:08:38Z","title":"Selective formation of metastable polymorphs in solid-state synthesis"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2309.05800","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:739fbcc05529d29ee81ed78121322a5e04dcc0269a88c3b53276fbb0e9ddf71d","target":"record","created_at":"2026-07-05T06:49:46Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"a00fa5a77fdfc3958ffa509c94fd989e610e31d62d69bdd2275188f83191717b","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-09-11T20:08:38Z","title_canon_sha256":"8e3416cabb612b4c506b743dd1ff380a2b57e664c8b62c341355dbb43fbc90ac"},"schema_version":"1.0","source":{"id":"2309.05800","kind":"arxiv","version":1}},"canonical_sha256":"0e37cfbce870642420b1fcd4604fdc2ce5ec82f59ff349fd2388c4da4a6242b4","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"0e37cfbce870642420b1fcd4604fdc2ce5ec82f59ff349fd2388c4da4a6242b4","first_computed_at":"2026-07-05T06:49:46.832385Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T06:49:46.832385Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"8xBnviN66yWMSSZ0C/CtYxXHfen5xzGkOBPrArVswNdEXFk9s4sgzKLSDz1UcETs4y/If63GEFet+hC5THQTDg==","signature_status":"signed_v1","signed_at":"2026-07-05T06:49:46.832832Z","signed_message":"canonical_sha256_bytes"},"source_id":"2309.05800","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:739fbcc05529d29ee81ed78121322a5e04dcc0269a88c3b53276fbb0e9ddf71d","sha256:965551f6073faa51e42e029efbbc63db34be1343f526766f9ee5a3bb745b1316"],"state_sha256":"9f59c98f99110a28504c8b143b0bffba2cbe4d2031d2ca318443ca70bff31127"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BnqGScc8Neh6alwAY9q0BX60C/kyKaPwkElXJsv7wnkmYIjKit3FerytAF+rbTpkq12s4JF+wD7RcVrB8/0WDw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-06T17:18:40.276452Z","bundle_sha256":"0ede3939ec18f9cef7cddf3ae057054383ef0d5ab4a3f1a28ca4d3ba2915d341"}}