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Owing to the entropy dependence of the Mn yield in explosive thermonuclear burning, SNe Ia involving near Chandrasekhar-mass white dwarfs (WDs) are predicted to produce Mn to Fe ratios significantly exceeding those of SN Ia explosions involving sub-Chandrasekhar mass primary WDs. Of all current supernova explosion models, only SN Ia models involving near-Chandrasekhar mass WDs produce [Mn/Fe] > 0.0. 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