{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2025:CMIVEFVDPALVSEHA3YMVB6DO2H","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"dcadafa223a85ea87d9da51b6bcacf780e17c890e64379da16d44508d032994b","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2025-06-09T12:11:30Z","title_canon_sha256":"6a922acf81a8df862546d9eefd48c3b44491bf27c14cecd81048ed309ba6301f"},"schema_version":"1.0","source":{"id":"2506.07682","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2506.07682","created_at":"2026-07-05T11:18:31Z"},{"alias_kind":"arxiv_version","alias_value":"2506.07682v1","created_at":"2026-07-05T11:18:31Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2506.07682","created_at":"2026-07-05T11:18:31Z"},{"alias_kind":"pith_short_12","alias_value":"CMIVEFVDPALV","created_at":"2026-07-05T11:18:31Z"},{"alias_kind":"pith_short_16","alias_value":"CMIVEFVDPALVSEHA","created_at":"2026-07-05T11:18:31Z"},{"alias_kind":"pith_short_8","alias_value":"CMIVEFVD","created_at":"2026-07-05T11:18:31Z"}],"graph_snapshots":[{"event_id":"sha256:1abbbfec73eb8aa66477590a63fa012bfa7011f913642aaf1828b0000f60e148","target":"graph","created_at":"2026-07-05T11:18:31Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2506.07682/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"A pillar of our current understanding of the photoluminescence of Ir(III) complexes is the assumption that the population of triplet metal-centered states determines an efficient non-radiative decay to the ground state minimum. Based on that assumption, the energy separation between the emitting state and the minimum-energy crossing point of the triplet metal-centered and the ground states has been employed as a key variable for evaluating the ability of Ir(III) complexes to decay non-radiatively. We demonstrate that the strong spin-orbit coupling between the triplet metal-centered and the gro","authors_text":"Angelo Giussani, Enrique Orti, Ilya D. Dergachev, Ivan Soriano-Diaz, Sergey A. Varganov","cross_cats":["cond-mat.mtrl-sci"],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2025-06-09T12:11:30Z","title":"The role of spin-orbit coupling and state-crossing topography in the non-radiative decay of Ir(III) complexes"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2506.07682","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:4b1d989e8e05d910038fdb2f2e3ed56400a574a1f46dd44ada6503fa6e9b6047","target":"record","created_at":"2026-07-05T11:18:31Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"dcadafa223a85ea87d9da51b6bcacf780e17c890e64379da16d44508d032994b","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2025-06-09T12:11:30Z","title_canon_sha256":"6a922acf81a8df862546d9eefd48c3b44491bf27c14cecd81048ed309ba6301f"},"schema_version":"1.0","source":{"id":"2506.07682","kind":"arxiv","version":1}},"canonical_sha256":"13115216a378175910e0de1950f86ed1c028248fbcb2f3327b6cbc7eb7e67150","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"13115216a378175910e0de1950f86ed1c028248fbcb2f3327b6cbc7eb7e67150","first_computed_at":"2026-07-05T11:18:31.500186Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T11:18:31.500186Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"HmzpoJBWgmshcbtqJhXVuAoQv1nxPGzckVedzmAHRZ7s+IjGtC6KM6eaNQpijeaXJyfI72IQCny4TdtQL/NlBQ==","signature_status":"signed_v1","signed_at":"2026-07-05T11:18:31.500661Z","signed_message":"canonical_sha256_bytes"},"source_id":"2506.07682","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:4b1d989e8e05d910038fdb2f2e3ed56400a574a1f46dd44ada6503fa6e9b6047","sha256:1abbbfec73eb8aa66477590a63fa012bfa7011f913642aaf1828b0000f60e148"],"state_sha256":"cb446981499418dfc1a19633d98b9443b710f373f8aa54dd264d94bdbf6692d8"}