{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2025:CS5VD2XLJ3WD5LUVXKQVSFGD3Q","short_pith_number":"pith:CS5VD2XL","schema_version":"1.0","canonical_sha256":"14bb51eaeb4eec3eae95baa15914c3dc11f37b8ad6c4dd26051dd763f4a1f703","source":{"kind":"arxiv","id":"2503.09834","version":1},"attestation_state":"computed","paper":{"title":"Beyond Epitaxy: Ion Implantation as a New Tool for Orbital Engineering","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Andreas Herklotz, Jonathan R. Petrie, Thomas Z. Ward","submitted_at":"2025-03-12T20:56:11Z","abstract_excerpt":"Manipulating electronic orbital states in quantum materials provides a powerful means to control their physical properties and technological functionality. Here, we demonstrate that orbital populations in strongly correlated oxide thin films can be continuously and reversibly tuned through post-synthesis He ion implantation. Using LaNiO$_3$ as a model system, we show that the orbital preference can be systematically adjusted from favoring in-plane d$_{x^2-y^2}$ occupation toward out-of-plane d$_{z^2}$ states through precise control of ion fluence. X-ray linear dichroism measurements reveal thi"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2503.09834","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2025-03-12T20:56:11Z","cross_cats_sorted":[],"title_canon_sha256":"ec180f2bf9dc212c65d81ef2adae59b62f30e6870a43749a802b3b8798f49ae1","abstract_canon_sha256":"4109c11aaf98a81ce754489c57c3d5b5987d861d26851b9c5c8e1e67094c7e03"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T10:30:09.597859Z","signature_b64":"2irlk+Xk1WBQLHPAvhaBgxvZJIdzck/p+626Qk2HIHQJQU/8Hs5rOxcxOoJFavTD0Ykz+TNsZzCBeZiTI9TmAQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"14bb51eaeb4eec3eae95baa15914c3dc11f37b8ad6c4dd26051dd763f4a1f703","last_reissued_at":"2026-07-05T10:30:09.597267Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T10:30:09.597267Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Beyond Epitaxy: Ion Implantation as a New Tool for Orbital Engineering","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Andreas Herklotz, Jonathan R. Petrie, Thomas Z. Ward","submitted_at":"2025-03-12T20:56:11Z","abstract_excerpt":"Manipulating electronic orbital states in quantum materials provides a powerful means to control their physical properties and technological functionality. Here, we demonstrate that orbital populations in strongly correlated oxide thin films can be continuously and reversibly tuned through post-synthesis He ion implantation. Using LaNiO$_3$ as a model system, we show that the orbital preference can be systematically adjusted from favoring in-plane d$_{x^2-y^2}$ occupation toward out-of-plane d$_{z^2}$ states through precise control of ion fluence. X-ray linear dichroism measurements reveal thi"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2503.09834","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2503.09834/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2503.09834","created_at":"2026-07-05T10:30:09.597364+00:00"},{"alias_kind":"arxiv_version","alias_value":"2503.09834v1","created_at":"2026-07-05T10:30:09.597364+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2503.09834","created_at":"2026-07-05T10:30:09.597364+00:00"},{"alias_kind":"pith_short_12","alias_value":"CS5VD2XLJ3WD","created_at":"2026-07-05T10:30:09.597364+00:00"},{"alias_kind":"pith_short_16","alias_value":"CS5VD2XLJ3WD5LUV","created_at":"2026-07-05T10:30:09.597364+00:00"},{"alias_kind":"pith_short_8","alias_value":"CS5VD2XL","created_at":"2026-07-05T10:30:09.597364+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q","json":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q.json","graph_json":"https://pith.science/api/pith-number/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/graph.json","events_json":"https://pith.science/api/pith-number/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/events.json","paper":"https://pith.science/paper/CS5VD2XL"},"agent_actions":{"view_html":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q","download_json":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q.json","view_paper":"https://pith.science/paper/CS5VD2XL","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2503.09834&json=true","fetch_graph":"https://pith.science/api/pith-number/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/graph.json","fetch_events":"https://pith.science/api/pith-number/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/action/timestamp_anchor","attest_storage":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/action/storage_attestation","attest_author":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/action/author_attestation","sign_citation":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/action/citation_signature","submit_replication":"https://pith.science/pith/CS5VD2XLJ3WD5LUVXKQVSFGD3Q/action/replication_record"}},"created_at":"2026-07-05T10:30:09.597364+00:00","updated_at":"2026-07-05T10:30:09.597364+00:00"}