{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:CXQCH3ZGZBGERXYB73KSDZ7Q6X","short_pith_number":"pith:CXQCH3ZG","canonical_record":{"source":{"id":"1606.02663","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2016-06-08T18:00:26Z","cross_cats_sorted":[],"title_canon_sha256":"ca7330a726ec63aa4e63da21566dcc64e5e6afe62482899a272631c0ae4e72bb","abstract_canon_sha256":"c1b44e6c1253a5b571ef12df04a2097af643a8987aec867a7253801f3e459aae"},"schema_version":"1.0"},"canonical_sha256":"15e023ef26c84c48df01fed521e7f0f5f0e8954bb4f08a5342b0952e78cc259f","source":{"kind":"arxiv","id":"1606.02663","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1606.02663","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"arxiv_version","alias_value":"1606.02663v2","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1606.02663","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"pith_short_12","alias_value":"CXQCH3ZGZBGE","created_at":"2026-05-18T12:30:09Z"},{"alias_kind":"pith_short_16","alias_value":"CXQCH3ZGZBGERXYB","created_at":"2026-05-18T12:30:09Z"},{"alias_kind":"pith_short_8","alias_value":"CXQCH3ZG","created_at":"2026-05-18T12:30:09Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:CXQCH3ZGZBGERXYB73KSDZ7Q6X","target":"record","payload":{"canonical_record":{"source":{"id":"1606.02663","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2016-06-08T18:00:26Z","cross_cats_sorted":[],"title_canon_sha256":"ca7330a726ec63aa4e63da21566dcc64e5e6afe62482899a272631c0ae4e72bb","abstract_canon_sha256":"c1b44e6c1253a5b571ef12df04a2097af643a8987aec867a7253801f3e459aae"},"schema_version":"1.0"},"canonical_sha256":"15e023ef26c84c48df01fed521e7f0f5f0e8954bb4f08a5342b0952e78cc259f","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:41:01.952162Z","signature_b64":"TlwANKcgCwuAFU1GyHlgDl+086FKphYxwdm0ca1Fom6MKV0bZEapgFAbQKmD1yG3QFM68toCQ4ghOw+O/hsaCw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"15e023ef26c84c48df01fed521e7f0f5f0e8954bb4f08a5342b0952e78cc259f","last_reissued_at":"2026-05-18T00:41:01.951707Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:41:01.951707Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1606.02663","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:41:01Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"lks57nNReStlQTD6rjVysM90M4Xbol4b1Yg6BjzIYjCr58cc89VJXEqUdvT8/alkmk1FAJoF2SiiKTzdohH0DA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T00:35:56.022403Z"},"content_sha256":"054b7aa13070b4fb15a5bcb17041a0375990c8170a758c9f2f27342997d8719a","schema_version":"1.0","event_id":"sha256:054b7aa13070b4fb15a5bcb17041a0375990c8170a758c9f2f27342997d8719a"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:CXQCH3ZGZBGERXYB73KSDZ7Q6X","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Imaging the Breakdown of Molecular-Frame Dynamics through Rotational Uncoupling","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.atm-clus","authors_text":"Adi Natan, Lucas J. Zipp, Philip H. Bucksbaum","submitted_at":"2016-06-08T18:00:26Z","abstract_excerpt":"We demonstrate the breakdown of molecular-frame dynamics induced by the uncoupling of molecular rotation from electronic motion in molecular Rydberg states. We observe this non-Born-Oppenheimer regime in the time domain through photoelectron imaging of a coherent molecular Rydberg wave packet in $\\textrm{N}_2$. The photoelectron angular distribution shows a radically different time evolution than that of a typical molecular-frame-fixed electron orbital, revealing the uncoupled motion of the electron as it precesses around the $averaged$ anisotropic potential of the rotating ion-core."},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1606.02663","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:41:01Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"QDwAWJbv2jSXEI5NEiYMhzdahzrOZHQ5Uji/q8vu/zGKoS3QaWLQTc2oL+Dv7wxsgWXgFovlLDeIClCi+zoqAw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T00:35:56.023050Z"},"content_sha256":"46ef53b890bb77d2d8e44703ab92192a1b301644486f113fd131ffccec4ea063","schema_version":"1.0","event_id":"sha256:46ef53b890bb77d2d8e44703ab92192a1b301644486f113fd131ffccec4ea063"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/bundle.json","state_url":"https://pith.science/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-27T00:35:56Z","links":{"resolver":"https://pith.science/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X","bundle":"https://pith.science/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/bundle.json","state":"https://pith.science/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/state.json","well_known_bundle":"https://pith.science/.well-known/pith/CXQCH3ZGZBGERXYB73KSDZ7Q6X/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:CXQCH3ZGZBGERXYB73KSDZ7Q6X","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"c1b44e6c1253a5b571ef12df04a2097af643a8987aec867a7253801f3e459aae","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2016-06-08T18:00:26Z","title_canon_sha256":"ca7330a726ec63aa4e63da21566dcc64e5e6afe62482899a272631c0ae4e72bb"},"schema_version":"1.0","source":{"id":"1606.02663","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1606.02663","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"arxiv_version","alias_value":"1606.02663v2","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1606.02663","created_at":"2026-05-18T00:41:01Z"},{"alias_kind":"pith_short_12","alias_value":"CXQCH3ZGZBGE","created_at":"2026-05-18T12:30:09Z"},{"alias_kind":"pith_short_16","alias_value":"CXQCH3ZGZBGERXYB","created_at":"2026-05-18T12:30:09Z"},{"alias_kind":"pith_short_8","alias_value":"CXQCH3ZG","created_at":"2026-05-18T12:30:09Z"}],"graph_snapshots":[{"event_id":"sha256:46ef53b890bb77d2d8e44703ab92192a1b301644486f113fd131ffccec4ea063","target":"graph","created_at":"2026-05-18T00:41:01Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We demonstrate the breakdown of molecular-frame dynamics induced by the uncoupling of molecular rotation from electronic motion in molecular Rydberg states. We observe this non-Born-Oppenheimer regime in the time domain through photoelectron imaging of a coherent molecular Rydberg wave packet in $\\textrm{N}_2$. The photoelectron angular distribution shows a radically different time evolution than that of a typical molecular-frame-fixed electron orbital, revealing the uncoupled motion of the electron as it precesses around the $averaged$ anisotropic potential of the rotating ion-core.","authors_text":"Adi Natan, Lucas J. Zipp, Philip H. Bucksbaum","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2016-06-08T18:00:26Z","title":"Imaging the Breakdown of Molecular-Frame Dynamics through Rotational Uncoupling"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1606.02663","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:054b7aa13070b4fb15a5bcb17041a0375990c8170a758c9f2f27342997d8719a","target":"record","created_at":"2026-05-18T00:41:01Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"c1b44e6c1253a5b571ef12df04a2097af643a8987aec867a7253801f3e459aae","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2016-06-08T18:00:26Z","title_canon_sha256":"ca7330a726ec63aa4e63da21566dcc64e5e6afe62482899a272631c0ae4e72bb"},"schema_version":"1.0","source":{"id":"1606.02663","kind":"arxiv","version":2}},"canonical_sha256":"15e023ef26c84c48df01fed521e7f0f5f0e8954bb4f08a5342b0952e78cc259f","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"15e023ef26c84c48df01fed521e7f0f5f0e8954bb4f08a5342b0952e78cc259f","first_computed_at":"2026-05-18T00:41:01.951707Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:41:01.951707Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"TlwANKcgCwuAFU1GyHlgDl+086FKphYxwdm0ca1Fom6MKV0bZEapgFAbQKmD1yG3QFM68toCQ4ghOw+O/hsaCw==","signature_status":"signed_v1","signed_at":"2026-05-18T00:41:01.952162Z","signed_message":"canonical_sha256_bytes"},"source_id":"1606.02663","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:054b7aa13070b4fb15a5bcb17041a0375990c8170a758c9f2f27342997d8719a","sha256:46ef53b890bb77d2d8e44703ab92192a1b301644486f113fd131ffccec4ea063"],"state_sha256":"cf040f585d913583b032fe50102dd5f33e8c05139bd41d84b8662f9f35816b89"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Vq1uQuI1q/XbkSorEUxb+P5yyuCTAyb37WjPU+6giAZynTAc4t6fSNKTGTTd2+7bq/ApMzXxhAlD6F5fAEaKBQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-27T00:35:56.026069Z","bundle_sha256":"152ac043f80f8754e379c9d36ff0b345104808c8d1a60583e6690d9b2caf66b1"}}