{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2008:CYAVCG3CT3ZHR2DZL4PBDJWNKR","short_pith_number":"pith:CYAVCG3C","canonical_record":{"source":{"id":"0802.0625","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/publicdomain/","primary_cat":"physics.chem-ph","submitted_at":"2008-02-05T02:42:25Z","cross_cats_sorted":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"title_canon_sha256":"3a8a6e5633af2353ca53e756fbf16f2670a82150704aaf86d8b8d70acbc1ff80","abstract_canon_sha256":"255e5e80afc9082f6952f8536016b28fe04841403369469ce7321ffbed7493ce"},"schema_version":"1.0"},"canonical_sha256":"1601511b629ef278e8795f1e11a6cd5459af5f58413caf61db62cfc2252df1d9","source":{"kind":"arxiv","id":"0802.0625","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0802.0625","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"arxiv_version","alias_value":"0802.0625v1","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0802.0625","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"pith_short_12","alias_value":"CYAVCG3CT3ZH","created_at":"2026-05-18T12:25:57Z"},{"alias_kind":"pith_short_16","alias_value":"CYAVCG3CT3ZHR2DZ","created_at":"2026-05-18T12:25:57Z"},{"alias_kind":"pith_short_8","alias_value":"CYAVCG3C","created_at":"2026-05-18T12:25:57Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2008:CYAVCG3CT3ZHR2DZL4PBDJWNKR","target":"record","payload":{"canonical_record":{"source":{"id":"0802.0625","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/publicdomain/","primary_cat":"physics.chem-ph","submitted_at":"2008-02-05T02:42:25Z","cross_cats_sorted":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"title_canon_sha256":"3a8a6e5633af2353ca53e756fbf16f2670a82150704aaf86d8b8d70acbc1ff80","abstract_canon_sha256":"255e5e80afc9082f6952f8536016b28fe04841403369469ce7321ffbed7493ce"},"schema_version":"1.0"},"canonical_sha256":"1601511b629ef278e8795f1e11a6cd5459af5f58413caf61db62cfc2252df1d9","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:05:13.804614Z","signature_b64":"gwXlc5mqV9HW2OvMyImqno64sY8HFnT5I1eUfL3OENzMJuuarV4YiWrh4y1HgK6fu6ter6xro4X73csXGCOzAg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"1601511b629ef278e8795f1e11a6cd5459af5f58413caf61db62cfc2252df1d9","last_reissued_at":"2026-05-18T01:05:13.804036Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:05:13.804036Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"0802.0625","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:05:13Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"cNti0DUB+oxk5bJwpYopcXEoDEjfvY1Gn+6b7ES3TOBu5mbMXt0g4V4caiGZcM+i/Zm5FLce+71YAibS8EBsDw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-01T13:43:41.833025Z"},"content_sha256":"7f44881534e871ad2970ef1afb32e5184b149e7a01edac29d59d729e756cabab","schema_version":"1.0","event_id":"sha256:7f44881534e871ad2970ef1afb32e5184b149e7a01edac29d59d729e756cabab"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2008:CYAVCG3CT3ZHR2DZL4PBDJWNKR","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Ab Initio Study of Different Acid Molecules Interacting with H2O","license":"http://creativecommons.org/licenses/publicdomain/","headline":"","cross_cats":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"primary_cat":"physics.chem-ph","authors_text":"Aleksey A. Zakharenko, K.S. Kim, S. Karthikyan","submitted_at":"2008-02-05T02:42:25Z","abstract_excerpt":"Using the Gaussian-03 for ab initio calculations, we have studied interaction of different acid molecules with a single water molecule. The molecular and supermolecular optimized structures were found with the Becke-3-Lee-Yang-Parr (B3LYP-hybrid potential) calculations of density-functional theory (DFT) methods as well as the Moeller-Plesset second-order perturbation theory, using the basis set of Aug-cc-pVDZ quality and the CRENBL ECP effective core potential for molecules containing heavy iodine atom. Possible isomers of studied acids and supermolecules, consisting of acid molecules coupled "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0802.0625","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:05:13Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"FLobq5vjMdtAA+UFs8rHIkRHr3FtNs0VHYjz5WmTrqvim5T3TzdVj1+KwMiVOjJ4tom0ccPSuSjcavb6dMYPBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-01T13:43:41.833394Z"},"content_sha256":"9c1bf5990ed8b5d8c7d14d1c4b1123d345702e64113bf29ffa47f54af4b6b6f8","schema_version":"1.0","event_id":"sha256:9c1bf5990ed8b5d8c7d14d1c4b1123d345702e64113bf29ffa47f54af4b6b6f8"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/bundle.json","state_url":"https://pith.science/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-01T13:43:41Z","links":{"resolver":"https://pith.science/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR","bundle":"https://pith.science/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/bundle.json","state":"https://pith.science/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/state.json","well_known_bundle":"https://pith.science/.well-known/pith/CYAVCG3CT3ZHR2DZL4PBDJWNKR/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2008:CYAVCG3CT3ZHR2DZL4PBDJWNKR","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"255e5e80afc9082f6952f8536016b28fe04841403369469ce7321ffbed7493ce","cross_cats_sorted":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"license":"http://creativecommons.org/licenses/publicdomain/","primary_cat":"physics.chem-ph","submitted_at":"2008-02-05T02:42:25Z","title_canon_sha256":"3a8a6e5633af2353ca53e756fbf16f2670a82150704aaf86d8b8d70acbc1ff80"},"schema_version":"1.0","source":{"id":"0802.0625","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0802.0625","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"arxiv_version","alias_value":"0802.0625v1","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0802.0625","created_at":"2026-05-18T01:05:13Z"},{"alias_kind":"pith_short_12","alias_value":"CYAVCG3CT3ZH","created_at":"2026-05-18T12:25:57Z"},{"alias_kind":"pith_short_16","alias_value":"CYAVCG3CT3ZHR2DZ","created_at":"2026-05-18T12:25:57Z"},{"alias_kind":"pith_short_8","alias_value":"CYAVCG3C","created_at":"2026-05-18T12:25:57Z"}],"graph_snapshots":[{"event_id":"sha256:9c1bf5990ed8b5d8c7d14d1c4b1123d345702e64113bf29ffa47f54af4b6b6f8","target":"graph","created_at":"2026-05-18T01:05:13Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Using the Gaussian-03 for ab initio calculations, we have studied interaction of different acid molecules with a single water molecule. The molecular and supermolecular optimized structures were found with the Becke-3-Lee-Yang-Parr (B3LYP-hybrid potential) calculations of density-functional theory (DFT) methods as well as the Moeller-Plesset second-order perturbation theory, using the basis set of Aug-cc-pVDZ quality and the CRENBL ECP effective core potential for molecules containing heavy iodine atom. Possible isomers of studied acids and supermolecules, consisting of acid molecules coupled ","authors_text":"Aleksey A. Zakharenko, K.S. Kim, S. Karthikyan","cross_cats":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"headline":"","license":"http://creativecommons.org/licenses/publicdomain/","primary_cat":"physics.chem-ph","submitted_at":"2008-02-05T02:42:25Z","title":"Ab Initio Study of Different Acid Molecules Interacting with H2O"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0802.0625","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:7f44881534e871ad2970ef1afb32e5184b149e7a01edac29d59d729e756cabab","target":"record","created_at":"2026-05-18T01:05:13Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"255e5e80afc9082f6952f8536016b28fe04841403369469ce7321ffbed7493ce","cross_cats_sorted":["physics.atm-clus","physics.bio-ph","physics.comp-ph","physics.med-ph","physics.space-ph"],"license":"http://creativecommons.org/licenses/publicdomain/","primary_cat":"physics.chem-ph","submitted_at":"2008-02-05T02:42:25Z","title_canon_sha256":"3a8a6e5633af2353ca53e756fbf16f2670a82150704aaf86d8b8d70acbc1ff80"},"schema_version":"1.0","source":{"id":"0802.0625","kind":"arxiv","version":1}},"canonical_sha256":"1601511b629ef278e8795f1e11a6cd5459af5f58413caf61db62cfc2252df1d9","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"1601511b629ef278e8795f1e11a6cd5459af5f58413caf61db62cfc2252df1d9","first_computed_at":"2026-05-18T01:05:13.804036Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:05:13.804036Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"gwXlc5mqV9HW2OvMyImqno64sY8HFnT5I1eUfL3OENzMJuuarV4YiWrh4y1HgK6fu6ter6xro4X73csXGCOzAg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:05:13.804614Z","signed_message":"canonical_sha256_bytes"},"source_id":"0802.0625","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:7f44881534e871ad2970ef1afb32e5184b149e7a01edac29d59d729e756cabab","sha256:9c1bf5990ed8b5d8c7d14d1c4b1123d345702e64113bf29ffa47f54af4b6b6f8"],"state_sha256":"ddd91531f4bed705b5d2e53883859410b8293911fe69ce93b9ccaa29e5b0b698"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"s/2BdG6Ntgu/O+ffvG0BDlCgdeVl4pEbcW8OT8uF4aLYfzz/DmWM150RB3UE31lcSy30e8xpPGUO14KfIBKSDw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-01T13:43:41.835398Z","bundle_sha256":"afa07928fa40fa8be80f4aa5dd3019158528e201f98badc47030cad2ea7162a8"}}