{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2016:DTF27ZEGMB7SM23HLNISTMW55J","short_pith_number":"pith:DTF27ZEG","schema_version":"1.0","canonical_sha256":"1ccbafe486607f266b675b5129b2ddea403178a7df7fe0513f079051476120e0","source":{"kind":"arxiv","id":"1609.01020","version":1},"attestation_state":"computed","paper":{"title":"Cationic Effect on Pressure driven Spin-State Transition and cooperativity in Hybrid Perosvkites","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Hrishit Banerjee, Sudip Chakraborty, Tanusri Saha-Dasgupta","submitted_at":"2016-09-05T03:02:41Z","abstract_excerpt":"Hybrid or metal organic framework (MOF) perovskites of general composition, ABX$_3$, are known to show interesting properties which can lead to variety of technological applications. Our first principles study shows they are also potential candidates for exhibiting cooperative spin-state transitions upon application of external stimuli. We demonstrate this by considering two specific Fe-based MOF perovskites, namely Dimethylammonium Iron Formate, [CH$_{3}$NH$_{2}$CH$_{3}$][Fe(HCOO)$_3$] and Hydroxylammonium Iron Formate, [NH$_{3}$OH][Fe(HCOO)$_3$]. Both the compounds are found to undergo high-"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1609.01020","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-09-05T03:02:41Z","cross_cats_sorted":[],"title_canon_sha256":"4212f63106d4a17ed25bd09511f8be306eaa92ffe403620351728e796a7b01be","abstract_canon_sha256":"d8dee640fcba675a1fa9203ea37369a98c04299bc1b4715196b3381c0ef40474"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:06:19.267748Z","signature_b64":"TmEPA9wUUh3sKhpQDtsj/eb55jLok74HqV9H1gZ8ZGEW3xznzTVTGh6iBW+5M20HymO2MySnQLy46bZdUYDdDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"1ccbafe486607f266b675b5129b2ddea403178a7df7fe0513f079051476120e0","last_reissued_at":"2026-05-18T01:06:19.267051Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:06:19.267051Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Cationic Effect on Pressure driven Spin-State Transition and cooperativity in Hybrid Perosvkites","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Hrishit Banerjee, Sudip Chakraborty, Tanusri Saha-Dasgupta","submitted_at":"2016-09-05T03:02:41Z","abstract_excerpt":"Hybrid or metal organic framework (MOF) perovskites of general composition, ABX$_3$, are known to show interesting properties which can lead to variety of technological applications. Our first principles study shows they are also potential candidates for exhibiting cooperative spin-state transitions upon application of external stimuli. We demonstrate this by considering two specific Fe-based MOF perovskites, namely Dimethylammonium Iron Formate, [CH$_{3}$NH$_{2}$CH$_{3}$][Fe(HCOO)$_3$] and Hydroxylammonium Iron Formate, [NH$_{3}$OH][Fe(HCOO)$_3$]. Both the compounds are found to undergo high-"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1609.01020","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1609.01020","created_at":"2026-05-18T01:06:19.267161+00:00"},{"alias_kind":"arxiv_version","alias_value":"1609.01020v1","created_at":"2026-05-18T01:06:19.267161+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1609.01020","created_at":"2026-05-18T01:06:19.267161+00:00"},{"alias_kind":"pith_short_12","alias_value":"DTF27ZEGMB7S","created_at":"2026-05-18T12:30:12.583610+00:00"},{"alias_kind":"pith_short_16","alias_value":"DTF27ZEGMB7SM23H","created_at":"2026-05-18T12:30:12.583610+00:00"},{"alias_kind":"pith_short_8","alias_value":"DTF27ZEG","created_at":"2026-05-18T12:30:12.583610+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J","json":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J.json","graph_json":"https://pith.science/api/pith-number/DTF27ZEGMB7SM23HLNISTMW55J/graph.json","events_json":"https://pith.science/api/pith-number/DTF27ZEGMB7SM23HLNISTMW55J/events.json","paper":"https://pith.science/paper/DTF27ZEG"},"agent_actions":{"view_html":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J","download_json":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J.json","view_paper":"https://pith.science/paper/DTF27ZEG","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1609.01020&json=true","fetch_graph":"https://pith.science/api/pith-number/DTF27ZEGMB7SM23HLNISTMW55J/graph.json","fetch_events":"https://pith.science/api/pith-number/DTF27ZEGMB7SM23HLNISTMW55J/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J/action/timestamp_anchor","attest_storage":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J/action/storage_attestation","attest_author":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J/action/author_attestation","sign_citation":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J/action/citation_signature","submit_replication":"https://pith.science/pith/DTF27ZEGMB7SM23HLNISTMW55J/action/replication_record"}},"created_at":"2026-05-18T01:06:19.267161+00:00","updated_at":"2026-05-18T01:06:19.267161+00:00"}