{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2022:EFJ6MDGRU5CRPZC6X2GUNPOJG6","short_pith_number":"pith:EFJ6MDGR","canonical_record":{"source":{"id":"2204.02510","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-04-05T22:20:04Z","cross_cats_sorted":["physics.app-ph"],"title_canon_sha256":"72196279fd27c0cab9195b9b3e842762f56fa7dca3879f91e3eb9a1da9e66124","abstract_canon_sha256":"f9ca383e4e002c5131dc623d143583906deb29fb06209aeda3318bfaa3246cb4"},"schema_version":"1.0"},"canonical_sha256":"2153e60cd1a74517e45ebe8d46bdc937a6b580869e0924b3361c7d5adab22696","source":{"kind":"arxiv","id":"2204.02510","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2204.02510","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"arxiv_version","alias_value":"2204.02510v1","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2204.02510","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_12","alias_value":"EFJ6MDGRU5CR","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_16","alias_value":"EFJ6MDGRU5CRPZC6","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_8","alias_value":"EFJ6MDGR","created_at":"2026-07-05T04:12:09Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2022:EFJ6MDGRU5CRPZC6X2GUNPOJG6","target":"record","payload":{"canonical_record":{"source":{"id":"2204.02510","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-04-05T22:20:04Z","cross_cats_sorted":["physics.app-ph"],"title_canon_sha256":"72196279fd27c0cab9195b9b3e842762f56fa7dca3879f91e3eb9a1da9e66124","abstract_canon_sha256":"f9ca383e4e002c5131dc623d143583906deb29fb06209aeda3318bfaa3246cb4"},"schema_version":"1.0"},"canonical_sha256":"2153e60cd1a74517e45ebe8d46bdc937a6b580869e0924b3361c7d5adab22696","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:12:09.006200Z","signature_b64":"a/n9rlDcHqkwKUs+NUdnK4lhVh1uJLOXHb9U0t79McEs9KpT2BXeiuMIJL/YGl0/e3DInPTW09bGi6crvb4WCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2153e60cd1a74517e45ebe8d46bdc937a6b580869e0924b3361c7d5adab22696","last_reissued_at":"2026-07-05T04:12:09.005746Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:12:09.005746Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2204.02510","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:12:09Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"fDNLKJuKwPzMVrgNLnfRUqLmToZQBxJavfW8u6nZdpE30jgOfmGoeXevfiAXqVKpjkoM6GDyKb2LXvW9z58kCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-08T07:45:02.287933Z"},"content_sha256":"4d5d6160f84ac719ca0d838f2a9eca0c1c41197191d8969c9a22abd94c1e6be6","schema_version":"1.0","event_id":"sha256:4d5d6160f84ac719ca0d838f2a9eca0c1c41197191d8969c9a22abd94c1e6be6"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2022:EFJ6MDGRU5CRPZC6X2GUNPOJG6","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Unraveling the stable cathode electrolyte interface in all solid-state thin-film battery operating at 5V","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.app-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Bingyu Lu, Diyi Cheng, Guomin Zhu, Min-Cheol Kim, Minghao Zhang, Randall Burger, Ryosuke Shimizu, Thomas A. Wynn, Ying Shirley Meng","submitted_at":"2022-04-05T22:20:04Z","abstract_excerpt":"Spinel-type LiNi0.5Mn1.5O4 (LNMO) is one of the most promising 5 V-class cathode materials for Li-ion batteries that can achieve high energy density and low production costs. However, in liquid electrolyte cells, the high voltage causes continuous cell degradation through the oxidative decomposition of carbonate-based liquid electrolytes. In contrast, some solid-state electrolytes have a wide electrochemical stability range and can withstand the required oxidative potential. In this work, a thin-film battery consisting of a LNMO cathode with a solid lithium phosphorus oxynitride (LiPON) electr"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2204.02510","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2204.02510/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:12:09Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"gINqYtH74hvQak6znwIof/Q5pV8fB9OyTK7Zf59Fs3b7bxga8QVRAemOVVMx/zRYbWBvRglE7z3Roc4Ic2tTBA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-08T07:45:02.288335Z"},"content_sha256":"5f8af194441aa5e0d9767f1555b033b44090ba1e088dd2227a90f9e89c8a7bde","schema_version":"1.0","event_id":"sha256:5f8af194441aa5e0d9767f1555b033b44090ba1e088dd2227a90f9e89c8a7bde"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/bundle.json","state_url":"https://pith.science/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-08T07:45:02Z","links":{"resolver":"https://pith.science/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6","bundle":"https://pith.science/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/bundle.json","state":"https://pith.science/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/state.json","well_known_bundle":"https://pith.science/.well-known/pith/EFJ6MDGRU5CRPZC6X2GUNPOJG6/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2022:EFJ6MDGRU5CRPZC6X2GUNPOJG6","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"f9ca383e4e002c5131dc623d143583906deb29fb06209aeda3318bfaa3246cb4","cross_cats_sorted":["physics.app-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-04-05T22:20:04Z","title_canon_sha256":"72196279fd27c0cab9195b9b3e842762f56fa7dca3879f91e3eb9a1da9e66124"},"schema_version":"1.0","source":{"id":"2204.02510","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2204.02510","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"arxiv_version","alias_value":"2204.02510v1","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2204.02510","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_12","alias_value":"EFJ6MDGRU5CR","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_16","alias_value":"EFJ6MDGRU5CRPZC6","created_at":"2026-07-05T04:12:09Z"},{"alias_kind":"pith_short_8","alias_value":"EFJ6MDGR","created_at":"2026-07-05T04:12:09Z"}],"graph_snapshots":[{"event_id":"sha256:5f8af194441aa5e0d9767f1555b033b44090ba1e088dd2227a90f9e89c8a7bde","target":"graph","created_at":"2026-07-05T04:12:09Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2204.02510/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Spinel-type LiNi0.5Mn1.5O4 (LNMO) is one of the most promising 5 V-class cathode materials for Li-ion batteries that can achieve high energy density and low production costs. However, in liquid electrolyte cells, the high voltage causes continuous cell degradation through the oxidative decomposition of carbonate-based liquid electrolytes. In contrast, some solid-state electrolytes have a wide electrochemical stability range and can withstand the required oxidative potential. In this work, a thin-film battery consisting of a LNMO cathode with a solid lithium phosphorus oxynitride (LiPON) electr","authors_text":"Bingyu Lu, Diyi Cheng, Guomin Zhu, Min-Cheol Kim, Minghao Zhang, Randall Burger, Ryosuke Shimizu, Thomas A. Wynn, Ying Shirley Meng","cross_cats":["physics.app-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-04-05T22:20:04Z","title":"Unraveling the stable cathode electrolyte interface in all solid-state thin-film battery operating at 5V"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2204.02510","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:4d5d6160f84ac719ca0d838f2a9eca0c1c41197191d8969c9a22abd94c1e6be6","target":"record","created_at":"2026-07-05T04:12:09Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"f9ca383e4e002c5131dc623d143583906deb29fb06209aeda3318bfaa3246cb4","cross_cats_sorted":["physics.app-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-04-05T22:20:04Z","title_canon_sha256":"72196279fd27c0cab9195b9b3e842762f56fa7dca3879f91e3eb9a1da9e66124"},"schema_version":"1.0","source":{"id":"2204.02510","kind":"arxiv","version":1}},"canonical_sha256":"2153e60cd1a74517e45ebe8d46bdc937a6b580869e0924b3361c7d5adab22696","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2153e60cd1a74517e45ebe8d46bdc937a6b580869e0924b3361c7d5adab22696","first_computed_at":"2026-07-05T04:12:09.005746Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T04:12:09.005746Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"a/n9rlDcHqkwKUs+NUdnK4lhVh1uJLOXHb9U0t79McEs9KpT2BXeiuMIJL/YGl0/e3DInPTW09bGi6crvb4WCA==","signature_status":"signed_v1","signed_at":"2026-07-05T04:12:09.006200Z","signed_message":"canonical_sha256_bytes"},"source_id":"2204.02510","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:4d5d6160f84ac719ca0d838f2a9eca0c1c41197191d8969c9a22abd94c1e6be6","sha256:5f8af194441aa5e0d9767f1555b033b44090ba1e088dd2227a90f9e89c8a7bde"],"state_sha256":"6d83c787751a75a2d8e8814982e9b2369286795e2fec0479718fce9aee714c20"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"l/cXfDk64Xh2dzek9AerzMBkyzKuzr+FH9SXpKGkjCTOVMqWNJjfG5vK7yK50W9v86BZLlZWI3TsvKffCv+PAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-08T07:45:02.291077Z","bundle_sha256":"fb4b55ea932ef729c9e50a079491526aeda441caa2a9717b3cf40b2c558c5f28"}}