{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2021:F3ZH4J44G2ASXOM6PLQ4JKT2MA","short_pith_number":"pith:F3ZH4J44","canonical_record":{"source":{"id":"2109.00315","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-09-01T11:47:20Z","cross_cats_sorted":["physics.ao-ph"],"title_canon_sha256":"be57e461bb8c6bbf97df7a3b97c8123290506fa0e7db790c087fac8f44a7431b","abstract_canon_sha256":"910492e8af9888534d49d732a6283445653b245f5143081a35bfdc974f15b102"},"schema_version":"1.0"},"canonical_sha256":"2ef27e279c36812bb99e7ae1c4aa7a6034fa0327263153e4c5a6d7405aeff770","source":{"kind":"arxiv","id":"2109.00315","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2109.00315","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"arxiv_version","alias_value":"2109.00315v1","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2109.00315","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_12","alias_value":"F3ZH4J44G2AS","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_16","alias_value":"F3ZH4J44G2ASXOM6","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_8","alias_value":"F3ZH4J44","created_at":"2026-07-05T04:03:50Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2021:F3ZH4J44G2ASXOM6PLQ4JKT2MA","target":"record","payload":{"canonical_record":{"source":{"id":"2109.00315","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-09-01T11:47:20Z","cross_cats_sorted":["physics.ao-ph"],"title_canon_sha256":"be57e461bb8c6bbf97df7a3b97c8123290506fa0e7db790c087fac8f44a7431b","abstract_canon_sha256":"910492e8af9888534d49d732a6283445653b245f5143081a35bfdc974f15b102"},"schema_version":"1.0"},"canonical_sha256":"2ef27e279c36812bb99e7ae1c4aa7a6034fa0327263153e4c5a6d7405aeff770","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:03:50.796075Z","signature_b64":"j6avCy+/KFugSKOkWX7B0EjefAw3btWPlLfo3QMmZBvRUY8xnvyMDBsAlvUJtJJh5T08i5DsDqW3z4K6W1L4Dw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2ef27e279c36812bb99e7ae1c4aa7a6034fa0327263153e4c5a6d7405aeff770","last_reissued_at":"2026-07-05T04:03:50.795660Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:03:50.795660Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2109.00315","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:03:50Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"t7FjeDfkI778aeIq+0C/r1xsU5USSZuviZwR+Bov9tPcIgbbGh/YB3tKNUkNnC7OEfVscT/vM/niBsz6RMejAQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-12T05:54:37.572891Z"},"content_sha256":"1da49345e689be5fb79e401ee4926accd31a4a781abb7de74e4ee7031618930a","schema_version":"1.0","event_id":"sha256:1da49345e689be5fb79e401ee4926accd31a4a781abb7de74e4ee7031618930a"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2021:F3ZH4J44G2ASXOM6PLQ4JKT2MA","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Ozone formation in ternary collisions: Theory and experiment reconciled","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.ao-ph"],"primary_cat":"physics.chem-ph","authors_text":"2), (2) Department of Physics, (3) Quamer Laboratory, 4), (4) Groupe de Spectrometrie Mol\\'eculaire et Atmospherique, (5) Department of Physics, Berlin, Florida, France, Germany, Jes\\'us P\\'erez-R\\'ios (1, Marjan Mirahmadi (1), New York, Oleg Egorov (3), Reims, Russia, Stony Brook University, Tomsk, Tomsk State University, University of Central Florida, University of Reims Champagne-Ardenne, USA, USA), Viatcheslav Kokoouline (5) ((1) Fritz-Haber-Institut der Max-Planck-Gesellschaft, Vladimir Tyuterev (3","submitted_at":"2021-09-01T11:47:20Z","abstract_excerpt":"Absorbing UV radiation, ozone protects life on Earth and plays a fundamental role in Earth's temperature balance. The formation of ozone occurs through the ternary recombination reaction: O$_2$+O+M $\\rightarrow$ O$_3$+M, where M can be N$_2$, O$_2$ or Ar. Here, we developed a theoretical approach capable of modeling the formation of ozone molecules in ternary collisions, and applied it to the reaction with M=Ar because of extensive experimental data available. The rate coefficients for the direct formation of O$_3$ in ternary collisions O+O$_2$+Ar were computed for the first time as a function"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2109.00315","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2109.00315/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:03:50Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"tujb0nwLBi+OCf5tS3OOgkE0KXjl2XAQfARHd/CfQszGb0DSWP2z/oOKrv9ywQ2/Cult8AoWFHDCTdEQIE19BA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-12T05:54:37.573403Z"},"content_sha256":"ffbbbdfc7716d6af8c5f9567944c51f7c74a35226f0ee39cc07240f5d1c8d857","schema_version":"1.0","event_id":"sha256:ffbbbdfc7716d6af8c5f9567944c51f7c74a35226f0ee39cc07240f5d1c8d857"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/bundle.json","state_url":"https://pith.science/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-12T05:54:37Z","links":{"resolver":"https://pith.science/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA","bundle":"https://pith.science/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/bundle.json","state":"https://pith.science/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/state.json","well_known_bundle":"https://pith.science/.well-known/pith/F3ZH4J44G2ASXOM6PLQ4JKT2MA/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2021:F3ZH4J44G2ASXOM6PLQ4JKT2MA","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"910492e8af9888534d49d732a6283445653b245f5143081a35bfdc974f15b102","cross_cats_sorted":["physics.ao-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-09-01T11:47:20Z","title_canon_sha256":"be57e461bb8c6bbf97df7a3b97c8123290506fa0e7db790c087fac8f44a7431b"},"schema_version":"1.0","source":{"id":"2109.00315","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2109.00315","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"arxiv_version","alias_value":"2109.00315v1","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2109.00315","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_12","alias_value":"F3ZH4J44G2AS","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_16","alias_value":"F3ZH4J44G2ASXOM6","created_at":"2026-07-05T04:03:50Z"},{"alias_kind":"pith_short_8","alias_value":"F3ZH4J44","created_at":"2026-07-05T04:03:50Z"}],"graph_snapshots":[{"event_id":"sha256:ffbbbdfc7716d6af8c5f9567944c51f7c74a35226f0ee39cc07240f5d1c8d857","target":"graph","created_at":"2026-07-05T04:03:50Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2109.00315/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Absorbing UV radiation, ozone protects life on Earth and plays a fundamental role in Earth's temperature balance. The formation of ozone occurs through the ternary recombination reaction: O$_2$+O+M $\\rightarrow$ O$_3$+M, where M can be N$_2$, O$_2$ or Ar. Here, we developed a theoretical approach capable of modeling the formation of ozone molecules in ternary collisions, and applied it to the reaction with M=Ar because of extensive experimental data available. The rate coefficients for the direct formation of O$_3$ in ternary collisions O+O$_2$+Ar were computed for the first time as a function","authors_text":"2), (2) Department of Physics, (3) Quamer Laboratory, 4), (4) Groupe de Spectrometrie Mol\\'eculaire et Atmospherique, (5) Department of Physics, Berlin, Florida, France, Germany, Jes\\'us P\\'erez-R\\'ios (1, Marjan Mirahmadi (1), New York, Oleg Egorov (3), Reims, Russia, Stony Brook University, Tomsk, Tomsk State University, University of Central Florida, University of Reims Champagne-Ardenne, USA, USA), Viatcheslav Kokoouline (5) ((1) Fritz-Haber-Institut der Max-Planck-Gesellschaft, Vladimir Tyuterev (3","cross_cats":["physics.ao-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-09-01T11:47:20Z","title":"Ozone formation in ternary collisions: Theory and experiment reconciled"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2109.00315","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:1da49345e689be5fb79e401ee4926accd31a4a781abb7de74e4ee7031618930a","target":"record","created_at":"2026-07-05T04:03:50Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"910492e8af9888534d49d732a6283445653b245f5143081a35bfdc974f15b102","cross_cats_sorted":["physics.ao-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-09-01T11:47:20Z","title_canon_sha256":"be57e461bb8c6bbf97df7a3b97c8123290506fa0e7db790c087fac8f44a7431b"},"schema_version":"1.0","source":{"id":"2109.00315","kind":"arxiv","version":1}},"canonical_sha256":"2ef27e279c36812bb99e7ae1c4aa7a6034fa0327263153e4c5a6d7405aeff770","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2ef27e279c36812bb99e7ae1c4aa7a6034fa0327263153e4c5a6d7405aeff770","first_computed_at":"2026-07-05T04:03:50.795660Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T04:03:50.795660Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"j6avCy+/KFugSKOkWX7B0EjefAw3btWPlLfo3QMmZBvRUY8xnvyMDBsAlvUJtJJh5T08i5DsDqW3z4K6W1L4Dw==","signature_status":"signed_v1","signed_at":"2026-07-05T04:03:50.796075Z","signed_message":"canonical_sha256_bytes"},"source_id":"2109.00315","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:1da49345e689be5fb79e401ee4926accd31a4a781abb7de74e4ee7031618930a","sha256:ffbbbdfc7716d6af8c5f9567944c51f7c74a35226f0ee39cc07240f5d1c8d857"],"state_sha256":"7390eac1a17fed9a030e9f2b392ee1b8f7bb492d188066ad95dc4564fd1c0ace"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"VWkjo17BhGB0l71F0sek0etHKnTAAGzFis5+E+SWhCIofeEhAgEFkYBMEeAizi9UNguj9cxNjjHhuJlvHjmACQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-12T05:54:37.577946Z","bundle_sha256":"ed2f443e3af36da954f6c31efc17a3f16c222780133bb79899ba06cb4330b454"}}