{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2023:F5PAWEW6IW4MT3CMQSBCERIIMG","short_pith_number":"pith:F5PAWEW6","schema_version":"1.0","canonical_sha256":"2f5e0b12de45b8c9ec4c84822245086194df15aee79c2f173e4fdc6ded2cf782","source":{"kind":"arxiv","id":"2306.11831","version":1},"attestation_state":"computed","paper":{"title":"Simultaneous Single Crystal Growth and Segregation of Ni-Rich Cathode Enabled by Nanoscale Phase Separation for Advanced Lithium-Ion Batteries","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Chongmin Wang, Dianying Liu, Enyuan Hu, Jiangtao Hu, Jie Xiao, Jingnan Li, Jing Wu, Job Rijssenbeek, Liu Luo, Peng Zuo, Qiuyan Li, Ran Yi, Rebecca O Toole, Sha Tan, Subramanian Venkatachalam, Xiaoguang Hao, Yaobin Xu, Yujing Bi","submitted_at":"2023-06-20T18:42:03Z","abstract_excerpt":"Synthesis of high-performance single crystal LiNi0.8Mn0.1Co0.1O2 (NMC811) in the absence of molten salt is challenging with no success yet. An innovative drop-in approach is discovered to synthesize single crystal NMC811 by controlling the morphology of transition metal hydroxide TM(OH)2 precursors followed by a simple decomposition step to form transition metal oxide (TMO) intermediates. Ni redistribution in TMO, as a result of the concurrent formation of mixed spinel and rock salt phases, helps deagglomerate the later formed NMC811 clusters of single crystals. As-prepared single crystal NMC8"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2306.11831","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-06-20T18:42:03Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"a34047bb28d229644c468a9022b034bdcb4b5af1b99e3f460e312d8a9014b00e","abstract_canon_sha256":"13539bdd183a23e77cb5e24d86fb2e32e637b76f99973d32dcac29643ed35771"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T06:23:07.354636Z","signature_b64":"6kPJRlR9ikA+/6b1uVZEnCxu/9D5oxpeyUp7Xi1bR2ARfeuKr1Am18dmt5fSbQA3RGtfNELuk92KsnYcjt9BCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2f5e0b12de45b8c9ec4c84822245086194df15aee79c2f173e4fdc6ded2cf782","last_reissued_at":"2026-07-05T06:23:07.354062Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T06:23:07.354062Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Simultaneous Single Crystal Growth and Segregation of Ni-Rich Cathode Enabled by Nanoscale Phase Separation for Advanced Lithium-Ion Batteries","license":"http://creativecommons.org/licenses/by-nc-sa/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Chongmin Wang, Dianying Liu, Enyuan Hu, Jiangtao Hu, Jie Xiao, Jingnan Li, Jing Wu, Job Rijssenbeek, Liu Luo, Peng Zuo, Qiuyan Li, Ran Yi, Rebecca O Toole, Sha Tan, Subramanian Venkatachalam, Xiaoguang Hao, Yaobin Xu, Yujing Bi","submitted_at":"2023-06-20T18:42:03Z","abstract_excerpt":"Synthesis of high-performance single crystal LiNi0.8Mn0.1Co0.1O2 (NMC811) in the absence of molten salt is challenging with no success yet. An innovative drop-in approach is discovered to synthesize single crystal NMC811 by controlling the morphology of transition metal hydroxide TM(OH)2 precursors followed by a simple decomposition step to form transition metal oxide (TMO) intermediates. Ni redistribution in TMO, as a result of the concurrent formation of mixed spinel and rock salt phases, helps deagglomerate the later formed NMC811 clusters of single crystals. As-prepared single crystal NMC8"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2306.11831","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2306.11831/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2306.11831","created_at":"2026-07-05T06:23:07.354123+00:00"},{"alias_kind":"arxiv_version","alias_value":"2306.11831v1","created_at":"2026-07-05T06:23:07.354123+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2306.11831","created_at":"2026-07-05T06:23:07.354123+00:00"},{"alias_kind":"pith_short_12","alias_value":"F5PAWEW6IW4M","created_at":"2026-07-05T06:23:07.354123+00:00"},{"alias_kind":"pith_short_16","alias_value":"F5PAWEW6IW4MT3CM","created_at":"2026-07-05T06:23:07.354123+00:00"},{"alias_kind":"pith_short_8","alias_value":"F5PAWEW6","created_at":"2026-07-05T06:23:07.354123+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG","json":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG.json","graph_json":"https://pith.science/api/pith-number/F5PAWEW6IW4MT3CMQSBCERIIMG/graph.json","events_json":"https://pith.science/api/pith-number/F5PAWEW6IW4MT3CMQSBCERIIMG/events.json","paper":"https://pith.science/paper/F5PAWEW6"},"agent_actions":{"view_html":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG","download_json":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG.json","view_paper":"https://pith.science/paper/F5PAWEW6","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2306.11831&json=true","fetch_graph":"https://pith.science/api/pith-number/F5PAWEW6IW4MT3CMQSBCERIIMG/graph.json","fetch_events":"https://pith.science/api/pith-number/F5PAWEW6IW4MT3CMQSBCERIIMG/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG/action/timestamp_anchor","attest_storage":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG/action/storage_attestation","attest_author":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG/action/author_attestation","sign_citation":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG/action/citation_signature","submit_replication":"https://pith.science/pith/F5PAWEW6IW4MT3CMQSBCERIIMG/action/replication_record"}},"created_at":"2026-07-05T06:23:07.354123+00:00","updated_at":"2026-07-05T06:23:07.354123+00:00"}