{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2018:F6OFTORICZMKOPRDAZQTRBZE24","short_pith_number":"pith:F6OFTORI","canonical_record":{"source":{"id":"1806.06431","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2018-06-17T19:09:34Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"283e2db2d67a66f7897defd0a70c900aa416ce34205798dd10f709b29bac995c","abstract_canon_sha256":"a88af18269b816031467aea0ef77654e6713f501bb2412de4f5043e4bb253b5d"},"schema_version":"1.0"},"canonical_sha256":"2f9c59ba281658a73e230661388724d7254c6125fcd530e10650fa01d2570375","source":{"kind":"arxiv","id":"1806.06431","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1806.06431","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"arxiv_version","alias_value":"1806.06431v1","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1806.06431","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"pith_short_12","alias_value":"F6OFTORICZMK","created_at":"2026-05-18T12:32:22Z"},{"alias_kind":"pith_short_16","alias_value":"F6OFTORICZMKOPRD","created_at":"2026-05-18T12:32:22Z"},{"alias_kind":"pith_short_8","alias_value":"F6OFTORI","created_at":"2026-05-18T12:32:22Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2018:F6OFTORICZMKOPRDAZQTRBZE24","target":"record","payload":{"canonical_record":{"source":{"id":"1806.06431","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2018-06-17T19:09:34Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"283e2db2d67a66f7897defd0a70c900aa416ce34205798dd10f709b29bac995c","abstract_canon_sha256":"a88af18269b816031467aea0ef77654e6713f501bb2412de4f5043e4bb253b5d"},"schema_version":"1.0"},"canonical_sha256":"2f9c59ba281658a73e230661388724d7254c6125fcd530e10650fa01d2570375","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:13:02.411259Z","signature_b64":"JqJGDZE6AZJKaIeRO2gEGH8WFBXqrPTkZ5NVMVlJPLv5YHdIIGL6gwYv6kX1ozONUQ+w/DUg+7OnZs1dwcpTBg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2f9c59ba281658a73e230661388724d7254c6125fcd530e10650fa01d2570375","last_reissued_at":"2026-05-18T00:13:02.410575Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:13:02.410575Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1806.06431","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:13:02Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"u+Svz6IhUFQNvRJU6t4ne6d1VV2i+4c8NdPa8ZM6fMjcqbfuoqTfIELBbcaBTfprS+Jfm8KUqOg2BtzL5mnkAw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-28T06:17:14.209255Z"},"content_sha256":"bb7d489806ff4adea89010f172405e3306b75265cf5342a60f651d88e047f8cf","schema_version":"1.0","event_id":"sha256:bb7d489806ff4adea89010f172405e3306b75265cf5342a60f651d88e047f8cf"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2018:F6OFTORICZMKOPRDAZQTRBZE24","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Local fluctuations of vibrational polaritons monitored by two-dimensional infrared spectroscopy","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"quant-ph","authors_text":"Kai Wang, Marlan O. Scully, Shaul Mukamel, Zhedong Zhang, Zhenhuan Yi","submitted_at":"2018-06-17T19:09:34Z","abstract_excerpt":"We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due to intermolecule coherence. To further resolve such process, we develop a two-dimensional infrared spectroscopy (2D-IR) for molecules interacting with cavity modes. The cooperative feature in correspondence to the spectroscopic signal is specified. The results reveal the dark states by the cross peaks apart from the ones for polaritons, as a result of the bre"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1806.06431","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:13:02Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"3aKVcrKtzKRJgZ7xE2VCALbWFZejSVaLfDL7aWsBHBQfprw/snPKdWntpaPLJIsuqQqiaYDT5kmlz3kntcDiAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-28T06:17:14.209620Z"},"content_sha256":"e54c16b19b79efd3d9524402f444f1b4836fff1ebe5692632888afadaa39966f","schema_version":"1.0","event_id":"sha256:e54c16b19b79efd3d9524402f444f1b4836fff1ebe5692632888afadaa39966f"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/F6OFTORICZMKOPRDAZQTRBZE24/bundle.json","state_url":"https://pith.science/pith/F6OFTORICZMKOPRDAZQTRBZE24/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/F6OFTORICZMKOPRDAZQTRBZE24/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-28T06:17:14Z","links":{"resolver":"https://pith.science/pith/F6OFTORICZMKOPRDAZQTRBZE24","bundle":"https://pith.science/pith/F6OFTORICZMKOPRDAZQTRBZE24/bundle.json","state":"https://pith.science/pith/F6OFTORICZMKOPRDAZQTRBZE24/state.json","well_known_bundle":"https://pith.science/.well-known/pith/F6OFTORICZMKOPRDAZQTRBZE24/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2018:F6OFTORICZMKOPRDAZQTRBZE24","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"a88af18269b816031467aea0ef77654e6713f501bb2412de4f5043e4bb253b5d","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2018-06-17T19:09:34Z","title_canon_sha256":"283e2db2d67a66f7897defd0a70c900aa416ce34205798dd10f709b29bac995c"},"schema_version":"1.0","source":{"id":"1806.06431","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1806.06431","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"arxiv_version","alias_value":"1806.06431v1","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1806.06431","created_at":"2026-05-18T00:13:02Z"},{"alias_kind":"pith_short_12","alias_value":"F6OFTORICZMK","created_at":"2026-05-18T12:32:22Z"},{"alias_kind":"pith_short_16","alias_value":"F6OFTORICZMKOPRD","created_at":"2026-05-18T12:32:22Z"},{"alias_kind":"pith_short_8","alias_value":"F6OFTORI","created_at":"2026-05-18T12:32:22Z"}],"graph_snapshots":[{"event_id":"sha256:e54c16b19b79efd3d9524402f444f1b4836fff1ebe5692632888afadaa39966f","target":"graph","created_at":"2026-05-18T00:13:02Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due to intermolecule coherence. To further resolve such process, we develop a two-dimensional infrared spectroscopy (2D-IR) for molecules interacting with cavity modes. The cooperative feature in correspondence to the spectroscopic signal is specified. The results reveal the dark states by the cross peaks apart from the ones for polaritons, as a result of the bre","authors_text":"Kai Wang, Marlan O. Scully, Shaul Mukamel, Zhedong Zhang, Zhenhuan Yi","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2018-06-17T19:09:34Z","title":"Local fluctuations of vibrational polaritons monitored by two-dimensional infrared spectroscopy"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1806.06431","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:bb7d489806ff4adea89010f172405e3306b75265cf5342a60f651d88e047f8cf","target":"record","created_at":"2026-05-18T00:13:02Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"a88af18269b816031467aea0ef77654e6713f501bb2412de4f5043e4bb253b5d","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2018-06-17T19:09:34Z","title_canon_sha256":"283e2db2d67a66f7897defd0a70c900aa416ce34205798dd10f709b29bac995c"},"schema_version":"1.0","source":{"id":"1806.06431","kind":"arxiv","version":1}},"canonical_sha256":"2f9c59ba281658a73e230661388724d7254c6125fcd530e10650fa01d2570375","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2f9c59ba281658a73e230661388724d7254c6125fcd530e10650fa01d2570375","first_computed_at":"2026-05-18T00:13:02.410575Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:13:02.410575Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"JqJGDZE6AZJKaIeRO2gEGH8WFBXqrPTkZ5NVMVlJPLv5YHdIIGL6gwYv6kX1ozONUQ+w/DUg+7OnZs1dwcpTBg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:13:02.411259Z","signed_message":"canonical_sha256_bytes"},"source_id":"1806.06431","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:bb7d489806ff4adea89010f172405e3306b75265cf5342a60f651d88e047f8cf","sha256:e54c16b19b79efd3d9524402f444f1b4836fff1ebe5692632888afadaa39966f"],"state_sha256":"9040e9385888e7f48aa4dd80f6ebc71cd0af1aa0eebd1ff6ff95a78278eab05f"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"QQw+TMOByEgpunFtrUXR8WDQ5kblS167JcbLidgDQEDnLa39Vv0Hy2IpoItbJu1KRS8sgjZx059Ffc1T9M1IAQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-28T06:17:14.211661Z","bundle_sha256":"6da9bdd3de80599a0037292bcf56da29203fcf4ab500ba43b33563570aa3e707"}}