{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2022:FOWVOERHDEUNUSPL5VIAI7WUZQ","short_pith_number":"pith:FOWVOERH","canonical_record":{"source":{"id":"2203.15384","kind":"arxiv","version":4},"metadata":{"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-03-29T09:23:00Z","cross_cats_sorted":[],"title_canon_sha256":"906eca8dfa2cce5404626b5f108de1a71ad5de73a26e2cdb5768c690e435a141","abstract_canon_sha256":"a7daa5ae307440de61befc79eff353d610742e8fe9c1baacb97ffad38b8ef430"},"schema_version":"1.0"},"canonical_sha256":"2bad5712271928da49ebed50047ed4cc2249c17a8b8888d919daa704201c7e55","source":{"kind":"arxiv","id":"2203.15384","version":4},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2203.15384","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"arxiv_version","alias_value":"2203.15384v4","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2203.15384","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_12","alias_value":"FOWVOERHDEUN","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_16","alias_value":"FOWVOERHDEUNUSPL","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_8","alias_value":"FOWVOERH","created_at":"2026-07-05T04:50:15Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2022:FOWVOERHDEUNUSPL5VIAI7WUZQ","target":"record","payload":{"canonical_record":{"source":{"id":"2203.15384","kind":"arxiv","version":4},"metadata":{"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-03-29T09:23:00Z","cross_cats_sorted":[],"title_canon_sha256":"906eca8dfa2cce5404626b5f108de1a71ad5de73a26e2cdb5768c690e435a141","abstract_canon_sha256":"a7daa5ae307440de61befc79eff353d610742e8fe9c1baacb97ffad38b8ef430"},"schema_version":"1.0"},"canonical_sha256":"2bad5712271928da49ebed50047ed4cc2249c17a8b8888d919daa704201c7e55","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T04:50:15.635225Z","signature_b64":"dEVC5EL9YYzJbKvRdVd8ZSLbWqI0gYWvbLyN+6pBzHvwwhXaQt+RKD1PD8Lsbz3+npcEIBN4PskzP8LLJ0sGBw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2bad5712271928da49ebed50047ed4cc2249c17a8b8888d919daa704201c7e55","last_reissued_at":"2026-07-05T04:50:15.634635Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T04:50:15.634635Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2203.15384","source_version":4,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:50:15Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"QoES87Ck2h2hxxsVwTyZ29Y776Zk65jphnuNiqAQt4AZBd/X05Kl725+eD50M7UYRlp9d8dJpG6inTd+JtuoCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-01T11:59:13.444986Z"},"content_sha256":"e3200444c1a4a716521ee97a9796695d4b3f3a251fc014af9d0257fa08f4aafc","schema_version":"1.0","event_id":"sha256:e3200444c1a4a716521ee97a9796695d4b3f3a251fc014af9d0257fa08f4aafc"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2022:FOWVOERHDEUNUSPL5VIAI7WUZQ","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Doping effect and Li-ion conduction mechanism of ALi6XO6 (A = K or Rb, and X = pentavalent): A first-principles study","license":"http://creativecommons.org/licenses/by-sa/4.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Joohwi Lee, Ryoji Asahi","submitted_at":"2022-03-29T09:23:00Z","abstract_excerpt":"Recent theoretical and experimental evaluations demonstrated that KLi6TaO6 is a good Li-ion conductor. In this study, the energetics and detailed mechanism of Li-ion migration, relevant to the point defects of KLi6TaO6, were analyzed by first-principles calculations. Defect formation energy analysis suggested that it has limited chemical potential conditions for attaining Li-excess conditions through doping (substituting tetravalent elements for Ta). The formation of other native defects, such as Li vacancies, hinders the stabilization of the dopant and compensates for the interstitial Li. Whe"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2203.15384","kind":"arxiv","version":4},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2203.15384/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T04:50:15Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"rFRO/gQUvH979N7LncjHDSG7CSeqtA9UijNdur6My85mJRFCUbVDwIT2Exeb8qyQcYT8ZQFXFUNMIOHTl2luCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-01T11:59:13.445510Z"},"content_sha256":"7f6aa1203a9aa20ccee0810daa270a9ac32b3f7369a2852dd06ade05fd1ebccf","schema_version":"1.0","event_id":"sha256:7f6aa1203a9aa20ccee0810daa270a9ac32b3f7369a2852dd06ade05fd1ebccf"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/bundle.json","state_url":"https://pith.science/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-01T11:59:13Z","links":{"resolver":"https://pith.science/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ","bundle":"https://pith.science/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/bundle.json","state":"https://pith.science/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/state.json","well_known_bundle":"https://pith.science/.well-known/pith/FOWVOERHDEUNUSPL5VIAI7WUZQ/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2022:FOWVOERHDEUNUSPL5VIAI7WUZQ","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"a7daa5ae307440de61befc79eff353d610742e8fe9c1baacb97ffad38b8ef430","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-03-29T09:23:00Z","title_canon_sha256":"906eca8dfa2cce5404626b5f108de1a71ad5de73a26e2cdb5768c690e435a141"},"schema_version":"1.0","source":{"id":"2203.15384","kind":"arxiv","version":4}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2203.15384","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"arxiv_version","alias_value":"2203.15384v4","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2203.15384","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_12","alias_value":"FOWVOERHDEUN","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_16","alias_value":"FOWVOERHDEUNUSPL","created_at":"2026-07-05T04:50:15Z"},{"alias_kind":"pith_short_8","alias_value":"FOWVOERH","created_at":"2026-07-05T04:50:15Z"}],"graph_snapshots":[{"event_id":"sha256:7f6aa1203a9aa20ccee0810daa270a9ac32b3f7369a2852dd06ade05fd1ebccf","target":"graph","created_at":"2026-07-05T04:50:15Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2203.15384/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Recent theoretical and experimental evaluations demonstrated that KLi6TaO6 is a good Li-ion conductor. In this study, the energetics and detailed mechanism of Li-ion migration, relevant to the point defects of KLi6TaO6, were analyzed by first-principles calculations. Defect formation energy analysis suggested that it has limited chemical potential conditions for attaining Li-excess conditions through doping (substituting tetravalent elements for Ta). The formation of other native defects, such as Li vacancies, hinders the stabilization of the dopant and compensates for the interstitial Li. Whe","authors_text":"Joohwi Lee, Ryoji Asahi","cross_cats":[],"headline":"","license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-03-29T09:23:00Z","title":"Doping effect and Li-ion conduction mechanism of ALi6XO6 (A = K or Rb, and X = pentavalent): A first-principles study"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2203.15384","kind":"arxiv","version":4},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:e3200444c1a4a716521ee97a9796695d4b3f3a251fc014af9d0257fa08f4aafc","target":"record","created_at":"2026-07-05T04:50:15Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"a7daa5ae307440de61befc79eff353d610742e8fe9c1baacb97ffad38b8ef430","cross_cats_sorted":[],"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2022-03-29T09:23:00Z","title_canon_sha256":"906eca8dfa2cce5404626b5f108de1a71ad5de73a26e2cdb5768c690e435a141"},"schema_version":"1.0","source":{"id":"2203.15384","kind":"arxiv","version":4}},"canonical_sha256":"2bad5712271928da49ebed50047ed4cc2249c17a8b8888d919daa704201c7e55","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2bad5712271928da49ebed50047ed4cc2249c17a8b8888d919daa704201c7e55","first_computed_at":"2026-07-05T04:50:15.634635Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T04:50:15.634635Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"dEVC5EL9YYzJbKvRdVd8ZSLbWqI0gYWvbLyN+6pBzHvwwhXaQt+RKD1PD8Lsbz3+npcEIBN4PskzP8LLJ0sGBw==","signature_status":"signed_v1","signed_at":"2026-07-05T04:50:15.635225Z","signed_message":"canonical_sha256_bytes"},"source_id":"2203.15384","source_kind":"arxiv","source_version":4}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:e3200444c1a4a716521ee97a9796695d4b3f3a251fc014af9d0257fa08f4aafc","sha256:7f6aa1203a9aa20ccee0810daa270a9ac32b3f7369a2852dd06ade05fd1ebccf"],"state_sha256":"cd1fb095e063bfae00868578db53e0f11132ec325e46bce50e518c103a880e0e"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"4zfNhFlqbvhWSJtEXtDxtUAs3yWlrY8T47pLwoGTDRVy8eMwv96CFPrnHE8E4Ew6xw2i6JlZ38iTfAZhmpuACA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-01T11:59:13.450026Z","bundle_sha256":"aff29deb64b28833079949fb1fcac21d2267b6e6c0720a50635f69ce9d41f309"}}