{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2024:FVAC4DR742EMFOGCL4VIC3ZEMA","short_pith_number":"pith:FVAC4DR7","canonical_record":{"source":{"id":"2402.04246","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2024-02-06T18:53:58Z","cross_cats_sorted":["physics.chem-ph","physics.optics"],"title_canon_sha256":"04995d5cf6c0813ca6131dee9a3c7d42246ebe3fbd45b52c5db2f5fb134f6f8b","abstract_canon_sha256":"e6754370e46047b0719b098d3279746a098b9abe4045f5006afc857d887ae25b"},"schema_version":"1.0"},"canonical_sha256":"2d402e0e3fe688c2b8c25f2a816f2460343ec8e41d80e8035413b7cc90e2a6aa","source":{"kind":"arxiv","id":"2402.04246","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2402.04246","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"arxiv_version","alias_value":"2402.04246v2","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2402.04246","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_12","alias_value":"FVAC4DR742EM","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_16","alias_value":"FVAC4DR742EMFOGC","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_8","alias_value":"FVAC4DR7","created_at":"2026-07-05T07:56:59Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2024:FVAC4DR742EMFOGCL4VIC3ZEMA","target":"record","payload":{"canonical_record":{"source":{"id":"2402.04246","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2024-02-06T18:53:58Z","cross_cats_sorted":["physics.chem-ph","physics.optics"],"title_canon_sha256":"04995d5cf6c0813ca6131dee9a3c7d42246ebe3fbd45b52c5db2f5fb134f6f8b","abstract_canon_sha256":"e6754370e46047b0719b098d3279746a098b9abe4045f5006afc857d887ae25b"},"schema_version":"1.0"},"canonical_sha256":"2d402e0e3fe688c2b8c25f2a816f2460343ec8e41d80e8035413b7cc90e2a6aa","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T07:56:59.249876Z","signature_b64":"MNie4i46ja2lzWGy9tVYBxEybLwWV4kwCt+94E3qLtCoCtUKU3Cz4qM4p5tiioGjVXq7YIeNOTc/INzJSzSFAw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2d402e0e3fe688c2b8c25f2a816f2460343ec8e41d80e8035413b7cc90e2a6aa","last_reissued_at":"2026-07-05T07:56:59.249410Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T07:56:59.249410Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2402.04246","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T07:56:59Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"FRTT6Bh9z6i8pUFh8nfjzkxzAVB+CptWY3cKyOXuxHPGKwQkMynP8MHFOlYDboEQSB5pVD40Uqz7mbTcu7kUAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T19:01:36.731913Z"},"content_sha256":"a68f1d909d5de1806fa90afa93c23ffd8548e3655b8465ea456e9f5f33a88799","schema_version":"1.0","event_id":"sha256:a68f1d909d5de1806fa90afa93c23ffd8548e3655b8465ea456e9f5f33a88799"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2024:FVAC4DR742EMFOGCL4VIC3ZEMA","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Theory of Supervibronic Transitions via Casimir Polaritons","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph","physics.optics"],"primary_cat":"quant-ph","authors_text":"Tao E. Li","submitted_at":"2024-02-06T18:53:58Z","abstract_excerpt":"A remote energy transfer pathway from electronic to vibrational degrees of freedom is identified inside an infrared optical cavity under vibrational strong coupling conditions. This mechanism relies on the dynamical Casimir effect, whereby real infrared photons are generated due to a sudden electronic transition of anisotropic molecules. Moreover, the formation of vibrational polaritons enables the excited photon energy to be transferred to the vibrational degrees of freedom before any dissipation occurs. Both analytic solutions and numerical simulations reveal that the magnitude of this elect"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2402.04246","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2402.04246/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T07:56:59Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"W5IyRvtwJQJbbV3d+dE8lb96yjPE2wWEfGp4KrhhXRlITxcZiCNgP9WjmwKaDPgYW2v4bi5HB6zWefxO0V/SBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T19:01:36.732276Z"},"content_sha256":"ae637edcf400eb6673e0b76569b3fc91035317e6173fe7b3b896625d1e0433af","schema_version":"1.0","event_id":"sha256:ae637edcf400eb6673e0b76569b3fc91035317e6173fe7b3b896625d1e0433af"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/bundle.json","state_url":"https://pith.science/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-06T19:01:36Z","links":{"resolver":"https://pith.science/pith/FVAC4DR742EMFOGCL4VIC3ZEMA","bundle":"https://pith.science/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/bundle.json","state":"https://pith.science/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/state.json","well_known_bundle":"https://pith.science/.well-known/pith/FVAC4DR742EMFOGCL4VIC3ZEMA/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2024:FVAC4DR742EMFOGCL4VIC3ZEMA","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"e6754370e46047b0719b098d3279746a098b9abe4045f5006afc857d887ae25b","cross_cats_sorted":["physics.chem-ph","physics.optics"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2024-02-06T18:53:58Z","title_canon_sha256":"04995d5cf6c0813ca6131dee9a3c7d42246ebe3fbd45b52c5db2f5fb134f6f8b"},"schema_version":"1.0","source":{"id":"2402.04246","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2402.04246","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"arxiv_version","alias_value":"2402.04246v2","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2402.04246","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_12","alias_value":"FVAC4DR742EM","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_16","alias_value":"FVAC4DR742EMFOGC","created_at":"2026-07-05T07:56:59Z"},{"alias_kind":"pith_short_8","alias_value":"FVAC4DR7","created_at":"2026-07-05T07:56:59Z"}],"graph_snapshots":[{"event_id":"sha256:ae637edcf400eb6673e0b76569b3fc91035317e6173fe7b3b896625d1e0433af","target":"graph","created_at":"2026-07-05T07:56:59Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2402.04246/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"A remote energy transfer pathway from electronic to vibrational degrees of freedom is identified inside an infrared optical cavity under vibrational strong coupling conditions. This mechanism relies on the dynamical Casimir effect, whereby real infrared photons are generated due to a sudden electronic transition of anisotropic molecules. Moreover, the formation of vibrational polaritons enables the excited photon energy to be transferred to the vibrational degrees of freedom before any dissipation occurs. Both analytic solutions and numerical simulations reveal that the magnitude of this elect","authors_text":"Tao E. Li","cross_cats":["physics.chem-ph","physics.optics"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2024-02-06T18:53:58Z","title":"Theory of Supervibronic Transitions via Casimir Polaritons"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2402.04246","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a68f1d909d5de1806fa90afa93c23ffd8548e3655b8465ea456e9f5f33a88799","target":"record","created_at":"2026-07-05T07:56:59Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"e6754370e46047b0719b098d3279746a098b9abe4045f5006afc857d887ae25b","cross_cats_sorted":["physics.chem-ph","physics.optics"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2024-02-06T18:53:58Z","title_canon_sha256":"04995d5cf6c0813ca6131dee9a3c7d42246ebe3fbd45b52c5db2f5fb134f6f8b"},"schema_version":"1.0","source":{"id":"2402.04246","kind":"arxiv","version":2}},"canonical_sha256":"2d402e0e3fe688c2b8c25f2a816f2460343ec8e41d80e8035413b7cc90e2a6aa","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"2d402e0e3fe688c2b8c25f2a816f2460343ec8e41d80e8035413b7cc90e2a6aa","first_computed_at":"2026-07-05T07:56:59.249410Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T07:56:59.249410Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"MNie4i46ja2lzWGy9tVYBxEybLwWV4kwCt+94E3qLtCoCtUKU3Cz4qM4p5tiioGjVXq7YIeNOTc/INzJSzSFAw==","signature_status":"signed_v1","signed_at":"2026-07-05T07:56:59.249876Z","signed_message":"canonical_sha256_bytes"},"source_id":"2402.04246","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a68f1d909d5de1806fa90afa93c23ffd8548e3655b8465ea456e9f5f33a88799","sha256:ae637edcf400eb6673e0b76569b3fc91035317e6173fe7b3b896625d1e0433af"],"state_sha256":"cf0ed8edc443b3633553252061c5e8e7494cf946beaa79774a2f9a519c123825"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ebS0TMoavMWvIs1C4EZcqLoXD27UMxu4t3TmvuXIMqsKX562lUR40/L96opRix7Fy0oknuwnpFNv7pOWIKuJBQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-06T19:01:36.734185Z","bundle_sha256":"38db14177b44ad7768da064dc97e8e852d4e3aa49c0ae972e883fc523b7c4292"}}