{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2016:FVEBAY5VW67BZOMTQLTSWYU5UK","short_pith_number":"pith:FVEBAY5V","schema_version":"1.0","canonical_sha256":"2d481063b5b7be1cb99382e72b629da2a304be12930a861f287452276195ad5a","source":{"kind":"arxiv","id":"1603.00355","version":1},"attestation_state":"computed","paper":{"title":"Control of the third dimension in copper-based square-lattice antiferromagnets","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"cond-mat.str-el","authors_text":"Andrew J. Steele, Brendan W. Twamley, C. Baines, Craig V. Topping, Francis L. Pratt, Hope E. Tran, Isabel Franke, Jamie Brambleby, Jamie L. Manson, J. A. Schlueter, Jesper Bendix, Johannes S. Moller, John Singleton, Jordan F. Corbey, Kylee Funk, Marianne M. Conner, Martin R. Lees, Paul A. Goddard, Peter W. Stephens, Ross D. McDonald, Saul H. Lapidus, Stephen J. Blundell, Tom Lancaster","submitted_at":"2016-03-01T16:52:25Z","abstract_excerpt":"Using a mixed-ligand synthetic scheme, we create a family of quasi-two-dimensional antiferromagnets, namely, [Cu(HF$_2$)(pyz)$_2$]ClO$_4$ [pyz = pyrazine], [Cu$L_2$(pyz)$_2$](ClO$_4$)$_2$ [$L$ = pyO = pyridine-N-oxide and 4-phpyO = 4-phenylpyridine-N-oxide. These materials are shown to possess equivalent two-dimensional [Cu(pyz)$_2$]$^{2+}$ nearly square layers, but exhibit interlayer spacings that vary from 6.5713~\\AA ~to 16.777~\\AA, as dictated by the axial ligands. We present the structural and magnetic properties of this family as determined via x-ray diffraction, electron-spin resonance, "},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1603.00355","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2016-03-01T16:52:25Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"070bb330dbfae4b9e326948373e015a5a519c49948b5b78fb1a9148742bb2df9","abstract_canon_sha256":"250e5429143ab97fd3c02293d11a1c5a2eeb3d63d222f6cf00cb7ed7f79c8633"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:16:13.797707Z","signature_b64":"HORbkkRgXu4ZhJYDfdMmSC/sqWnVy5rz6ViJ9ZGUzv8lCdaXUWt5kEBMpHpLZMg57QDU+2X0hnLj3DntvGxnBA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"2d481063b5b7be1cb99382e72b629da2a304be12930a861f287452276195ad5a","last_reissued_at":"2026-05-18T01:16:13.797061Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:16:13.797061Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Control of the third dimension in copper-based square-lattice antiferromagnets","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"cond-mat.str-el","authors_text":"Andrew J. Steele, Brendan W. Twamley, C. Baines, Craig V. Topping, Francis L. Pratt, Hope E. Tran, Isabel Franke, Jamie Brambleby, Jamie L. Manson, J. A. Schlueter, Jesper Bendix, Johannes S. Moller, John Singleton, Jordan F. Corbey, Kylee Funk, Marianne M. Conner, Martin R. Lees, Paul A. Goddard, Peter W. Stephens, Ross D. McDonald, Saul H. Lapidus, Stephen J. Blundell, Tom Lancaster","submitted_at":"2016-03-01T16:52:25Z","abstract_excerpt":"Using a mixed-ligand synthetic scheme, we create a family of quasi-two-dimensional antiferromagnets, namely, [Cu(HF$_2$)(pyz)$_2$]ClO$_4$ [pyz = pyrazine], [Cu$L_2$(pyz)$_2$](ClO$_4$)$_2$ [$L$ = pyO = pyridine-N-oxide and 4-phpyO = 4-phenylpyridine-N-oxide. These materials are shown to possess equivalent two-dimensional [Cu(pyz)$_2$]$^{2+}$ nearly square layers, but exhibit interlayer spacings that vary from 6.5713~\\AA ~to 16.777~\\AA, as dictated by the axial ligands. We present the structural and magnetic properties of this family as determined via x-ray diffraction, electron-spin resonance, "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1603.00355","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1603.00355","created_at":"2026-05-18T01:16:13.797168+00:00"},{"alias_kind":"arxiv_version","alias_value":"1603.00355v1","created_at":"2026-05-18T01:16:13.797168+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1603.00355","created_at":"2026-05-18T01:16:13.797168+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK","json":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK.json","graph_json":"https://pith.science/api/pith-number/FVEBAY5VW67BZOMTQLTSWYU5UK/graph.json","events_json":"https://pith.science/api/pith-number/FVEBAY5VW67BZOMTQLTSWYU5UK/events.json","paper":"https://pith.science/paper/FVEBAY5V"},"agent_actions":{"view_html":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK","download_json":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK.json","view_paper":"https://pith.science/paper/FVEBAY5V","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1603.00355&json=true","fetch_graph":"https://pith.science/api/pith-number/FVEBAY5VW67BZOMTQLTSWYU5UK/graph.json","fetch_events":"https://pith.science/api/pith-number/FVEBAY5VW67BZOMTQLTSWYU5UK/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK/action/timestamp_anchor","attest_storage":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK/action/storage_attestation","attest_author":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK/action/author_attestation","sign_citation":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK/action/citation_signature","submit_replication":"https://pith.science/pith/FVEBAY5VW67BZOMTQLTSWYU5UK/action/replication_record"}},"created_at":"2026-05-18T01:16:13.797168+00:00","updated_at":"2026-05-18T01:16:13.797168+00:00"}