{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2019:GQUE2WWSTIXKYKMROS2UVARHXP","short_pith_number":"pith:GQUE2WWS","canonical_record":{"source":{"id":"1901.02171","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2019-01-08T06:36:00Z","cross_cats_sorted":[],"title_canon_sha256":"b1737e4a63eef18d53eb5e61c7987696dc7c87a066972f15f531b6632c481820","abstract_canon_sha256":"faaa3fb19481de7199d190b3fbe238ecece6dc978c90d53203ee74a0687c2544"},"schema_version":"1.0"},"canonical_sha256":"34284d5ad29a2eac299174b54a8227bbdbabe87df7c9eb1bbb96760b487df264","source":{"kind":"arxiv","id":"1901.02171","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1901.02171","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"arxiv_version","alias_value":"1901.02171v1","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1901.02171","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"pith_short_12","alias_value":"GQUE2WWSTIXK","created_at":"2026-05-18T12:33:18Z"},{"alias_kind":"pith_short_16","alias_value":"GQUE2WWSTIXKYKMR","created_at":"2026-05-18T12:33:18Z"},{"alias_kind":"pith_short_8","alias_value":"GQUE2WWS","created_at":"2026-05-18T12:33:18Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2019:GQUE2WWSTIXKYKMROS2UVARHXP","target":"record","payload":{"canonical_record":{"source":{"id":"1901.02171","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2019-01-08T06:36:00Z","cross_cats_sorted":[],"title_canon_sha256":"b1737e4a63eef18d53eb5e61c7987696dc7c87a066972f15f531b6632c481820","abstract_canon_sha256":"faaa3fb19481de7199d190b3fbe238ecece6dc978c90d53203ee74a0687c2544"},"schema_version":"1.0"},"canonical_sha256":"34284d5ad29a2eac299174b54a8227bbdbabe87df7c9eb1bbb96760b487df264","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-17T23:56:43.869603Z","signature_b64":"1SLGDx6PiaVz0GkSEqK3wPW2cFUKRPZqj49OXgGMcN+Aw06ammAPhgMOdbC3i8pGPUck6cyQxJeH4h2V4DgTBA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"34284d5ad29a2eac299174b54a8227bbdbabe87df7c9eb1bbb96760b487df264","last_reissued_at":"2026-05-17T23:56:43.869155Z","signature_status":"signed_v1","first_computed_at":"2026-05-17T23:56:43.869155Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1901.02171","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:56:43Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"XHX9ac3uVSkgfvI+/e9WPxw9ERm17vlR5RGPv7zdl2Cnk0pLUV883PXFL6oJlcn+OCRa3eg8ZRIXxaYF8nrsAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T22:31:40.392335Z"},"content_sha256":"a627c2f8898e7b5c93b75c7ee0daae63d28d59473c60419a20a178704b9891f4","schema_version":"1.0","event_id":"sha256:a627c2f8898e7b5c93b75c7ee0daae63d28d59473c60419a20a178704b9891f4"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2019:GQUE2WWSTIXKYKMROS2UVARHXP","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Controlling the stoichiometry of the triangular lattice antiferromagnet Li$_{1+x}$Zn$_{2-y}$Mo$_3$O$_8$","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"(2) Australian Nuclear Science, 3), (3) School of Chemistry, D. Okuyama (1), K. E. Sandvik (1), K. Nawa (1), M. Avdeev (2, Technology Organization, The University of Sydney), T. J. Sato (1) ((1) Institute of Multidisciplinary Research for Advanced Materials, Tohoku University","submitted_at":"2019-01-08T06:36:00Z","abstract_excerpt":"The control of the stoichiometry of Li$_{1+x}$Zn$_{2-y}$Mo$_3$O$_8$ was achieved by the solid-state-reaction. We found that the best sample that has the chemical composition Li$_{0.95(4)}$Zn$_{1.92(8)}$Mo$_3$O$_8$ was obtained from the starting nominal composition with Li : Zn : Mo : O = $(1+w)$ : $(2.8-w)$ : $3$ : $8.6$ with $w = -0.1$, indicating that the stoichiometry is greatly improved compared to those in the earlier reports. For larger $w$ detailed structural analysis indicates that the mixed sites of Li and Zn are preferentially occupied by Li atoms, as well as the fraction of the non-"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1901.02171","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:56:43Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"pKPbJgPUa01FJkkiQNyBbqPAwnAqE4kp+4IyZM+Mxu6GQwmrpzsBQWNuetrvW7mO37Txr6R+ZTinF6HWTCl1Cg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T22:31:40.392686Z"},"content_sha256":"e98df469aec3d37382585c904547424343d55cf8592ab92f7dc4146cd45b94c1","schema_version":"1.0","event_id":"sha256:e98df469aec3d37382585c904547424343d55cf8592ab92f7dc4146cd45b94c1"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/GQUE2WWSTIXKYKMROS2UVARHXP/bundle.json","state_url":"https://pith.science/pith/GQUE2WWSTIXKYKMROS2UVARHXP/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/GQUE2WWSTIXKYKMROS2UVARHXP/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-08T22:31:40Z","links":{"resolver":"https://pith.science/pith/GQUE2WWSTIXKYKMROS2UVARHXP","bundle":"https://pith.science/pith/GQUE2WWSTIXKYKMROS2UVARHXP/bundle.json","state":"https://pith.science/pith/GQUE2WWSTIXKYKMROS2UVARHXP/state.json","well_known_bundle":"https://pith.science/.well-known/pith/GQUE2WWSTIXKYKMROS2UVARHXP/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2019:GQUE2WWSTIXKYKMROS2UVARHXP","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"faaa3fb19481de7199d190b3fbe238ecece6dc978c90d53203ee74a0687c2544","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2019-01-08T06:36:00Z","title_canon_sha256":"b1737e4a63eef18d53eb5e61c7987696dc7c87a066972f15f531b6632c481820"},"schema_version":"1.0","source":{"id":"1901.02171","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1901.02171","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"arxiv_version","alias_value":"1901.02171v1","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1901.02171","created_at":"2026-05-17T23:56:43Z"},{"alias_kind":"pith_short_12","alias_value":"GQUE2WWSTIXK","created_at":"2026-05-18T12:33:18Z"},{"alias_kind":"pith_short_16","alias_value":"GQUE2WWSTIXKYKMR","created_at":"2026-05-18T12:33:18Z"},{"alias_kind":"pith_short_8","alias_value":"GQUE2WWS","created_at":"2026-05-18T12:33:18Z"}],"graph_snapshots":[{"event_id":"sha256:e98df469aec3d37382585c904547424343d55cf8592ab92f7dc4146cd45b94c1","target":"graph","created_at":"2026-05-17T23:56:43Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The control of the stoichiometry of Li$_{1+x}$Zn$_{2-y}$Mo$_3$O$_8$ was achieved by the solid-state-reaction. We found that the best sample that has the chemical composition Li$_{0.95(4)}$Zn$_{1.92(8)}$Mo$_3$O$_8$ was obtained from the starting nominal composition with Li : Zn : Mo : O = $(1+w)$ : $(2.8-w)$ : $3$ : $8.6$ with $w = -0.1$, indicating that the stoichiometry is greatly improved compared to those in the earlier reports. For larger $w$ detailed structural analysis indicates that the mixed sites of Li and Zn are preferentially occupied by Li atoms, as well as the fraction of the non-","authors_text":"(2) Australian Nuclear Science, 3), (3) School of Chemistry, D. Okuyama (1), K. E. Sandvik (1), K. Nawa (1), M. Avdeev (2, Technology Organization, The University of Sydney), T. J. Sato (1) ((1) Institute of Multidisciplinary Research for Advanced Materials, Tohoku University","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2019-01-08T06:36:00Z","title":"Controlling the stoichiometry of the triangular lattice antiferromagnet Li$_{1+x}$Zn$_{2-y}$Mo$_3$O$_8$"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1901.02171","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a627c2f8898e7b5c93b75c7ee0daae63d28d59473c60419a20a178704b9891f4","target":"record","created_at":"2026-05-17T23:56:43Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"faaa3fb19481de7199d190b3fbe238ecece6dc978c90d53203ee74a0687c2544","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.str-el","submitted_at":"2019-01-08T06:36:00Z","title_canon_sha256":"b1737e4a63eef18d53eb5e61c7987696dc7c87a066972f15f531b6632c481820"},"schema_version":"1.0","source":{"id":"1901.02171","kind":"arxiv","version":1}},"canonical_sha256":"34284d5ad29a2eac299174b54a8227bbdbabe87df7c9eb1bbb96760b487df264","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"34284d5ad29a2eac299174b54a8227bbdbabe87df7c9eb1bbb96760b487df264","first_computed_at":"2026-05-17T23:56:43.869155Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-17T23:56:43.869155Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"1SLGDx6PiaVz0GkSEqK3wPW2cFUKRPZqj49OXgGMcN+Aw06ammAPhgMOdbC3i8pGPUck6cyQxJeH4h2V4DgTBA==","signature_status":"signed_v1","signed_at":"2026-05-17T23:56:43.869603Z","signed_message":"canonical_sha256_bytes"},"source_id":"1901.02171","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a627c2f8898e7b5c93b75c7ee0daae63d28d59473c60419a20a178704b9891f4","sha256:e98df469aec3d37382585c904547424343d55cf8592ab92f7dc4146cd45b94c1"],"state_sha256":"a25ed28e03277f1f0fa449abedb548aa8d02f2b45e1ab909987dcfef9cf58350"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"g6memy38R1UKKXwBIJnPiSpImkXYOlew47L2bV7LZPrCn9Uz/hqfzoHNfQ6bHObU43+DdV6tEdvionFLOe7iAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-08T22:31:40.394898Z","bundle_sha256":"ef71fad0d9cb860a3d69c8dae01dbb10bb37b43ddbcf0659b1f84f035bf370e8"}}