{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2018:HCSG7FJVPEU5EWR7PWLND5L4D5","short_pith_number":"pith:HCSG7FJV","canonical_record":{"source":{"id":"1804.09863","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-04-26T02:39:51Z","cross_cats_sorted":[],"title_canon_sha256":"3bcfd6d51d168128287d1a74bd1a9223d19c1de9929961b9a049f35c600fbce0","abstract_canon_sha256":"3334ae4c3ab6fa0c1bcb86f9196e8e4bc56ff272ae21b6e0f995ab6bb2fd4ee2"},"schema_version":"1.0"},"canonical_sha256":"38a46f95357929d25a3f7d96d1f57c1f4c95b6ac003f9fbc80d7ff462b1156d6","source":{"kind":"arxiv","id":"1804.09863","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1804.09863","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"arxiv_version","alias_value":"1804.09863v2","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1804.09863","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"pith_short_12","alias_value":"HCSG7FJVPEU5","created_at":"2026-05-18T12:32:28Z"},{"alias_kind":"pith_short_16","alias_value":"HCSG7FJVPEU5EWR7","created_at":"2026-05-18T12:32:28Z"},{"alias_kind":"pith_short_8","alias_value":"HCSG7FJV","created_at":"2026-05-18T12:32:28Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2018:HCSG7FJVPEU5EWR7PWLND5L4D5","target":"record","payload":{"canonical_record":{"source":{"id":"1804.09863","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-04-26T02:39:51Z","cross_cats_sorted":[],"title_canon_sha256":"3bcfd6d51d168128287d1a74bd1a9223d19c1de9929961b9a049f35c600fbce0","abstract_canon_sha256":"3334ae4c3ab6fa0c1bcb86f9196e8e4bc56ff272ae21b6e0f995ab6bb2fd4ee2"},"schema_version":"1.0"},"canonical_sha256":"38a46f95357929d25a3f7d96d1f57c1f4c95b6ac003f9fbc80d7ff462b1156d6","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-17T23:57:41.527473Z","signature_b64":"rwoiAPGNLIebAsTXC+M5B+DO0OEOqhaIputGqrbumGWdqVGY7lzHkl6ZBFH2K+R2UHHAXEMLt+R2ha5Vk6TFCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"38a46f95357929d25a3f7d96d1f57c1f4c95b6ac003f9fbc80d7ff462b1156d6","last_reissued_at":"2026-05-17T23:57:41.526072Z","signature_status":"signed_v1","first_computed_at":"2026-05-17T23:57:41.526072Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1804.09863","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:57:41Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"dKMNm2coDlq1WtXVON89f5XZUklSA6WzoSRKju3Tk4EPSFTVQhLBSp3wSnBYxe3r3Ee6bRr/H3RqxvW4WDbABQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-28T10:01:28.705377Z"},"content_sha256":"62df46cd6fed20aec935d810621928a672b06ac58c3fc71915197b0c80e7ec58","schema_version":"1.0","event_id":"sha256:62df46cd6fed20aec935d810621928a672b06ac58c3fc71915197b0c80e7ec58"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2018:HCSG7FJVPEU5EWR7PWLND5L4D5","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Exploring vibrational ladder climbing in vibronic coupling models: Toward experimental observation of a geometric phase signature of a conical intersection","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Artur F. Izmaylov, Hazem Daoud, Loic Joubert-Doriol, R. J. Dwayne Miller","submitted_at":"2018-04-26T02:39:51Z","abstract_excerpt":"Conical intersections (CIs) have been widely studied using spectroscopic techniques. However, CIs have mainly been identified by rapid internal conversion transitions that take place after the photoexcitation. Such identifications cannot distinguish various types of intersections as well as to separate the actual intersection from an avoided crossing. In this paper, we investigate how ultrafast IR laser pulses can be utilized to stimulate nuclear dynamics revealing geometric phase features associated with CIs. We consider two low-dimensional nonadiabatic models to obtain optimal two- and three"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1804.09863","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-17T23:57:41Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"9RTMwwzOi8EmpP+aCengnmtYiVeipDlMjvvuHVNLs1oqhLUr25E9IjFTe0p8ACugCGIAtgJl2agYFALILwlVBg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-28T10:01:28.706016Z"},"content_sha256":"ba7365dc702ee4be16017c777ceb207604662091107d4be7f82fe6547c2e048c","schema_version":"1.0","event_id":"sha256:ba7365dc702ee4be16017c777ceb207604662091107d4be7f82fe6547c2e048c"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/bundle.json","state_url":"https://pith.science/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-28T10:01:28Z","links":{"resolver":"https://pith.science/pith/HCSG7FJVPEU5EWR7PWLND5L4D5","bundle":"https://pith.science/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/bundle.json","state":"https://pith.science/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/state.json","well_known_bundle":"https://pith.science/.well-known/pith/HCSG7FJVPEU5EWR7PWLND5L4D5/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2018:HCSG7FJVPEU5EWR7PWLND5L4D5","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"3334ae4c3ab6fa0c1bcb86f9196e8e4bc56ff272ae21b6e0f995ab6bb2fd4ee2","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-04-26T02:39:51Z","title_canon_sha256":"3bcfd6d51d168128287d1a74bd1a9223d19c1de9929961b9a049f35c600fbce0"},"schema_version":"1.0","source":{"id":"1804.09863","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1804.09863","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"arxiv_version","alias_value":"1804.09863v2","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1804.09863","created_at":"2026-05-17T23:57:41Z"},{"alias_kind":"pith_short_12","alias_value":"HCSG7FJVPEU5","created_at":"2026-05-18T12:32:28Z"},{"alias_kind":"pith_short_16","alias_value":"HCSG7FJVPEU5EWR7","created_at":"2026-05-18T12:32:28Z"},{"alias_kind":"pith_short_8","alias_value":"HCSG7FJV","created_at":"2026-05-18T12:32:28Z"}],"graph_snapshots":[{"event_id":"sha256:ba7365dc702ee4be16017c777ceb207604662091107d4be7f82fe6547c2e048c","target":"graph","created_at":"2026-05-17T23:57:41Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Conical intersections (CIs) have been widely studied using spectroscopic techniques. However, CIs have mainly been identified by rapid internal conversion transitions that take place after the photoexcitation. Such identifications cannot distinguish various types of intersections as well as to separate the actual intersection from an avoided crossing. In this paper, we investigate how ultrafast IR laser pulses can be utilized to stimulate nuclear dynamics revealing geometric phase features associated with CIs. We consider two low-dimensional nonadiabatic models to obtain optimal two- and three","authors_text":"Artur F. Izmaylov, Hazem Daoud, Loic Joubert-Doriol, R. J. Dwayne Miller","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-04-26T02:39:51Z","title":"Exploring vibrational ladder climbing in vibronic coupling models: Toward experimental observation of a geometric phase signature of a conical intersection"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1804.09863","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:62df46cd6fed20aec935d810621928a672b06ac58c3fc71915197b0c80e7ec58","target":"record","created_at":"2026-05-17T23:57:41Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"3334ae4c3ab6fa0c1bcb86f9196e8e4bc56ff272ae21b6e0f995ab6bb2fd4ee2","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2018-04-26T02:39:51Z","title_canon_sha256":"3bcfd6d51d168128287d1a74bd1a9223d19c1de9929961b9a049f35c600fbce0"},"schema_version":"1.0","source":{"id":"1804.09863","kind":"arxiv","version":2}},"canonical_sha256":"38a46f95357929d25a3f7d96d1f57c1f4c95b6ac003f9fbc80d7ff462b1156d6","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"38a46f95357929d25a3f7d96d1f57c1f4c95b6ac003f9fbc80d7ff462b1156d6","first_computed_at":"2026-05-17T23:57:41.526072Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-17T23:57:41.526072Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"rwoiAPGNLIebAsTXC+M5B+DO0OEOqhaIputGqrbumGWdqVGY7lzHkl6ZBFH2K+R2UHHAXEMLt+R2ha5Vk6TFCA==","signature_status":"signed_v1","signed_at":"2026-05-17T23:57:41.527473Z","signed_message":"canonical_sha256_bytes"},"source_id":"1804.09863","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:62df46cd6fed20aec935d810621928a672b06ac58c3fc71915197b0c80e7ec58","sha256:ba7365dc702ee4be16017c777ceb207604662091107d4be7f82fe6547c2e048c"],"state_sha256":"0c8216ea042887a9342f3d3b176a80a49ac0c79fb10547ec2a18516a5f8c287e"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"RLL0PD0J8KZWPoi9yyO2rqWkxk1Nl+7hWQ12n4ZtCF+cTqH3fdkgSlxUm3W9VaPgNb1k2WNN/yN+hBW7fNCFCg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-28T10:01:28.708793Z","bundle_sha256":"ff7ef0a36e1f45618ea1ea9e12eb682a6c04d89b145889524a51d688539b190f"}}