{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2000:HFODXBNAY27W664W6UTQ4TTDDL","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"cf962d63d58dcd84568e67df7aa3bc80964524e5153903e4694ccc4678e284f0","cross_cats_sorted":["cond-mat.stat-mech"],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2000-08-18T21:56:14Z","title_canon_sha256":"6833387a43be1a3af6fcdda73822c3c700a902a533b17c6dff36da81c1e47874"},"schema_version":"1.0","source":{"id":"physics/0008164","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"physics/0008164","created_at":"2026-07-04T14:43:19Z"},{"alias_kind":"arxiv_version","alias_value":"physics/0008164v1","created_at":"2026-07-04T14:43:19Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0008164","created_at":"2026-07-04T14:43:19Z"},{"alias_kind":"pith_short_12","alias_value":"HFODXBNAY27W","created_at":"2026-07-04T14:43:19Z"},{"alias_kind":"pith_short_16","alias_value":"HFODXBNAY27W664W","created_at":"2026-07-04T14:43:19Z"},{"alias_kind":"pith_short_8","alias_value":"HFODXBNA","created_at":"2026-07-04T14:43:19Z"}],"graph_snapshots":[{"event_id":"sha256:b529dba24c89e1b5b9a289d1ec613b68f34289087e22d002b9925f06d6da0a26","target":"graph","created_at":"2026-07-04T14:43:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/physics/0008164/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The electron transfer kinetics of mixed-valence systems is studied via solving the eigen-structure of the two-state non-adiabatic diffusion operator for a wide range of electronic coupling constants and energy bias constants. The calculated spectral structure consists of three branches in the eigen-diagram, a real branch corresponding to exponential or multi-exponential decay and two symmetric branches corresponding to population oscillations between donor and acceptor states. The observed electronic coherence is shown as a result of underdamped Rabi oscillations in an overdamped solvent envir","authors_text":"J. Cao, R. J. Silbey, Y. Jung","cross_cats":["cond-mat.stat-mech"],"headline":"","license":"","primary_cat":"physics.chem-ph","submitted_at":"2000-08-18T21:56:14Z","title":"Electronic coherence in mixed-valence systems: Spectral analysis"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0008164","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:a7b5b66733c3759558a409f79740306f483ad45d48341a050997f03465c2434a","target":"record","created_at":"2026-07-04T14:43:19Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"cf962d63d58dcd84568e67df7aa3bc80964524e5153903e4694ccc4678e284f0","cross_cats_sorted":["cond-mat.stat-mech"],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2000-08-18T21:56:14Z","title_canon_sha256":"6833387a43be1a3af6fcdda73822c3c700a902a533b17c6dff36da81c1e47874"},"schema_version":"1.0","source":{"id":"physics/0008164","kind":"arxiv","version":1}},"canonical_sha256":"395c3b85a0c6bf6f7b96f5270e4e631af750117cd52d720a48ba6e422fc94b91","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"395c3b85a0c6bf6f7b96f5270e4e631af750117cd52d720a48ba6e422fc94b91","first_computed_at":"2026-07-04T14:43:19.725447Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-04T14:43:19.725447Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"SkjP+cFO/OqCGw3wQnbx6Zvw5R5/mtZ6ul8whLop9qpe1Psx6yWxSEBZhbOQJRTLU/JXZsxhiRaCYaoeWZITAg==","signature_status":"signed_v1","signed_at":"2026-07-04T14:43:19.725802Z","signed_message":"canonical_sha256_bytes"},"source_id":"physics/0008164","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:a7b5b66733c3759558a409f79740306f483ad45d48341a050997f03465c2434a","sha256:b529dba24c89e1b5b9a289d1ec613b68f34289087e22d002b9925f06d6da0a26"],"state_sha256":"2775b53622a62f6208518802c622ea1d33a9fbbd766db07ad18cbb929cb441f4"}