{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2012:HK6OG2FJPGXKSA3ZDCHO3KVKPX","short_pith_number":"pith:HK6OG2FJ","canonical_record":{"source":{"id":"1208.1587","kind":"arxiv","version":5},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-08T05:50:00Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"9a0b7842012c868497b33b6e226b0560037edad92da7f8691bb90e370f194247","abstract_canon_sha256":"6d66d938cfc53b40c44e06fc309113f1073f9eb7b341d90878b4e291010b132e"},"schema_version":"1.0"},"canonical_sha256":"3abce368a979aea90379188eedaaaa7de94c0c8d42ee6b096023645ee1a953e4","source":{"kind":"arxiv","id":"1208.1587","version":5},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1208.1587","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"arxiv_version","alias_value":"1208.1587v5","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1208.1587","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"pith_short_12","alias_value":"HK6OG2FJPGXK","created_at":"2026-05-18T12:27:09Z"},{"alias_kind":"pith_short_16","alias_value":"HK6OG2FJPGXKSA3Z","created_at":"2026-05-18T12:27:09Z"},{"alias_kind":"pith_short_8","alias_value":"HK6OG2FJ","created_at":"2026-05-18T12:27:09Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2012:HK6OG2FJPGXKSA3ZDCHO3KVKPX","target":"record","payload":{"canonical_record":{"source":{"id":"1208.1587","kind":"arxiv","version":5},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-08T05:50:00Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"9a0b7842012c868497b33b6e226b0560037edad92da7f8691bb90e370f194247","abstract_canon_sha256":"6d66d938cfc53b40c44e06fc309113f1073f9eb7b341d90878b4e291010b132e"},"schema_version":"1.0"},"canonical_sha256":"3abce368a979aea90379188eedaaaa7de94c0c8d42ee6b096023645ee1a953e4","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T03:27:54.669036Z","signature_b64":"DVgSZKd22ArsNaVWoLZrRE05egthZoPBy80Pmzor1j4gdJy8G5nAPwO2MduuDOyaX+u/2zmQEX0qCGuRO6/FBQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"3abce368a979aea90379188eedaaaa7de94c0c8d42ee6b096023645ee1a953e4","last_reissued_at":"2026-05-18T03:27:54.668243Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T03:27:54.668243Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1208.1587","source_version":5,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:27:54Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"fyHSJEEwMf77kI1hkqCeTAVLSOSi9RX+xrQNNqOHdY06tbCrnEkXJ/JNCuwnbspC7OwjIz78EozwswI6ogt8Cg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-30T11:10:16.704645Z"},"content_sha256":"246b72d3057b478444abfb68e5c16039c2b682107a171dbe377140f48fbf53a7","schema_version":"1.0","event_id":"sha256:246b72d3057b478444abfb68e5c16039c2b682107a171dbe377140f48fbf53a7"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2012:HK6OG2FJPGXKSA3ZDCHO3KVKPX","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Martin Z. Bazant","submitted_at":"2012-08-08T05:50:00Z","abstract_excerpt":"Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create inhomogeneities that can dramatically affect the reaction rate. The extreme case is that of a reaction coupled to a phase transformation, whose kinetics must depend on the order parameter -- and its gradients, at phase boundaries. This Account presents a general theory of chemical kinetics based on nonequilibrium thermodynamics. The reaction rate is a nonlinear function of the t"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1208.1587","kind":"arxiv","version":5},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T03:27:54Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Go1sQyd6tSoQWDE3hhHwrG2XJbAPLF8BjT+qD7/BoFC6wzp4EpTyIroQXcFQ1fUvext0r0H6JuVubIAO5EheAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-30T11:10:16.705380Z"},"content_sha256":"2a49f788db3b7ebde7cbe528c53806a46ad4f203da94e3082fc296823ccb1ce9","schema_version":"1.0","event_id":"sha256:2a49f788db3b7ebde7cbe528c53806a46ad4f203da94e3082fc296823ccb1ce9"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/bundle.json","state_url":"https://pith.science/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-30T11:10:16Z","links":{"resolver":"https://pith.science/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX","bundle":"https://pith.science/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/bundle.json","state":"https://pith.science/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/state.json","well_known_bundle":"https://pith.science/.well-known/pith/HK6OG2FJPGXKSA3ZDCHO3KVKPX/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2012:HK6OG2FJPGXKSA3ZDCHO3KVKPX","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"6d66d938cfc53b40c44e06fc309113f1073f9eb7b341d90878b4e291010b132e","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-08T05:50:00Z","title_canon_sha256":"9a0b7842012c868497b33b6e226b0560037edad92da7f8691bb90e370f194247"},"schema_version":"1.0","source":{"id":"1208.1587","kind":"arxiv","version":5}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1208.1587","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"arxiv_version","alias_value":"1208.1587v5","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1208.1587","created_at":"2026-05-18T03:27:54Z"},{"alias_kind":"pith_short_12","alias_value":"HK6OG2FJPGXK","created_at":"2026-05-18T12:27:09Z"},{"alias_kind":"pith_short_16","alias_value":"HK6OG2FJPGXKSA3Z","created_at":"2026-05-18T12:27:09Z"},{"alias_kind":"pith_short_8","alias_value":"HK6OG2FJ","created_at":"2026-05-18T12:27:09Z"}],"graph_snapshots":[{"event_id":"sha256:2a49f788db3b7ebde7cbe528c53806a46ad4f203da94e3082fc296823ccb1ce9","target":"graph","created_at":"2026-05-18T03:27:54Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create inhomogeneities that can dramatically affect the reaction rate. The extreme case is that of a reaction coupled to a phase transformation, whose kinetics must depend on the order parameter -- and its gradients, at phase boundaries. This Account presents a general theory of chemical kinetics based on nonequilibrium thermodynamics. The reaction rate is a nonlinear function of the t","authors_text":"Martin Z. Bazant","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-08T05:50:00Z","title":"Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1208.1587","kind":"arxiv","version":5},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:246b72d3057b478444abfb68e5c16039c2b682107a171dbe377140f48fbf53a7","target":"record","created_at":"2026-05-18T03:27:54Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"6d66d938cfc53b40c44e06fc309113f1073f9eb7b341d90878b4e291010b132e","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2012-08-08T05:50:00Z","title_canon_sha256":"9a0b7842012c868497b33b6e226b0560037edad92da7f8691bb90e370f194247"},"schema_version":"1.0","source":{"id":"1208.1587","kind":"arxiv","version":5}},"canonical_sha256":"3abce368a979aea90379188eedaaaa7de94c0c8d42ee6b096023645ee1a953e4","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"3abce368a979aea90379188eedaaaa7de94c0c8d42ee6b096023645ee1a953e4","first_computed_at":"2026-05-18T03:27:54.668243Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T03:27:54.668243Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"DVgSZKd22ArsNaVWoLZrRE05egthZoPBy80Pmzor1j4gdJy8G5nAPwO2MduuDOyaX+u/2zmQEX0qCGuRO6/FBQ==","signature_status":"signed_v1","signed_at":"2026-05-18T03:27:54.669036Z","signed_message":"canonical_sha256_bytes"},"source_id":"1208.1587","source_kind":"arxiv","source_version":5}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:246b72d3057b478444abfb68e5c16039c2b682107a171dbe377140f48fbf53a7","sha256:2a49f788db3b7ebde7cbe528c53806a46ad4f203da94e3082fc296823ccb1ce9"],"state_sha256":"3eef5d94220f9f03da9f2a431ff47fb967b31df9a92eefd31b4c23df8a61b9d8"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"aOvb9ZyPL9yAKCCS+7gOzw63pGR4Wi6ArdsWX0RsdOvlrjwn9Y/gOkhFPSXq+8Yccpy/8mFGeB/fhTEXkrYeDQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-30T11:10:16.710463Z","bundle_sha256":"45dd2ff3797a3fa35ed34197817be343713174ef5b81bb2d77fa0548bd25e499"}}