{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:IIY6ZSI7NGHAJMR6QLPJRP2LGD","short_pith_number":"pith:IIY6ZSI7","canonical_record":{"source":{"id":"1611.09115","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-11-28T13:47:03Z","cross_cats_sorted":[],"title_canon_sha256":"0ba5c33df839eec028383ed068e16407c5433171a8881626a4414f464d3756f4","abstract_canon_sha256":"b73e2ccad8ff4fac5e4280714c130b372038714d5b7d362ecf34435fceaf76a7"},"schema_version":"1.0"},"canonical_sha256":"4231ecc91f698e04b23e82de98bf4b30d524f751d58d193cfee9adb6b26b8617","source":{"kind":"arxiv","id":"1611.09115","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1611.09115","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"arxiv_version","alias_value":"1611.09115v1","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1611.09115","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"pith_short_12","alias_value":"IIY6ZSI7NGHA","created_at":"2026-05-18T12:30:22Z"},{"alias_kind":"pith_short_16","alias_value":"IIY6ZSI7NGHAJMR6","created_at":"2026-05-18T12:30:22Z"},{"alias_kind":"pith_short_8","alias_value":"IIY6ZSI7","created_at":"2026-05-18T12:30:22Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:IIY6ZSI7NGHAJMR6QLPJRP2LGD","target":"record","payload":{"canonical_record":{"source":{"id":"1611.09115","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-11-28T13:47:03Z","cross_cats_sorted":[],"title_canon_sha256":"0ba5c33df839eec028383ed068e16407c5433171a8881626a4414f464d3756f4","abstract_canon_sha256":"b73e2ccad8ff4fac5e4280714c130b372038714d5b7d362ecf34435fceaf76a7"},"schema_version":"1.0"},"canonical_sha256":"4231ecc91f698e04b23e82de98bf4b30d524f751d58d193cfee9adb6b26b8617","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:31:41.906563Z","signature_b64":"VYDOZAiuevz3XabEK7K9GhhGr9L62tB+AT4BSE+n4owzFJEzdklIQTWTwuam2yutAtlbc/XczUtoJWEm1lhBCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"4231ecc91f698e04b23e82de98bf4b30d524f751d58d193cfee9adb6b26b8617","last_reissued_at":"2026-05-18T00:31:41.906199Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:31:41.906199Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1611.09115","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:31:41Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"+4R3q98J4TEn+PEAdZJUd8KOLH99cbIh+xGypEjvAyS7jd+iA+H2EIqHvTgCQ8Nm+QUCYRn/W1HOtBMs0YqNDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T16:50:54.584905Z"},"content_sha256":"470ab29e6c81a862168d4a342da32f98dcc71432c6f9c66fce73c56c79098152","schema_version":"1.0","event_id":"sha256:470ab29e6c81a862168d4a342da32f98dcc71432c6f9c66fce73c56c79098152"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:IIY6ZSI7NGHAJMR6QLPJRP2LGD","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Tuning nonradiative lifetimes via molecular aggregation","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"A. Celestino, A. Eisfeld","submitted_at":"2016-11-28T13:47:03Z","abstract_excerpt":"We show that molecular aggregation can strongly influence the nonradiative decay (NRD) lifetime of an electronic excitation. As a demonstrative example, we consider a transition-dipole-dipole-interacting dimer whose monomers have harmonic potential energy surfaces (PESs). Depending on the position of the NRD channel ($q_{\\rm nr}$), we find that the NRD lifetime ($\\tau_{\\rm nr}^{\\rm dim}$) can exhibit a completely different dependence on the intermolecular-interaction strength. We observe that (i) for $q_{\\rm nr}$ near the Franck-Condon region, $\\tau_{\\rm nr}^{\\rm dim}$ increases with the inter"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1611.09115","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:31:41Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Zy/28ciHxgZvbyZ9JtGx4DJcEcq0umBjzCFfwcVhOvyeAIaWfhcS7qmxeClXGWV+uEhgDdvyekx1ta3WXPpJAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T16:50:54.585247Z"},"content_sha256":"868273ed6967c1583509a45df684298a98d66237944fb0dc81141d5b14c752fa","schema_version":"1.0","event_id":"sha256:868273ed6967c1583509a45df684298a98d66237944fb0dc81141d5b14c752fa"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/bundle.json","state_url":"https://pith.science/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-03T16:50:54Z","links":{"resolver":"https://pith.science/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD","bundle":"https://pith.science/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/bundle.json","state":"https://pith.science/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/state.json","well_known_bundle":"https://pith.science/.well-known/pith/IIY6ZSI7NGHAJMR6QLPJRP2LGD/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:IIY6ZSI7NGHAJMR6QLPJRP2LGD","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"b73e2ccad8ff4fac5e4280714c130b372038714d5b7d362ecf34435fceaf76a7","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-11-28T13:47:03Z","title_canon_sha256":"0ba5c33df839eec028383ed068e16407c5433171a8881626a4414f464d3756f4"},"schema_version":"1.0","source":{"id":"1611.09115","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1611.09115","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"arxiv_version","alias_value":"1611.09115v1","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1611.09115","created_at":"2026-05-18T00:31:41Z"},{"alias_kind":"pith_short_12","alias_value":"IIY6ZSI7NGHA","created_at":"2026-05-18T12:30:22Z"},{"alias_kind":"pith_short_16","alias_value":"IIY6ZSI7NGHAJMR6","created_at":"2026-05-18T12:30:22Z"},{"alias_kind":"pith_short_8","alias_value":"IIY6ZSI7","created_at":"2026-05-18T12:30:22Z"}],"graph_snapshots":[{"event_id":"sha256:868273ed6967c1583509a45df684298a98d66237944fb0dc81141d5b14c752fa","target":"graph","created_at":"2026-05-18T00:31:41Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We show that molecular aggregation can strongly influence the nonradiative decay (NRD) lifetime of an electronic excitation. As a demonstrative example, we consider a transition-dipole-dipole-interacting dimer whose monomers have harmonic potential energy surfaces (PESs). Depending on the position of the NRD channel ($q_{\\rm nr}$), we find that the NRD lifetime ($\\tau_{\\rm nr}^{\\rm dim}$) can exhibit a completely different dependence on the intermolecular-interaction strength. We observe that (i) for $q_{\\rm nr}$ near the Franck-Condon region, $\\tau_{\\rm nr}^{\\rm dim}$ increases with the inter","authors_text":"A. Celestino, A. Eisfeld","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-11-28T13:47:03Z","title":"Tuning nonradiative lifetimes via molecular aggregation"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1611.09115","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:470ab29e6c81a862168d4a342da32f98dcc71432c6f9c66fce73c56c79098152","target":"record","created_at":"2026-05-18T00:31:41Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"b73e2ccad8ff4fac5e4280714c130b372038714d5b7d362ecf34435fceaf76a7","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-11-28T13:47:03Z","title_canon_sha256":"0ba5c33df839eec028383ed068e16407c5433171a8881626a4414f464d3756f4"},"schema_version":"1.0","source":{"id":"1611.09115","kind":"arxiv","version":1}},"canonical_sha256":"4231ecc91f698e04b23e82de98bf4b30d524f751d58d193cfee9adb6b26b8617","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"4231ecc91f698e04b23e82de98bf4b30d524f751d58d193cfee9adb6b26b8617","first_computed_at":"2026-05-18T00:31:41.906199Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:31:41.906199Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"VYDOZAiuevz3XabEK7K9GhhGr9L62tB+AT4BSE+n4owzFJEzdklIQTWTwuam2yutAtlbc/XczUtoJWEm1lhBCA==","signature_status":"signed_v1","signed_at":"2026-05-18T00:31:41.906563Z","signed_message":"canonical_sha256_bytes"},"source_id":"1611.09115","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:470ab29e6c81a862168d4a342da32f98dcc71432c6f9c66fce73c56c79098152","sha256:868273ed6967c1583509a45df684298a98d66237944fb0dc81141d5b14c752fa"],"state_sha256":"be820f2df8d56ea8750837b1529d53e32adf06c9260a24d51a7302e001cffb14"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"y9yf+SidbyGl+Jhl/v/PA6uCrYi0EJg8E0brmdfdJZBa3WdK6H/TW9mMmCF+2sFHDl8n7TbGqbRIQy0t65GeAQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-03T16:50:54.587179Z","bundle_sha256":"0ee1cd41c1a94d24521854fefcfa5de5d7e42a0053c8a105c55b0b4e51f19b7f"}}