{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2014:K3Z6BCWZ2CPHKECRY4SBSGECWU","short_pith_number":"pith:K3Z6BCWZ","schema_version":"1.0","canonical_sha256":"56f3e08ad9d09e751051c724191882b52a46a69544bef0920c6f9dd5e4fb21b1","source":{"kind":"arxiv","id":"1409.5323","version":1},"attestation_state":"computed","paper":{"title":"Tuning of magnetic frustration in $S=1/2$ Kagom\\'{e} lattices {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpe)_{3}$](ClO$_{4}$)$_2$}$_{n}$ and {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpy)_{3}$](ClO$_{4}$)$_2$}$_{n}$ through rigid and flexible ligands","license":"http://creativecommons.org/licenses/by/3.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"A. Yogi, M. O. Ajeesh, M. Padmanabhan, R. Nath","submitted_at":"2014-09-18T15:00:39Z","abstract_excerpt":"Single crystalline and polycrystalline samples of $S=1/2$ Kagom\\'{e} lattices {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpe)_{3}$](ClO$_{4}$)$_2$}$_{n}$ and {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpy)_{3}$](ClO$_{4}$)$_2$}$_{n}$, respectively were synthesized. Their structural and magnetic properties were characterized by means of x-ray diffraction and magnetization measurements. Both compounds crystalize in a hexagonal structure (space group $P-6$) consisting of CuO$_4$ Kagom\\'{e} layers in the $ab$-plane but linked along $c$ direction through either rigid $bpy$ or flexible $bpe$ ligands to form 3D frame works. Magne"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1409.5323","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/3.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-09-18T15:00:39Z","cross_cats_sorted":[],"title_canon_sha256":"5a0fe5d2fda149e483db77336daeeb79650715181409c63e0f2bb8247f04f58f","abstract_canon_sha256":"a7e864ca5768eb85fd60865615f01df1275f0f6045532ae9a413132727742d3a"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:37:49.348576Z","signature_b64":"Q7DsPgpnWCT7IoMqGz8ghppXKwkoxSQ/6AAt1fVIhP/FZutc3MdmiPEDGb8nW9CPPrnclyd2rmTLqHuC6zDfCw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"56f3e08ad9d09e751051c724191882b52a46a69544bef0920c6f9dd5e4fb21b1","last_reissued_at":"2026-05-18T01:37:49.347861Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:37:49.347861Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Tuning of magnetic frustration in $S=1/2$ Kagom\\'{e} lattices {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpe)_{3}$](ClO$_{4}$)$_2$}$_{n}$ and {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpy)_{3}$](ClO$_{4}$)$_2$}$_{n}$ through rigid and flexible ligands","license":"http://creativecommons.org/licenses/by/3.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"A. Yogi, M. O. Ajeesh, M. Padmanabhan, R. Nath","submitted_at":"2014-09-18T15:00:39Z","abstract_excerpt":"Single crystalline and polycrystalline samples of $S=1/2$ Kagom\\'{e} lattices {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpe)_{3}$](ClO$_{4}$)$_2$}$_{n}$ and {[Cu$_{3}$(CO$_{3}$)$_{2}$$(bpy)_{3}$](ClO$_{4}$)$_2$}$_{n}$, respectively were synthesized. Their structural and magnetic properties were characterized by means of x-ray diffraction and magnetization measurements. Both compounds crystalize in a hexagonal structure (space group $P-6$) consisting of CuO$_4$ Kagom\\'{e} layers in the $ab$-plane but linked along $c$ direction through either rigid $bpy$ or flexible $bpe$ ligands to form 3D frame works. Magne"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1409.5323","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1409.5323","created_at":"2026-05-18T01:37:49.347988+00:00"},{"alias_kind":"arxiv_version","alias_value":"1409.5323v1","created_at":"2026-05-18T01:37:49.347988+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1409.5323","created_at":"2026-05-18T01:37:49.347988+00:00"},{"alias_kind":"pith_short_12","alias_value":"K3Z6BCWZ2CPH","created_at":"2026-05-18T12:28:35.611951+00:00"},{"alias_kind":"pith_short_16","alias_value":"K3Z6BCWZ2CPHKECR","created_at":"2026-05-18T12:28:35.611951+00:00"},{"alias_kind":"pith_short_8","alias_value":"K3Z6BCWZ","created_at":"2026-05-18T12:28:35.611951+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU","json":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU.json","graph_json":"https://pith.science/api/pith-number/K3Z6BCWZ2CPHKECRY4SBSGECWU/graph.json","events_json":"https://pith.science/api/pith-number/K3Z6BCWZ2CPHKECRY4SBSGECWU/events.json","paper":"https://pith.science/paper/K3Z6BCWZ"},"agent_actions":{"view_html":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU","download_json":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU.json","view_paper":"https://pith.science/paper/K3Z6BCWZ","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1409.5323&json=true","fetch_graph":"https://pith.science/api/pith-number/K3Z6BCWZ2CPHKECRY4SBSGECWU/graph.json","fetch_events":"https://pith.science/api/pith-number/K3Z6BCWZ2CPHKECRY4SBSGECWU/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU/action/timestamp_anchor","attest_storage":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU/action/storage_attestation","attest_author":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU/action/author_attestation","sign_citation":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU/action/citation_signature","submit_replication":"https://pith.science/pith/K3Z6BCWZ2CPHKECRY4SBSGECWU/action/replication_record"}},"created_at":"2026-05-18T01:37:49.347988+00:00","updated_at":"2026-05-18T01:37:49.347988+00:00"}