{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2001:KNCWIQJ7OMZMJDMDY2R4S67I7C","short_pith_number":"pith:KNCWIQJ7","schema_version":"1.0","canonical_sha256":"534564413f7332c48d83c6a3c97be8f8a89e9fdc5ac0488454c501cf2c10b739","source":{"kind":"arxiv","id":"cond-mat/0108207","version":2},"attestation_state":"computed","paper":{"title":"Lattice Relaxation and Charge-Transfer Optical Transitions Due to Self-Trapped Holes in Non-Stoichiometric LaMnO$_3$ Crystal","license":"","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"A. L. Shluger, A. M. Stoneham, A. V. Boris, J. L. Gavartin, N. N. Kovaleva","submitted_at":"2001-08-13T16:25:30Z","abstract_excerpt":"We use the Mott-Littleton approach to evaluate polarisation energies in LaMnO$_3$ lattice associated with holes localized on both Mn$^{3+}$ cation and O$^{2-}$ anion. The full (electronic and ionic) lattice relaxation energy for a hole localized at the O-site is estimated as 2.4 eV which is appreciably greater than that of 0.8 eV for a hole localized at the Mn-site, indicating on the strong electron-phonon interaction in the former case. Using a Born-Haber cycle we examine thermal and optical energies of the hole formation associated with electron ionization from Mn$^{3+}$, O$^{2-}$ and La$^{3"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"cond-mat/0108207","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-08-13T16:25:30Z","cross_cats_sorted":[],"title_canon_sha256":"708f92e6552b4cf12e2e86c1274249c70009ec354214d2a84526feb205c5792b","abstract_canon_sha256":"be88e6f2c867073b13aadaa973297c47b3d2f0cf6e567b095e673130e41a953a"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-04T16:26:07.906367Z","signature_b64":"NXAtdrlt7GCU1Ufy8LYfKeAz8KOwREIAta5qjAAsSwuqfSC7LMm/B05J8mUJCWNP0WA27Z2ck9wyj36KJkiMBA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"534564413f7332c48d83c6a3c97be8f8a89e9fdc5ac0488454c501cf2c10b739","last_reissued_at":"2026-07-04T16:26:07.905948Z","signature_status":"signed_v1","first_computed_at":"2026-07-04T16:26:07.905948Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Lattice Relaxation and Charge-Transfer Optical Transitions Due to Self-Trapped Holes in Non-Stoichiometric LaMnO$_3$ Crystal","license":"","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"A. L. Shluger, A. M. Stoneham, A. V. Boris, J. L. Gavartin, N. N. Kovaleva","submitted_at":"2001-08-13T16:25:30Z","abstract_excerpt":"We use the Mott-Littleton approach to evaluate polarisation energies in LaMnO$_3$ lattice associated with holes localized on both Mn$^{3+}$ cation and O$^{2-}$ anion. The full (electronic and ionic) lattice relaxation energy for a hole localized at the O-site is estimated as 2.4 eV which is appreciably greater than that of 0.8 eV for a hole localized at the Mn-site, indicating on the strong electron-phonon interaction in the former case. Using a Born-Haber cycle we examine thermal and optical energies of the hole formation associated with electron ionization from Mn$^{3+}$, O$^{2-}$ and La$^{3"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0108207","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/cond-mat/0108207/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0108207","created_at":"2026-07-04T16:26:07.906011+00:00"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0108207v2","created_at":"2026-07-04T16:26:07.906011+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0108207","created_at":"2026-07-04T16:26:07.906011+00:00"},{"alias_kind":"pith_short_12","alias_value":"KNCWIQJ7OMZM","created_at":"2026-07-04T16:26:07.906011+00:00"},{"alias_kind":"pith_short_16","alias_value":"KNCWIQJ7OMZMJDMD","created_at":"2026-07-04T16:26:07.906011+00:00"},{"alias_kind":"pith_short_8","alias_value":"KNCWIQJ7","created_at":"2026-07-04T16:26:07.906011+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C","json":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C.json","graph_json":"https://pith.science/api/pith-number/KNCWIQJ7OMZMJDMDY2R4S67I7C/graph.json","events_json":"https://pith.science/api/pith-number/KNCWIQJ7OMZMJDMDY2R4S67I7C/events.json","paper":"https://pith.science/paper/KNCWIQJ7"},"agent_actions":{"view_html":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C","download_json":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C.json","view_paper":"https://pith.science/paper/KNCWIQJ7","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=cond-mat/0108207&json=true","fetch_graph":"https://pith.science/api/pith-number/KNCWIQJ7OMZMJDMDY2R4S67I7C/graph.json","fetch_events":"https://pith.science/api/pith-number/KNCWIQJ7OMZMJDMDY2R4S67I7C/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C/action/timestamp_anchor","attest_storage":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C/action/storage_attestation","attest_author":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C/action/author_attestation","sign_citation":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C/action/citation_signature","submit_replication":"https://pith.science/pith/KNCWIQJ7OMZMJDMDY2R4S67I7C/action/replication_record"}},"created_at":"2026-07-04T16:26:07.906011+00:00","updated_at":"2026-07-04T16:26:07.906011+00:00"}